One significant challenge for electronic devices is that the energy storage devices are unable to provide su cient energy for continuous and long-time operation,leading to frequent recharging or inconvenient battery r...One significant challenge for electronic devices is that the energy storage devices are unable to provide su cient energy for continuous and long-time operation,leading to frequent recharging or inconvenient battery replacement.To satisfy the needs of next-generation electronic devices for sustainable working,conspicuous progress has been achieved regarding the development for nanogenerator-based self-charging energy storage devices.Herein,the development of the self-charging energy storage devices is summarized.Focus will be on preparation of nanomaterials for Li-ion batteries and supercapacitors,structural design of the nanogenerator-based self-charging energy storage devices,performance testing,and potential applications.Moreover,the challenges and perspectives regarding self-charging energy storage devices are also discussed.展开更多
Three-dimensional(3D)printing has gained popularity in a variety of applications,particularly in the manufacture of wearable devices.Aided by the large degree of freedom in customizable fabrication,3D printing can cat...Three-dimensional(3D)printing has gained popularity in a variety of applications,particularly in the manufacture of wearable devices.Aided by the large degree of freedom in customizable fabrication,3D printing can cater towards the practical requirements of wearable devices in terms of light weight and flexibility.In particular,this focus review aims to cover the important aspect of wearable energy storage devices(WESDs),which is an essential component of most wearable devices.Herein,the topics discussed are the fundamentals of 3D printing inks used,the optimizing strategies in improving the mechanical and electrochemical properties of wearable devices and the recent developments and challenges of wearable electrochemical systems such as batteries and supercapacitors.It can be expected that,with the development of 3D printing technology,realization of the full potential of WESDs and seamless integration into smart devices also needs further in-depth investigations.展开更多
The increasing energy requirements to power the modern world has driven active research into more advanced electrochemical energy storage devices(EESD)with both high energy densities and power densities.Wide range of ...The increasing energy requirements to power the modern world has driven active research into more advanced electrochemical energy storage devices(EESD)with both high energy densities and power densities.Wide range of newly discovered materials with promising electrochemical properties has shown great potential for next-generation devices,but their performance is normally associated with contradicting demands of thin electrodes and high mass loading that can be hardly achieved for practical applications.Design of three-dimensional(3D)porous electrodes can increase the mass loading while maintaining the effective charge transport even with thick electrodes,which has proven to be efficient to overcome the limitations.3D structures have also been demonstrated excellent structural stability to withstand strong strains and stresses generated during charge/discharge cycle.3D printing,which can fabricate various delicate and complex structural designs,thus offering brand-new opportunities for the rational design and facile construction of next-generation EESDs.The recent developments in 3D printing of next-generation EESDs with high performance are reviewed.Advanced/multiscale electrode structures,such as hierarchically porous structure that can be constructed via high-resolution 3D printing or with post-treatment,are further emphasized.The ability of current 3D printing techniques to fulfill multimaterial printing to fulfill simple packaging will be covered.展开更多
The rapid development of micro-electronics raises the demand of their power sources to be simplified,miniaturized and highly integratable with other electronics on a chip.In-plane Micro-sized energy storage devices(ME...The rapid development of micro-electronics raises the demand of their power sources to be simplified,miniaturized and highly integratable with other electronics on a chip.In-plane Micro-sized energy storage devices(MESDs),which are composed of interdigitated electrodes on a single chip,have aroused particular attentions since they could be easily integrated with other miniaturized electronics,reducing the complexity of overall chip design via removing complex interconnections with bulky power sources.This review highlights the achievements in the device fabrication of in-plane MESDs,as well as their integration and intelligent designs.We also discussed the current challenges and future perspectives for the development of in-plane MESDs.展开更多
The rapid progress of micro/nanoelectronic systems and miniaturized portable devices has tremendously increased the urgent demands for miniaturized and integrated power supplies.Miniaturized energy storage devices(MES...The rapid progress of micro/nanoelectronic systems and miniaturized portable devices has tremendously increased the urgent demands for miniaturized and integrated power supplies.Miniaturized energy storage devices(MESDs),with their excellent properties and additional intelligent functions,are considered to be the preferable energy supplies for uninterrupted powering of microsystems.In this review,we aim to provide a comprehensive overview of the background,fundamentals,device configurations,manufacturing processes,and typical applications of MESDs,including their recent advances.Particular attention is paid to advanced device configurations,such as two-dimensional(2D)stacked,2D planar interdigital,2D arbitrary-shaped,three-dimensional planar,and wire-shaped structures,and their corresponding manufacturing strategies,such as printing,scribing,and masking techniques.Additionally,recent developments in MESDs,including microbatteries and microsupercapacitors,as well as microhybrid metal ion capacitors,are systematically summarized.A series of on-chip microsystems,created by integrating functional MESDs,are also highlighted.Finally,the remaining challenges and future research scope on MESDs are discussed.展开更多
With the growing market of wearable devices for smart sensing and personalized healthcare applications,energy storage devices that ensure stable power supply and can be constructed in flexible platforms have attracted...With the growing market of wearable devices for smart sensing and personalized healthcare applications,energy storage devices that ensure stable power supply and can be constructed in flexible platforms have attracted tremendous research interests.A variety of active materials and fabrication strategies of flexible energy storage devices have been intensively studied in recent years,especially for integrated self-powered systems and biosensing.A series of materials and applications for flexible energy storage devices have been studied in recent years.In this review,the commonly adopted fabrication methods of flexible energy storage devices are introduced.Besides,recent advances in integrating these energy devices into flexible self-powered systems are presented.Furthermore,the applications of flexible energy storage devices for biosensing are summarized.Finally,the prospects and challenges of the self-powered sensing system for wearable electronics are discussed.展开更多
To prevent and mitigate environmental degradation,high-performance and cost-effective electrochemical flexible energy storage systems need to be urgently developed.This demand has led to an increase in research on ele...To prevent and mitigate environmental degradation,high-performance and cost-effective electrochemical flexible energy storage systems need to be urgently developed.This demand has led to an increase in research on electrode materials for high-capacity flexible supercapacitors and secondary batteries,which have greatly aided the development of contemporary digital communications and electric vehicles.The use of layered double hydroxides(LDHs)as electrode materials has shown productive results over the last decade,owing to their easy production,versatile composition,low cost,and excellent physicochemical features.This review highlights the distinctive 2D sheet-like structures and electrochemical characteristics of LDH materials,as well as current developments in their fabrication strategies for expanding the application scope of LDHs as electrode materials for flexible supercapacitors and alkali metal(Li,Na,K)ion batteries.展开更多
Flexible electrochromic energy storage devices(FECESDs)for powering flexible electronics have attracted considerable attention.Silver nanowires(AgNWs)are one kind of the most promising flexible transparent electrodes(...Flexible electrochromic energy storage devices(FECESDs)for powering flexible electronics have attracted considerable attention.Silver nanowires(AgNWs)are one kind of the most promising flexible transparent electrodes(FTEs)materials for the emerging flexible devices.Currently,fabricating FECESD based on AgNWs FTEs is still hindered by their intrinsic poor electrochemical stability.To address this issue,a hybrid AgNWs/Co(OH)_(2)/PEDOT:PSS electrode is proposed.The PEDOT:PSS could not only improve the resistance against electrochemical corrosion of AgNWs,but also work as functional layer to realize the color-changing and energy storage properties.Moreover,the Co(OH)_(2)interlayer further improved the color-changing and energy storage performance.Based on the improvement,we assembled the symmetrical FECESDs.Under the same condition,the areal capacitance(0.8 mF cm^(−2))and coloration efficiency(269.80 cm^(2)C−1)of AgNWs/Co(OH)_(2)/PEDOT:PSS FECESDs were obviously higher than AgNWs/PEDOT:PSS FECESDs.Furthermore,the obtained FECESDs exhibited excellent stability against the mechanical deformation.The areal capacitance remained stable during 1000 times cyclic bending with a 25 mm curvature radius.These results demonstrated the broad application potential of the AgNWs/Co(OH)_(2)/PEDOT:PSS FECESD for the emerging portable and multifunctional electronics.展开更多
The booming developments in portable and wearable electronics promote the design of flexible energy storage systems. Flexible supercapacitors and batteries as promising energy storage devices have attracted tremendous...The booming developments in portable and wearable electronics promote the design of flexible energy storage systems. Flexible supercapacitors and batteries as promising energy storage devices have attracted tremendous attention. As the key component of both supercapacitors and batteries, electrode materials with excellent flexibility should be considered to match with highly flexible energy storage devices. Owing to large surface area, good thermal and chemical stability, high conductivity and mechanical flexibility,graphene-based materials have been widely employed to serve as promising electrodes of flexible energy storage devices. Considerable efforts have been devoted to the fabrication of flexible graphene-based electrodes through a variety of strategies. Moreover, different configurations of energy storage devices based on these active materials are designed. This review highlights flexible graphene-based two-dimensional film and one-dimensional fiber supercapacitors and various batteries including lithium-ion, lithium–sulfur and other batteries. The challenges and promising perspectives of the graphene-based materials for flexible energy storage devices are also discussed.展开更多
The research for three-dimension(3D)printing carbon and carbide energy storage devices has attracted widespread exploration interests.Being designable in structure and materials,graphene oxide(GO)and MXene accompanied...The research for three-dimension(3D)printing carbon and carbide energy storage devices has attracted widespread exploration interests.Being designable in structure and materials,graphene oxide(GO)and MXene accompanied with a direct ink writing exhibit a promising prospect for constructing high areal and volume energy density devices.This review not only summarizes the recent advances in 3D printing energy storage devices including printing methods,ink rheological properties,and different energy storage systems,but also discusses the printing methods related to energy storage.In addition,the binder or additive free of two-dimensional carbide materials is quite important for the present electrochemical energy storage devices,which also are presented.展开更多
The rapid growth of miniaturized electronics has led to an urgent demand for microscale energy storage devices(MESDs)to sustainably power the micro electronic devices.However,most MESDs reported to date have suffered ...The rapid growth of miniaturized electronics has led to an urgent demand for microscale energy storage devices(MESDs)to sustainably power the micro electronic devices.However,most MESDs reported to date have suffered from the limited energy densities and shape versatility compared to conventional large-scale counterparts because of the architectural constraints inherent in microfabrication-based cell manufacturing and cell dimension/structure.This review addresses the cell architecture design for MESDs that can achieve both miniaturization and high energy density.We provide a comprehensive overview of five types of cell architectures of MESDs and their fabrication techniques.In addition,to enable practical applications of MESDs,several cell design approaches are presented with the aim of minimizing the inactive parts of the cell and maximizing the performance metrics of MESDs.Finally,we discuss development direction and outlook of MESDs with a focus on materials chemistry,energy-dense electrochemical systems,and cell performance normalization,which will help to expand their applications and manufacturing scalability.展开更多
Stretchable power sources,especially stretchable lithium-ion batteries(LIBs),have attracted increasing attention due to their enormous prospects for powering flexible/wearable electronics.Despite recent advances,it is...Stretchable power sources,especially stretchable lithium-ion batteries(LIBs),have attracted increasing attention due to their enormous prospects for powering flexible/wearable electronics.Despite recent advances,it is still challenging to develop ultra-stretchable LIBs that can withstand large deformation.In particular,stretchable LIBs require an elastic electrolyte as a basic component,while the conductivity of most elastic electrolytes drops sharply during deformation,especially during large deformations.This is why highly stretchable LIBs have not yet been realized until now.As a proof of concept,a super-stretchable LIB with strain up to 1200%is created based on an intrinsically super-stretchable polymer electrolyte as the lithium-ion conductor.The super-stretchable conductive system is constructed by an effective diblock copolymerization strategy via photocuring of vinyl functionalized 2-ureido-4-pyrimidone(VFUpy),an acrylic monomer containing succinonitrile and a lithium salt,achieving high ionic conductivity(3.5×10^(-4)mS cm^(-1)at room temperature(RT))and large deformation(the strain can reach 4560%).The acrylic elastomer containing Li-ion conductive domains can strongly increase the compatibility between the neighboring elastic networks,resulting in high ionic conductivity under ultra-large deformation,while VFUpy increases elasticity modulus(over three times)and electrochemical stability(voltage window reaches 5.3 V)of the prepared polymer conductor.At a strain of up to 1200%,the resulting stretchable LIBs are still sufficient to power LEDs.This study sheds light on the design and development of high-performance intrinsically super-stretchable materials for the advancement of highly elastic energy storage devices for powering flexible/wearable electronics that can endure large deformation.展开更多
The increasing popularity of the Internet of Things and the growing microelectronics market have led to a heightened demand for microscale energy storage devices,such as microbatteries and microsupercapacitors.Althoug...The increasing popularity of the Internet of Things and the growing microelectronics market have led to a heightened demand for microscale energy storage devices,such as microbatteries and microsupercapacitors.Although lithium microbatteries have dominated the market,safety concerns arising from incidents like self-ignition and explosions have prompted a shift towards new microscale energy storage devices prioritizing high safety.Zinc-based micro-energy storage devices(ZMSDs),known for their high safety,low cost,and favorable electrochemical performance,are emerging as promising alternatives to lithium microbatteries.However,challenges persist in the fabrication of microelectrodes,electrolyte infusion,device packaging,and integration with microelectronics.Despite these challenges,significant progress has been made over the last decade.This review focuses on the challenges and recent advancements in zinc-based micro-energy storage,offering unique insights into their applications and paving the way for the commercial deployment of high-performance ZMSDs.展开更多
New energy storage devices such as batteries and supercapacitors are widely used in various fields because of their irreplaceable excellent characteristics.Because there are relatively few monitoring parameters and li...New energy storage devices such as batteries and supercapacitors are widely used in various fields because of their irreplaceable excellent characteristics.Because there are relatively few monitoring parameters and limited under-standing of their operation,they present problems in accurately predicting their state and controlling operation,such as state of charge,state of health,and early failure indicators.Poor monitoring can seriously affect the performance of energy storage devices.Therefore,to maximize the efficiency of new energy storage devices without damaging the equipment,it is important to make full use of sensing systems to accurately monitor important parameters such as voltage,current,temperature,and strain.These are highly related to their states.Hence,this paper reviews the sensing methods and divides them into two categories:embedded and non-embedded sensors.A variety of measurement methods used to measure the above parameters of various new energy storage devices such as batteries and super-capacitors are systematically summarized.The methods with different innovative points are listed,their advantages and disadvantages are summarized,and the application of optical fiber sensors is emphasized.Finally,the challenges and prospects for these studies are described.The intent is to encourage researchers in relevant fields to study the early warning of safety accidents from the root causes.展开更多
Efficient energy storage devices with suitable electrode materials,that integrate high power and high energy,are the crucial requisites of the renewable power source,which have unwrapped new possibilities in the susta...Efficient energy storage devices with suitable electrode materials,that integrate high power and high energy,are the crucial requisites of the renewable power source,which have unwrapped new possibilities in the sustainable development of energy and the environment.Herein,a facile collagen microstructure modulation strategy is proposed to construct a nitrogen/oxygen dual-doped hierarchically porous carbon fiber with ultrahigh specific surface area(2788 m^(2)g^(-1))and large pore volume(4.56 cm^(3)g^(-1))via local microfibrous breakage/disassembly of natural structured proteins.Combining operando spectroscopy and density functional theory unveil that the dual-heteroatom doping could effectively regulate the electronic structure of carbon atom framework with enhanced electric conductivity and electronegativity as well as decreased diffusion resistance in favor of rapid pseudocapacitive-dominated Li^(+)-storage(353 mAh g^(-1)at 10 A g^(-1)).Theoretical calculations reveal that the tailored micro-/mesoporous structures favor the rapid charge transfer and ion storage,synergistically realizing high capacity and superior rate performance for NPCF-H cathode(75.0 mAh g^(-1)at 30 A g^(-1)).The assembled device with NPCF-H as both anode and cathode achieves extremely high energy density(200 Wh kg^(-1))with maximum power density(42600 W kg^(-1))and ultralong lifespan(80%capacity retention over 10000 cycles).展开更多
Next-generation electronics that are fused into the human body can play a key role in future intelligent communication,smart healthcare,and human enhancement applications.As a promising energy supply component for sma...Next-generation electronics that are fused into the human body can play a key role in future intelligent communication,smart healthcare,and human enhancement applications.As a promising energy supply component for smart biointegrated electronics,environment-adaptive electrochemical energy storage(EES)devices with complementary adaptability and functions have garnered huge interest in the past decade.Owing to the advancements in autonomous chemistry,which regulate the constitutional dynamic networks in materials,EES devices have witnessed higher freedom of autonomous adaptability in terms of mechano-adaptable,biocompatibility,and stimuli-response properties for biointegrated and smart applications.In this mini-review,we summarize the recent progress in emerging environmentadaptive EES devices enabled by the constitutional dynamic network of mechanical adaptable materials,biocompatible materials,and stimuli-responsive supramolecular polymer materials.Finally,the challenges and perspectives of autonomous chemistry on the environment-adaptive EES devices are discussed.展开更多
The catalytic effect of electrode materials is one of the most crucial factors for achieving efficient electrochemical energy conversion and storage.Carbon-based metal composites were widely synthesized and employed a...The catalytic effect of electrode materials is one of the most crucial factors for achieving efficient electrochemical energy conversion and storage.Carbon-based metal composites were widely synthesized and employed as electrode materials because of their inherited outstanding properties.Usually,electrode materials can provide a higher capacity than the anticipated values,even beyond the theoretical limit.The origin of the extra capacity has not yet been explained accurately,and its formation mechanism is still ambiguous.Herein,we first summarized the current research progress and drawbacks in energy storage devices(ESDs),and elaborated the role of catalytic effect in enhancing the performance of ESDs as follows:promoting the evolution of the solid electrolyte interphase(SEI),accelerating the reversible conversion of discharge/charge products,and improving the conversion speed of the intermediate and the utilization rate of the active materials,thereby avoiding the shuttling effect.Additionally,a particular focus was placed on the interaction between the catalytic effect and energy storage performance in order to highlight the efficacy and role of the catalytic effect.We hope that this review could provide innovative ideas for designing the electrode materials with an efficient catalytic effect for ESDs to promote the development of this research field.展开更多
Charging wearable energy storage devices with bioenergy from human-bodymotions, biofluids, and body heat holds great potential to construct self-powered body-worn electronics, especially considering the ceaseless natu...Charging wearable energy storage devices with bioenergy from human-bodymotions, biofluids, and body heat holds great potential to construct self-powered body-worn electronics, especially considering the ceaseless nature ofhuman metabolic activities. To bridge the gap between human-body bioen-ergy and storage of energy, wearable triboelectric/piezoelectric nanogenerators(TENGs/PENGs), biofuel cells (BFCs), thermoelectric generators (TEGs) havebeen designed to harvest energy from body-motions, biofluids, and body heat,respectively. Researchers have explored various strategies using bioenergy har-vesters to charge wearable supercapacitors and batteries to relieve or even fullyeliminate the recharging process from external power stations, thus, makingwearable electronics more sustainable, autonomous, and user friendly. In thisarticle, we review the advances in the design of sustainable energy storagedevices charged by human-body energy harvesters. The progress in multifunc-tional wearable energy storage devices that cater to the easy integration withhuman-body energy harvesters will be summarized. Then, the focus is laid onthe integrating strategies (single-cell strategy and separated-cell strategy), devicedesign, materials selection, and characteristics of different self-charging human-body energy harvesting-storage systems. Finally, the challenges that impedethe wide application of human-body energy harvesters charged supercapaci-tors/batteries and prospects will be discussed both from materials and structuraldesign aspects.展开更多
1 Results Electrochemical energy storage devices such as lithium-ion batteries[1-2] and double-layer capacitors[3-4] have attracted a great deal of attention because of their potential application to electric hybrid v...1 Results Electrochemical energy storage devices such as lithium-ion batteries[1-2] and double-layer capacitors[3-4] have attracted a great deal of attention because of their potential application to electric hybrid vehicles. They utilize nonaqueous electrolyte solutions comprising from organic solvents and lithium or quaternary ammonium salts with fluorine-containing anions. This is because the relatively large anions with electron-withdrawing atoms enable ionic dissociation in dipolar aprotic solvents...展开更多
Although a great deal of studies focus on the design of flexible energy storage devices(ESDs),their mechanical behaviors under bending states are still not sufficiently investigated,and the understanding of the corres...Although a great deal of studies focus on the design of flexible energy storage devices(ESDs),their mechanical behaviors under bending states are still not sufficiently investigated,and the understanding of the corresponding structural conversion therefore still lags behind.Here,we systematically and thoroughly investigated the mechanical behaviors of flexible all-in-one ESDs under bending deformation by the finite element method.The influences of thicknesses,Young’s moduli and Poisson’s ratios of electrodes and electrolyte were taken into account.Visualized and quantified results including displacement,strain energy,von Mises stress,and tensile,compressive,and interfacial shear stress are demonstrated and analyzed.Based on these results,significant conclusions are drawn for the design of flexible integrated ESDs with robust mechanical properties.This work will provide guidance for the design of ESDs with high flexibility.展开更多
基金the support from the National Key R&D Program of China(No.2016YFA0202701)the National Natural Science Foundation of China(No.51472055)+7 种基金External Cooperation Program of BIC,Chinese Academy of Sciences(No.121411KYS820150028)the 2015 Annual Beijing Talents Fund(No.2015000021223ZK32)the University of Chinese Academy of Sciences(No.Y8540XX2D2)Qingdao National Laboratory for Marine Science and Technology(No.2017ASKJ01)the Shenzhen Peacock Plan(No.KQTD2015071616442225)the National Natural Science Foundation of China(No.51504133)the Natural Science Foundation of Liaoning Province(No.20170540465)the “thousands talents” program for the pioneer researcher and his innovation team,China
文摘One significant challenge for electronic devices is that the energy storage devices are unable to provide su cient energy for continuous and long-time operation,leading to frequent recharging or inconvenient battery replacement.To satisfy the needs of next-generation electronic devices for sustainable working,conspicuous progress has been achieved regarding the development for nanogenerator-based self-charging energy storage devices.Herein,the development of the self-charging energy storage devices is summarized.Focus will be on preparation of nanomaterials for Li-ion batteries and supercapacitors,structural design of the nanogenerator-based self-charging energy storage devices,performance testing,and potential applications.Moreover,the challenges and perspectives regarding self-charging energy storage devices are also discussed.
基金Australian Research Council,Grant/Award Numbers:DP190100120,FT200100015。
文摘Three-dimensional(3D)printing has gained popularity in a variety of applications,particularly in the manufacture of wearable devices.Aided by the large degree of freedom in customizable fabrication,3D printing can cater towards the practical requirements of wearable devices in terms of light weight and flexibility.In particular,this focus review aims to cover the important aspect of wearable energy storage devices(WESDs),which is an essential component of most wearable devices.Herein,the topics discussed are the fundamentals of 3D printing inks used,the optimizing strategies in improving the mechanical and electrochemical properties of wearable devices and the recent developments and challenges of wearable electrochemical systems such as batteries and supercapacitors.It can be expected that,with the development of 3D printing technology,realization of the full potential of WESDs and seamless integration into smart devices also needs further in-depth investigations.
基金supports by National Natural Science Foundation of China(grant no.51902265)Fundamental Research Funds for the Central Universities,Key Research and Development Program of Shaanxi(no.2020KWZ-001)Project for graduate Innovation team of Northwestern Polytechnical University.
文摘The increasing energy requirements to power the modern world has driven active research into more advanced electrochemical energy storage devices(EESD)with both high energy densities and power densities.Wide range of newly discovered materials with promising electrochemical properties has shown great potential for next-generation devices,but their performance is normally associated with contradicting demands of thin electrodes and high mass loading that can be hardly achieved for practical applications.Design of three-dimensional(3D)porous electrodes can increase the mass loading while maintaining the effective charge transport even with thick electrodes,which has proven to be efficient to overcome the limitations.3D structures have also been demonstrated excellent structural stability to withstand strong strains and stresses generated during charge/discharge cycle.3D printing,which can fabricate various delicate and complex structural designs,thus offering brand-new opportunities for the rational design and facile construction of next-generation EESDs.The recent developments in 3D printing of next-generation EESDs with high performance are reviewed.Advanced/multiscale electrode structures,such as hierarchically porous structure that can be constructed via high-resolution 3D printing or with post-treatment,are further emphasized.The ability of current 3D printing techniques to fulfill multimaterial printing to fulfill simple packaging will be covered.
基金supported by the Ministry of Science and Technology of China(Grant No.2019YFA0705600)the National Natural Science Foundation of China(Grant Nos.51822205,21875121)+2 种基金the Natural Science Foundation of Tianjin(Grant Nos.18JCJQJC46300,19JCZDJC31900)the Ministry of Education of China(Grant No.B12015)the “Frontiers Science Center for New Organic Matter”,Nankai University(Grant No.63181206)。
文摘The rapid development of micro-electronics raises the demand of their power sources to be simplified,miniaturized and highly integratable with other electronics on a chip.In-plane Micro-sized energy storage devices(MESDs),which are composed of interdigitated electrodes on a single chip,have aroused particular attentions since they could be easily integrated with other miniaturized electronics,reducing the complexity of overall chip design via removing complex interconnections with bulky power sources.This review highlights the achievements in the device fabrication of in-plane MESDs,as well as their integration and intelligent designs.We also discussed the current challenges and future perspectives for the development of in-plane MESDs.
基金the financial support from the National Natural Science Foundation of China(Grant Nos.51702095,51722503,51975204)Natural Science Foundation of Hunan Province,China(Grant No.2018JJ3041)+1 种基金the Fundamental Research Funds for the Central Universities(531118010016)Science and Technology Bureau Foundation of Changsha City(kh1904005)。
文摘The rapid progress of micro/nanoelectronic systems and miniaturized portable devices has tremendously increased the urgent demands for miniaturized and integrated power supplies.Miniaturized energy storage devices(MESDs),with their excellent properties and additional intelligent functions,are considered to be the preferable energy supplies for uninterrupted powering of microsystems.In this review,we aim to provide a comprehensive overview of the background,fundamentals,device configurations,manufacturing processes,and typical applications of MESDs,including their recent advances.Particular attention is paid to advanced device configurations,such as two-dimensional(2D)stacked,2D planar interdigital,2D arbitrary-shaped,three-dimensional planar,and wire-shaped structures,and their corresponding manufacturing strategies,such as printing,scribing,and masking techniques.Additionally,recent developments in MESDs,including microbatteries and microsupercapacitors,as well as microhybrid metal ion capacitors,are systematically summarized.A series of on-chip microsystems,created by integrating functional MESDs,are also highlighted.Finally,the remaining challenges and future research scope on MESDs are discussed.
基金the Engineering Research Center of Integrated Circuits for Next-Generation Communications Grant(Y01796303)Southern University of Science and Technology Grant(Y01796108,Y01796208).
文摘With the growing market of wearable devices for smart sensing and personalized healthcare applications,energy storage devices that ensure stable power supply and can be constructed in flexible platforms have attracted tremendous research interests.A variety of active materials and fabrication strategies of flexible energy storage devices have been intensively studied in recent years,especially for integrated self-powered systems and biosensing.A series of materials and applications for flexible energy storage devices have been studied in recent years.In this review,the commonly adopted fabrication methods of flexible energy storage devices are introduced.Besides,recent advances in integrating these energy devices into flexible self-powered systems are presented.Furthermore,the applications of flexible energy storage devices for biosensing are summarized.Finally,the prospects and challenges of the self-powered sensing system for wearable electronics are discussed.
基金the National Natural Science Foundation of China(NSFC Grant No.62174152).
文摘To prevent and mitigate environmental degradation,high-performance and cost-effective electrochemical flexible energy storage systems need to be urgently developed.This demand has led to an increase in research on electrode materials for high-capacity flexible supercapacitors and secondary batteries,which have greatly aided the development of contemporary digital communications and electric vehicles.The use of layered double hydroxides(LDHs)as electrode materials has shown productive results over the last decade,owing to their easy production,versatile composition,low cost,and excellent physicochemical features.This review highlights the distinctive 2D sheet-like structures and electrochemical characteristics of LDH materials,as well as current developments in their fabrication strategies for expanding the application scope of LDHs as electrode materials for flexible supercapacitors and alkali metal(Li,Na,K)ion batteries.
基金supports from the National Natural Science Foundation of China (Grant No. 52175300)Fundamental Research Funds for the Central Universities (2022FRFK060008)+2 种基金Heilongjiang Touyan Innovation Team Program (HITTY-20190013)Shenzhen Fundamental Research Programs (JCYJ20200925160843002)Start-up fund of SUSTech (Y01256114)
文摘Flexible electrochromic energy storage devices(FECESDs)for powering flexible electronics have attracted considerable attention.Silver nanowires(AgNWs)are one kind of the most promising flexible transparent electrodes(FTEs)materials for the emerging flexible devices.Currently,fabricating FECESD based on AgNWs FTEs is still hindered by their intrinsic poor electrochemical stability.To address this issue,a hybrid AgNWs/Co(OH)_(2)/PEDOT:PSS electrode is proposed.The PEDOT:PSS could not only improve the resistance against electrochemical corrosion of AgNWs,but also work as functional layer to realize the color-changing and energy storage properties.Moreover,the Co(OH)_(2)interlayer further improved the color-changing and energy storage performance.Based on the improvement,we assembled the symmetrical FECESDs.Under the same condition,the areal capacitance(0.8 mF cm^(−2))and coloration efficiency(269.80 cm^(2)C−1)of AgNWs/Co(OH)_(2)/PEDOT:PSS FECESDs were obviously higher than AgNWs/PEDOT:PSS FECESDs.Furthermore,the obtained FECESDs exhibited excellent stability against the mechanical deformation.The areal capacitance remained stable during 1000 times cyclic bending with a 25 mm curvature radius.These results demonstrated the broad application potential of the AgNWs/Co(OH)_(2)/PEDOT:PSS FECESD for the emerging portable and multifunctional electronics.
基金supported by the National Natural Science Foundation of China(21573116 and 21231005)Ministry of Education of China(B12015 and IRT13R30)Tianjin Basic and High-Tech Development(15JCYBJC17300)
文摘The booming developments in portable and wearable electronics promote the design of flexible energy storage systems. Flexible supercapacitors and batteries as promising energy storage devices have attracted tremendous attention. As the key component of both supercapacitors and batteries, electrode materials with excellent flexibility should be considered to match with highly flexible energy storage devices. Owing to large surface area, good thermal and chemical stability, high conductivity and mechanical flexibility,graphene-based materials have been widely employed to serve as promising electrodes of flexible energy storage devices. Considerable efforts have been devoted to the fabrication of flexible graphene-based electrodes through a variety of strategies. Moreover, different configurations of energy storage devices based on these active materials are designed. This review highlights flexible graphene-based two-dimensional film and one-dimensional fiber supercapacitors and various batteries including lithium-ion, lithium–sulfur and other batteries. The challenges and promising perspectives of the graphene-based materials for flexible energy storage devices are also discussed.
基金financially supported by the Natural Science Research Project in Universities of Anhui Province in China (No.K J2020A0727)the Key Discipline of Material Science and Engineering of Suzhou University (No.2017XJZDXK3)+2 种基金the Doctor of Suzhou University Scientific Research (No.2020BS014)the Graduate Research and Innovation Fund of Suzhou University (No.2021KYCX11)the platform of Suzhou University (No.2021XJPT16)。
文摘The research for three-dimension(3D)printing carbon and carbide energy storage devices has attracted widespread exploration interests.Being designable in structure and materials,graphene oxide(GO)and MXene accompanied with a direct ink writing exhibit a promising prospect for constructing high areal and volume energy density devices.This review not only summarizes the recent advances in 3D printing energy storage devices including printing methods,ink rheological properties,and different energy storage systems,but also discusses the printing methods related to energy storage.In addition,the binder or additive free of two-dimensional carbide materials is quite important for the present electrochemical energy storage devices,which also are presented.
基金the Basic Science Research Program(Nos.2021R1A2B5B03001615,2021M3H4A1A02099355,and 2021M3D1A2043791)through the National Research Foundation of Korea(NRF)grant by the Korean Government(MSIT).
文摘The rapid growth of miniaturized electronics has led to an urgent demand for microscale energy storage devices(MESDs)to sustainably power the micro electronic devices.However,most MESDs reported to date have suffered from the limited energy densities and shape versatility compared to conventional large-scale counterparts because of the architectural constraints inherent in microfabrication-based cell manufacturing and cell dimension/structure.This review addresses the cell architecture design for MESDs that can achieve both miniaturization and high energy density.We provide a comprehensive overview of five types of cell architectures of MESDs and their fabrication techniques.In addition,to enable practical applications of MESDs,several cell design approaches are presented with the aim of minimizing the inactive parts of the cell and maximizing the performance metrics of MESDs.Finally,we discuss development direction and outlook of MESDs with a focus on materials chemistry,energy-dense electrochemical systems,and cell performance normalization,which will help to expand their applications and manufacturing scalability.
基金We acknowledge financial support from the National Natural Science Foundation of China(21835003,21674050,91833304,21805136 and 61904084)the National Key Basic Research Program of China(2023YFB3608904,2017YFB0404501 and 2014CB648300)+8 种基金the Natural Science Foundation of Jiangsu Province(BK20210601,BE2019120 and BK20190737)Program for Jiangsu Specially-Appointed Professor(RK030STP15001)the Six Talent Peaks Project of Jiangsu Province(TD-XCL-009)the 333 Project of Jiangsu Province(BRA2017402),the NUPT"1311 Project"and Scientific Foundation(NY219159,NY218164 and NY219020)the Leading Talent of Technological Innovation of National Ten-Thousands Talents Program of China,the Excellent Scientific and Technological Innovative Teams of Jiangsu Higher Education Institutions(TJ217038)the Priority Academic Program Development of Jiangsu Higher Education Institutions(PAPD,YX030003)Special Fund of"Jiangsu Provincial High-level Innovative and Entrepreneurial Talents Introduction Program"(the first batch)in 2020(Doctoral Aggregation Program)(CZ030SC20016)China Postdoctoral Science Foundation(2021M691652)Jiangsu Province Postdoctoral Science Foundation(2021K323C).
文摘Stretchable power sources,especially stretchable lithium-ion batteries(LIBs),have attracted increasing attention due to their enormous prospects for powering flexible/wearable electronics.Despite recent advances,it is still challenging to develop ultra-stretchable LIBs that can withstand large deformation.In particular,stretchable LIBs require an elastic electrolyte as a basic component,while the conductivity of most elastic electrolytes drops sharply during deformation,especially during large deformations.This is why highly stretchable LIBs have not yet been realized until now.As a proof of concept,a super-stretchable LIB with strain up to 1200%is created based on an intrinsically super-stretchable polymer electrolyte as the lithium-ion conductor.The super-stretchable conductive system is constructed by an effective diblock copolymerization strategy via photocuring of vinyl functionalized 2-ureido-4-pyrimidone(VFUpy),an acrylic monomer containing succinonitrile and a lithium salt,achieving high ionic conductivity(3.5×10^(-4)mS cm^(-1)at room temperature(RT))and large deformation(the strain can reach 4560%).The acrylic elastomer containing Li-ion conductive domains can strongly increase the compatibility between the neighboring elastic networks,resulting in high ionic conductivity under ultra-large deformation,while VFUpy increases elasticity modulus(over three times)and electrochemical stability(voltage window reaches 5.3 V)of the prepared polymer conductor.At a strain of up to 1200%,the resulting stretchable LIBs are still sufficient to power LEDs.This study sheds light on the design and development of high-performance intrinsically super-stretchable materials for the advancement of highly elastic energy storage devices for powering flexible/wearable electronics that can endure large deformation.
基金supported by the National Natural Science Foundation of China(52372213,52172219 and 52025028)the Priority Academic Program Development(PAPD)of Jiangsu Higher Education Institutions
文摘The increasing popularity of the Internet of Things and the growing microelectronics market have led to a heightened demand for microscale energy storage devices,such as microbatteries and microsupercapacitors.Although lithium microbatteries have dominated the market,safety concerns arising from incidents like self-ignition and explosions have prompted a shift towards new microscale energy storage devices prioritizing high safety.Zinc-based micro-energy storage devices(ZMSDs),known for their high safety,low cost,and favorable electrochemical performance,are emerging as promising alternatives to lithium microbatteries.However,challenges persist in the fabrication of microelectrodes,electrolyte infusion,device packaging,and integration with microelectronics.Despite these challenges,significant progress has been made over the last decade.This review focuses on the challenges and recent advancements in zinc-based micro-energy storage,offering unique insights into their applications and paving the way for the commercial deployment of high-performance ZMSDs.
基金funded by the Youth Fund of Shandong Province Natural Science Foundation grant number ZR2020QE212Key Projects of Shandong Province Natural Science Foundation grant number ZR2020KF020+2 种基金the Guangdong Provincial Key Lab of Green Chemical Product Technology grant number GC 202111Zhejiang Province Natural Science Foundation grant number LY22E070007National Natural Science Foundation of China grant number 52007170.
文摘New energy storage devices such as batteries and supercapacitors are widely used in various fields because of their irreplaceable excellent characteristics.Because there are relatively few monitoring parameters and limited under-standing of their operation,they present problems in accurately predicting their state and controlling operation,such as state of charge,state of health,and early failure indicators.Poor monitoring can seriously affect the performance of energy storage devices.Therefore,to maximize the efficiency of new energy storage devices without damaging the equipment,it is important to make full use of sensing systems to accurately monitor important parameters such as voltage,current,temperature,and strain.These are highly related to their states.Hence,this paper reviews the sensing methods and divides them into two categories:embedded and non-embedded sensors.A variety of measurement methods used to measure the above parameters of various new energy storage devices such as batteries and super-capacitors are systematically summarized.The methods with different innovative points are listed,their advantages and disadvantages are summarized,and the application of optical fiber sensors is emphasized.Finally,the challenges and prospects for these studies are described.The intent is to encourage researchers in relevant fields to study the early warning of safety accidents from the root causes.
基金financial support from the National Natural Science Foundation of China(21878192 and 51904193)the Fundamental Research Funds for the Central Universities(YJ2021141)the Science and Technology Cooperation Special Fund of Sichuan University and Zigong City(2021CDZG-14)
文摘Efficient energy storage devices with suitable electrode materials,that integrate high power and high energy,are the crucial requisites of the renewable power source,which have unwrapped new possibilities in the sustainable development of energy and the environment.Herein,a facile collagen microstructure modulation strategy is proposed to construct a nitrogen/oxygen dual-doped hierarchically porous carbon fiber with ultrahigh specific surface area(2788 m^(2)g^(-1))and large pore volume(4.56 cm^(3)g^(-1))via local microfibrous breakage/disassembly of natural structured proteins.Combining operando spectroscopy and density functional theory unveil that the dual-heteroatom doping could effectively regulate the electronic structure of carbon atom framework with enhanced electric conductivity and electronegativity as well as decreased diffusion resistance in favor of rapid pseudocapacitive-dominated Li^(+)-storage(353 mAh g^(-1)at 10 A g^(-1)).Theoretical calculations reveal that the tailored micro-/mesoporous structures favor the rapid charge transfer and ion storage,synergistically realizing high capacity and superior rate performance for NPCF-H cathode(75.0 mAh g^(-1)at 30 A g^(-1)).The assembled device with NPCF-H as both anode and cathode achieves extremely high energy density(200 Wh kg^(-1))with maximum power density(42600 W kg^(-1))and ultralong lifespan(80%capacity retention over 10000 cycles).
基金This work was financially supported by the Agency for Science,Technology and Research(A*STAR)under its AME Programmatic Funding Scheme of CyberPhysiochemical Interfaces Programme(Project No.A18A1b0045)。
文摘Next-generation electronics that are fused into the human body can play a key role in future intelligent communication,smart healthcare,and human enhancement applications.As a promising energy supply component for smart biointegrated electronics,environment-adaptive electrochemical energy storage(EES)devices with complementary adaptability and functions have garnered huge interest in the past decade.Owing to the advancements in autonomous chemistry,which regulate the constitutional dynamic networks in materials,EES devices have witnessed higher freedom of autonomous adaptability in terms of mechano-adaptable,biocompatibility,and stimuli-response properties for biointegrated and smart applications.In this mini-review,we summarize the recent progress in emerging environmentadaptive EES devices enabled by the constitutional dynamic network of mechanical adaptable materials,biocompatible materials,and stimuli-responsive supramolecular polymer materials.Finally,the challenges and perspectives of autonomous chemistry on the environment-adaptive EES devices are discussed.
基金the National Natural Science Foundation of China(21875221,21890753,22162026,22225204,and U1967215)the National Key Research and Development Program of China(2016YFB0101202)+2 种基金the Youth Talent Support Program of High-Level Talents Special Support Plan in Henan Province(ZYQR201810148)Qiushi Scientific Research Initiation Plan of Zhengzhou University(32213243)the Distinguished Young Scholars Innovation Team of Zhengzhou University(32320275).
文摘The catalytic effect of electrode materials is one of the most crucial factors for achieving efficient electrochemical energy conversion and storage.Carbon-based metal composites were widely synthesized and employed as electrode materials because of their inherited outstanding properties.Usually,electrode materials can provide a higher capacity than the anticipated values,even beyond the theoretical limit.The origin of the extra capacity has not yet been explained accurately,and its formation mechanism is still ambiguous.Herein,we first summarized the current research progress and drawbacks in energy storage devices(ESDs),and elaborated the role of catalytic effect in enhancing the performance of ESDs as follows:promoting the evolution of the solid electrolyte interphase(SEI),accelerating the reversible conversion of discharge/charge products,and improving the conversion speed of the intermediate and the utilization rate of the active materials,thereby avoiding the shuttling effect.Additionally,a particular focus was placed on the interaction between the catalytic effect and energy storage performance in order to highlight the efficacy and role of the catalytic effect.We hope that this review could provide innovative ideas for designing the electrode materials with an efficient catalytic effect for ESDs to promote the development of this research field.
文摘Charging wearable energy storage devices with bioenergy from human-bodymotions, biofluids, and body heat holds great potential to construct self-powered body-worn electronics, especially considering the ceaseless nature ofhuman metabolic activities. To bridge the gap between human-body bioen-ergy and storage of energy, wearable triboelectric/piezoelectric nanogenerators(TENGs/PENGs), biofuel cells (BFCs), thermoelectric generators (TEGs) havebeen designed to harvest energy from body-motions, biofluids, and body heat,respectively. Researchers have explored various strategies using bioenergy har-vesters to charge wearable supercapacitors and batteries to relieve or even fullyeliminate the recharging process from external power stations, thus, makingwearable electronics more sustainable, autonomous, and user friendly. In thisarticle, we review the advances in the design of sustainable energy storagedevices charged by human-body energy harvesters. The progress in multifunc-tional wearable energy storage devices that cater to the easy integration withhuman-body energy harvesters will be summarized. Then, the focus is laid onthe integrating strategies (single-cell strategy and separated-cell strategy), devicedesign, materials selection, and characteristics of different self-charging human-body energy harvesting-storage systems. Finally, the challenges that impedethe wide application of human-body energy harvesters charged supercapaci-tors/batteries and prospects will be discussed both from materials and structuraldesign aspects.
文摘1 Results Electrochemical energy storage devices such as lithium-ion batteries[1-2] and double-layer capacitors[3-4] have attracted a great deal of attention because of their potential application to electric hybrid vehicles. They utilize nonaqueous electrolyte solutions comprising from organic solvents and lithium or quaternary ammonium salts with fluorine-containing anions. This is because the relatively large anions with electron-withdrawing atoms enable ionic dissociation in dipolar aprotic solvents...
基金supported by the National Natural Science Foundation of China (51822205 and 21875121)the Ministry of Science and Technology of China (2019YFA0705600 and 2017YFA0206701)+2 种基金the Natural Science Foundation of Tianjin (18JCJQJC46300 and 19JCZDJC31900)the Ministry of Education of China (B12015)China Postdoctoral Science Foundation (2019M650045)
文摘Although a great deal of studies focus on the design of flexible energy storage devices(ESDs),their mechanical behaviors under bending states are still not sufficiently investigated,and the understanding of the corresponding structural conversion therefore still lags behind.Here,we systematically and thoroughly investigated the mechanical behaviors of flexible all-in-one ESDs under bending deformation by the finite element method.The influences of thicknesses,Young’s moduli and Poisson’s ratios of electrodes and electrolyte were taken into account.Visualized and quantified results including displacement,strain energy,von Mises stress,and tensile,compressive,and interfacial shear stress are demonstrated and analyzed.Based on these results,significant conclusions are drawn for the design of flexible integrated ESDs with robust mechanical properties.This work will provide guidance for the design of ESDs with high flexibility.
