[Objective] The paper was to carry out ecological geochemical survey and ecological risk assessment on the heavy metals in latosol in western area of Hainan Island.[Method] The contents of six heavy metals including C...[Objective] The paper was to carry out ecological geochemical survey and ecological risk assessment on the heavy metals in latosol in western area of Hainan Island.[Method] The contents of six heavy metals including Cr,Cu,Zn,As,Cd and Pb in latosol in western area of Hainan Island were analyzed.Single-factor index method and Hakanson ecological risk index method were used to evaluate the integrated pollution effect of heavy metals in latosol.[Result] The average contents of Cr,Cu,Zn,As,Cd and Pb in latosol in western area of Hainan Island were 65.57,35.16,93.56,8.50,0.24 and 79.29 mg/kg,respectively.The major pollution factor of heavy metal was Pb.The sequence of influence factors of various heavy metals was PbCu = ZnCrAsCd.The potential ecological risk coefficient of various heavy metals was PbCdCuAsCrZn.The average value of potential ecological risk index（RI）was 45.14,belonging to low ecological risk range.[Conclusion] The heavy metal pollution in latosol in western area of Hainan Island belongs to slight pollution.展开更多
Modified potential ecological risk index （MRI） was proposed based on the potential ecological risk index （RI） and risk assessment code （RAC） by modifying an index. The modified index was relevant to the chemical...Modified potential ecological risk index （MRI） was proposed based on the potential ecological risk index （RI） and risk assessment code （RAC） by modifying an index. The modified index was relevant to the chemical speciation of heavy metals. Xiawan Port, a typical region contaminated by industrial production, was selected as a case study area. The total concentrations and chemical speciation of heavy metals in sediments of Xiawan Port were analyzed. The experimental data indicate that Xiawan Port is seriously polluted by heavy metals, especially by Cd. The risks of heavy metals are evaluated by RI, RAC and MRI, respectively. The resluts of MRI show that the risks of heavy metals are in the decreasing order of Cd〉Pb〉Cu〉Zn. Comparison of results by different methods reveals that MRI integrates the characters of RI and RAC. MRI is recognized to be useful for risk managemnt of heavy metals in sediments.展开更多
Artisanal gold mining,a labor-intensive and antiquated technique,is a growing industry and the source of income for rural communities all over the world.However,artisanal gold mining has potential negative and long-te...Artisanal gold mining,a labor-intensive and antiquated technique,is a growing industry and the source of income for rural communities all over the world.However,artisanal gold mining has potential negative and long-term effects on economy,environment,and society.This study collected soil samples from 16 sample points including a control point to examine the pollution degrees and spatial distribution of heavy metals,as well as ecological and health risks associated with heavy metal pollution in the Ijero-Ekiti mining site,Nigeria.Geographical Information System(GIS)and remote sensing technologies were used to identify regions with high concentrations of heavy metals and assess the environmental impact of gold mining activities.The results show that the mean heavy metal concentrations of 16 soil pointa are 8.94(±5.97)mg/kg for As,0.18(±0.54)mg/kg for Cd,0.11(±1.06)mg/kg for Co,14.32(±3.43)mg/kg for Cr,6.89(±0.64)mg/kg for Cu,48.92(±11.77)mg/kg for Fe,135.81(±30.75)mg/kg for Mn,5.92(±0.96)mg/kg for Ni,5.72(±1.66)mg/kg for Pb,and 13.94(±1.38)mg/kg for Zn.The study reveals that heavy metal concentration in soils follows the order of Mn>Fe>Cr>Zn>As>Cu>Ni>Pb>Co>Cd.An analysis of soil samples indicates that 3 principal components(PCs)account for 70.008%of the total variance and there are strong positive correlations between various pairs of heavy metals.The total potential ecological risk index(309.599)in the study area is high.Non-carcinogenic risk suggests that there may be long-term health impacts on people who work in the mining areas due to chronic exposure to the environment.Based on the study,the hazard index of carcinogenic health risks associated with heavy metals through ingestion is 520.00×10^(–4).Dermal contact from As and Cr also increases the risk of cancer,with the highest hazard index value of 18.40×10^(–4).The lowest exposure pathway,with the hazard index value of 0.68×10^(–4),indicates that the inhalation of heavy metals has a comparatively low risk of cancer.This study recommends the formulation of policies to monitor the Ijero-Ekiti mining site and other regions in Nigeria where indiscriminate artisanal gold mining activities exist.展开更多
The sources and ecological risk from sixteen polycyclic aromatic hydrocarbons in surface sediment in the Liaodong Bay were investigated from 2014 to 2015.The total concentrations of PAHs ranged from 88.5 to 347.1 ng/g...The sources and ecological risk from sixteen polycyclic aromatic hydrocarbons in surface sediment in the Liaodong Bay were investigated from 2014 to 2015.The total concentrations of PAHs ranged from 88.5 to 347.1 ng/g,and the high value occurred in the central region of the Liaodong Bay.Cluster analysis identified two site clusters representing the coastal region affected by land-based pollution and the central region of the Liaodong Bay.Principal component analysis-multiple linear regression and diagnostic ratios suggested that PAHs contaminants originated from a mixture of combustion and petroleum sources,and the major was combustion sources.Based on sediment quality guideline,naphthalene,acenaphthylene,acenaphthene,phenanthrene and dibenz[a,h]anthracene may occasionally cause adverse biological effects in some stations.The toxic equivalent concentrations of carcinogenic PAHs indicated low carcinogenic risk for the Liaodong Bay.The ecological risk and toxic pollution levels of PAHs were higher in the central region than in the coastal region along the Liaodong Bay.展开更多
The distribution of hexachloroeyclohexanes （HCHs） and dichlorodiphenyltrichloroethanes （DDTs） in the surface sea- water and sediment of Jincheng Bay mariculture area were investigated in the present study. The con...The distribution of hexachloroeyclohexanes （HCHs） and dichlorodiphenyltrichloroethanes （DDTs） in the surface sea- water and sediment of Jincheng Bay mariculture area were investigated in the present study. The concentration of total HCHs and DDTs ranged from 2.98 to 14.87ngL-l and were〈0.032ngL-1, respectively, in surface seawater, and ranged from 5.52 to 9.43 and from 4.11 to 6.72 ng g-l, respectively, in surface sediment. It was deduced from the composition profile of HCH isomers and DDT congeners that HCH residues derived from a mixture of technical-grade HCH and lindane whereas the DDT residues derived from technical-grade DDT and dicofol. Moreover, both HCH and DDT residues may mainly originate from historical inputs. The hazard quotient of α-HCH, β-HCH, γ-HCH and δ-HCH to marine species was 0.030, 0.157, 3.008 and 0.008, respectively. It was estimated that the overall probability of adverse biological effect from HCHs was less than 5%, indicating that its risk to seawater column spe- cies was low. The threshold effect concentration exceeding frequency of γ-HCH, p,p＇-DDD, p,p＇-DDE and p,p＇-DDT in sediment ranged from 8.3% to 100%, and the relative concentration of the HCH and DDT mixture exceeded their probable effect level in sediment. These findings indicated that the risk to marine benthos was high and potentially detrimental to the safety of aquatic prod- ucts, e.g., sea cucumber and benthic shellfish.展开更多
Surface soil/sediment samples were collected from the Water-Level Fluctuation Zone(WLFZ), cultivated land and forest land at 50 different grid points from Shenjia watershed, the Three Gorges Reservoir area in August 2...Surface soil/sediment samples were collected from the Water-Level Fluctuation Zone(WLFZ), cultivated land and forest land at 50 different grid points from Shenjia watershed, the Three Gorges Reservoir area in August 2013. The spatial distribution, sources and ecological risk assessment for Arsenic(As), Cadmium(Cd),Chromium(Cr), Copper(Cu), Nickel(Ni), Lead(Pb)and Zinc(Zn) were analyzed in this study. The results showed all tested metals had similar distribution patterns except Ni and Cr, with areas of high concentrations distributed in the southwest(WLFZ and watershed outlet) of the study area. Ni and Cr,which were highly positively correlated and present in high concentrations, were primarily distributed in the south and middle zones of the study area. Lower concentration areas of all metals were uniformly distributed west of the high-elevation zones and forest land. Factor analysis(FA) and factor analysismultiple linear regression(FA-MLR) showed that the major sources of Cd were fertilizer and traffic sources,which together accounted for 87% of Cd. As, Zn and Cu levels were primarily supplied by industrial and domestic sources, accounting for 76% of As, 75% of Cu and 67% of Zn. Surface soils/sediments of the study watershed contaminated by Cd represent a high ecological risk, whereas other metals represent low ecological risks. The potential ecological risk index(PERI) analysis indicated that it had a low(widerange) ecological risk and a moderate(small-range)ecological risk primarily distributed in the outlet of the study watershed. Fertilizers and traffic are the primary sources of Cd pollution, which should be more closely controlled for the purposes of water quality and ecological conservation.展开更多
The Luanchuan molybdenum polymetallic mine concentration area is rich in mineral resources and has a long history of mining.The environmental impact of long-term mining activities cannot be ignored.It is of great sign...The Luanchuan molybdenum polymetallic mine concentration area is rich in mineral resources and has a long history of mining.The environmental impact of long-term mining activities cannot be ignored.It is of great significance to study the ecological risk and the accumulation trends of heavy metals in the soil of mining areas for scientific prevention and control of heavy metal pollution.Taking the Taowanbeigou River Basin in the mine concentration area as the research object,the ecological pollution risk and cumulative effect of heavy metals in the soil of the basin were studied by using the comprehensive pollution index method,potential ecological risk assessment method and geoaccumulation index method.On this basis,the cumulative exceeding years of specific heavy metals were predicted by using the early warning model.The comprehensive potential ecological risk of heavy metals in the soil near the Luanchuan mine concentration area is moderate,and the single element Cd is the main ecological risk factor,with a contribution rate of 53.6%.The overall cumulative degrees of Cu and Pb in the soil are“none-moderate”,Zn and Cd are moderate,Mo has reached an extremely strong cumulative level,Hg,As and Cr risks are not obvious,and the overall cumulative risks order is Mo>Cd>Zn>Cu>Pb>Hg.According to the current accumulation rate and taking the risk screening values for soil contamination of agricultural land as the reference standard,the locations over standard rates of Cu,Zn and Cd will exceed 78%in 90years,and the over standard rate of Pb will reach approximately 57%in 200 years.The cumulative exceeding standard periods of As,Cr and Hg are generally long,which basically indicates that these elements do not pose a significant potential threat to the ecological environment.Mining activities will accelerate the accumulation of heavy metals in soil.With the continuous development of mining activities,the potential pollution risk of heavy metals in the soil of mining areas will also increase.展开更多
Predicted no-effect concentration （PNEC） is often used in ecological risk assessment to determine low-risk concentrations for chemicals. In the present study, the chronic data from native saltwater species were used...Predicted no-effect concentration （PNEC） is often used in ecological risk assessment to determine low-risk concentrations for chemicals. In the present study, the chronic data from native saltwater species were used to calculated PNEC values using four methods： log-normal distribution （ETX 2.0）, log-triangle distribution （US EPA＇s water quality criteria procedure）, burr III distribution （BurrliOZ） and traditional assessment fac-tor （AF）. The PNECs that were calculated using four methods ranged from 0.08 μg/L to 1.8 μg/L. Three of the SSD-derived PNECs range from 0.94 to 1.8 μg/L, about a factor of two apart. To demonstrate the use of SSD-based PNEC values and comprehensively estimate the regional ecological risk for cadmium in surface water of the Bohai Sea, in the Liaodong Bay, Bohai Bay, and Laizhou Bay, China, the dissolved cadmium con-centrations were measured and obtained 753 valid data covering 190 stations from July 2006 to November 2007. Based on three ecological risk assessment approaches, namely hazard quotient （HQ）, probabilistic risk quotient and joint probability curve （JPC）, the potential ecological risk of cadmium in surface water of the Liaodong Bay, Bohai Bay, and Laizahou Bay were estimated. Overall, the ecological risk of cadmium to aquatic ecosystem in the whole Bohai Sea was at acceptable ecological risk level, the order of ecological risk was Liaodong Bay〉Bohai Bay〉Laizhou Bay. However, more concerns should be paid to aquatic ecological risk in the Liaodong Bay which is the home of many steel, metallurgy and petrochemical industrial in China.展开更多
Desertification, soil salinization and grassland degradation are the major environmental hazards faced by the Gannan Plateau, northeastern Tibetan Plateau. Ecological risk assessment plays an important role in formula...Desertification, soil salinization and grassland degradation are the major environmental hazards faced by the Gannan Plateau, northeastern Tibetan Plateau. Ecological risk assessment plays an important role in formulating environmental management strategies yet little attention to this region. In this study, we established an ecological risk assessment index system based on 30 evaluation indices in the categories of hydrometeorology, ecological environment, ground surface disturbance, and society and economy for the Gannan Plateau. An entropy method was used to calculate an index weight,and subsequently the matter-element method was used together with extension theory to establish a matter-element extension model of ecological risk. We assessed the ecological risk in this region by calculating the degree of association between index layer, system layer and target layer, and the cumulative ecological risk index. The degrees of ecological risk for the counties of the region were determined by using Arc GIS which would represent a spatial heterogeneity of the risk grade in production. Our results showed that the areas of high ecological risk were in Zhouqu County and Zhuoni County, and others were of low risk(Hezuo City, Diebu County, Xiahe County and Lintan County) or intermediate risk(Maqu County). The results of the assessment were in accord with the actual observed situation. Thus, our ecological risk assessment index system is appropriate for this region and suggests that high risk counties need a priori ecological protection. Such research could provide a technological support which would potentially prevent or reduce disasters by establishing an ecological barrier to promote the sustainable development of Gannan Plateau.展开更多
The Songhua River,one of the seven major rivers in China,locates in Northeast China with 1897 km long.This study aims to investigate the concentrations,distribution,source apportionment and ecological risk assessment ...The Songhua River,one of the seven major rivers in China,locates in Northeast China with 1897 km long.This study aims to investigate the concentrations,distribution,source apportionment and ecological risk assessment of heavy metals including copper(Cu),zinc(Zn),cadmium(Cd),lead(Pb),nickel(Ni)and chromium(Cr)in main stream and tributaries of the Songhua River in Jilin Province,Northeast China.Surface sediment samples(0–15 cm)were collected from 39 sampling sites in the Songhua River in July 2012.Concentrations of Cu,Zn,Cd,Pb,Ni and Cr were analyzed.The mean concentrations of heavy metals were(24.0±9.2)mg/kg,(59.3±18.0)mg/kg,(4.0±2.1)mg/kg,(39.0±27.9)mg/kg,(18.5±8.6)mg/kg and(56.1±17.6)mg/kg for Cu,Zn,Cd,Pb,Cr and Ni,respectively.The average contents of Cu,Cd,Pb,Cr and Ni were higher than their background values.Higher concentrations of heavy metals were found in the lower reaches with industrial enterprises and cities along the Songhua River.Zn,Pb and Ni might come from industrial sewage and mineral processing,while Cu and Cd were derived from electroplating wastewater and agricultural non-point source sewage.Cr originated from lithogenic sources.The concentrations of Cu,Zn and Cr were below the effect range low(ERL)at all sites,while Cd,Pb and Ni concentrations were detected ranging from ERL to the effect range median(ERM)at more than 15%of samples.Concentrations of Ni exceeded ERM in more than 50%of samples.The mean toxic units of heavy metals in the Songhua River decreased following the order:Cd(6.7)>Pb(2.2)>Ni(1.6)>Cu(0.7)>Cr(0.5)=Zn(0.5).Potential ecological risk index was found to be higher in middle and lower reaches of the Songhua River,where Cd could impose an extremely high ecological risk.展开更多
In this study, the concentration and spatial distribution of potentially toxic metals(PTMs), including arsenic(As), cadmium(Cd), chromium(Cr), lead(Pb), copper(Cu), iron(Fe), manganese(Mn), and magnesium(Mg) in 23 wel...In this study, the concentration and spatial distribution of potentially toxic metals(PTMs), including arsenic(As), cadmium(Cd), chromium(Cr), lead(Pb), copper(Cu), iron(Fe), manganese(Mn), and magnesium(Mg) in 23 wells and drinking groundwater distribution networks of Rafsanjan, located in southeast Iran were evaluated. Moreover, the assessment of carcinogenic and non-carcinogenic risks was estimated by Monte Carlo simulation(MCS). The results showed that the concentrations of As and Pb in more than 99% and 23.46% of the study area, respectively, were higher than the maximum concentration level(10 μg/L). The mean concentration of other metals, including Cd, Cr, Cu, Fe, Mg, and Mn in all drinking water resources was within the WHO standard level. The mean hazard quotient(HQ) for As in the age group of children was 9.246 and adults 2.972, indicating high non-carcinogenic risk of As in the study area. The lifetime cancer risk(LTCR) of As was 1.36 E-3 for adults and 1.52 E-2 for children, indicating high non-carcinogenic risk of As. The level of HQ and LTCR for Pb in both age groups was in the acceptable range. The results of sensitivity analysis showed that the most effective variables were pollutant concentration and body weight(BW), respectively. Finally, it can be concluded that exposure to PTMs, especially As through drinking water in the study area can have significant effects on people’s health living in the area;therefore, it is necessary to treat and remove As from groundwater resources before drinking or using for domestic purpose.展开更多
Classical statistics,Inverse Distance Weighted and Hakasnson potential ecological index were used to study the distribution characteristics of 8 kinds of heavy metals( Cr,Ni,Cu,Zn,As,Cd,Pb and Hg) as well as their pot...Classical statistics,Inverse Distance Weighted and Hakasnson potential ecological index were used to study the distribution characteristics of 8 kinds of heavy metals( Cr,Ni,Cu,Zn,As,Cd,Pb and Hg) as well as their potential ecological risks in the topsoil( 0-20 cm) of cultivated land in Donghai County,a typical agricultural area along the Southeast Coast of China.The results showed that the average content of heavy metals in the cultivated soil of Donghai County was not over the risk screening values set in the Environmental Quality Standard for Soils.However,it was worth noting that in some of the sampling points,the content of Cr exceeded the risk screening value,and the standard exceeding points accounted for 24.74% of the total.In addition,the average content of Cr,Ni,As,Cd,Pb and Hg exceeded the soil background values of Jiangsu Province,and values for Cd,Cr and Pb were more than 1.5 times of the soil background value of Jiangsu Province.The heavy metals were at the medium integrated potential ecological risk level,and the potential ecological risk indices were high in the east and low in the west,and distributed in interlaced island shape.The potential ecological risk indices of the plains in the east were higher than those of the central gentle slope area and the western hillock area.The potential ecological risk was at a high level in Niushan Town which was situated the county center and in some regions with high urbanization levels.展开更多
At present, the methods widely applied to assess ecological risk of heavy metals are essentially single-point estimates in which exposure and toxicity data cannot be fully used and probabilities of adverse biological ...At present, the methods widely applied to assess ecological risk of heavy metals are essentially single-point estimates in which exposure and toxicity data cannot be fully used and probabilities of adverse biological effects cannot be achieved. In this study, based on investigation of concentrations of six heavy metals(As, Hg, Pb, Cd, Cu, and Zn) in the surface seawater and sediment near the outlet of a zinc factory, located in Huludao City, Liaoning Province, China, a tiered approach consisting of several probabilistic options was used to refi ne ecological risk assessment for the individuals. A mixture of various heavy metals was detected in the surface seawater, and potential ecological risk index(PERI) was adopted to assess the potential ecological risk of heavy metals in the surface sediment. The results from all levels of aquatic ecological risk assessment in the tiered framework, ranging from comparison of single effects and exposure values to the use of distribution-based Hazard Quotient obtained through Monte Carlo simulation, are consistent with each other. Briefl y, aquatic Zn and Cu posed a clear ecological risk, while Cd, Pb, Hg, and As in the water column posed potential risk. As expected, combined ecological risk of heavy metal mixture in the surface seawater was proved signifi cantly higher than the risk caused by any individual heavy metal, calculated using the concept of total equivalent concentration. According to PERI, the severity of pollution by the six heavy metals in the surface sediment decreased in the following sequence: Cd>Hg>As>Pb>Cu>Zn, and the total heavy metals in the sediment posed a very high risk to the marine environment. This study provides a useful mathematical framework for ecological risk assessment of heavy metals.展开更多
The structure of Pb,Zn,Cu and Cd in lead zinc ore tailing soils in Yongzhou,Hunan is analyzed by the optimized BCR sequential extraction procedure.The content and proportion of heavy metals of the mine are measured.Me...The structure of Pb,Zn,Cu and Cd in lead zinc ore tailing soils in Yongzhou,Hunan is analyzed by the optimized BCR sequential extraction procedure.The content and proportion of heavy metals of the mine are measured.Meanwhile,the ecological risks are evaluated with the Lars Hakanson＇s potential ecological risk exponential method.The analysis shows that the content of heavy metals is very high,reaching the level of serious pollution.The order of metal pollution degrees are Cd〉Pb〉Cu〉Zn.On the other hand,it is very possible that the heavy metals may combine together as compounds or cling to the crystal form of clay.Since the form of soluble acid and free metals are very little,it is not an easy job for metal elating or restoration of plants.Yet it is possible to take out those heavy metals adopting the chemical extraction technology.DTPA and EDTA,indicated by a research,both have iterative value and strong conformity effect.So they are effective elutriants to restore the polluted soil.A chemical extraction method is put forward in this paper.展开更多
Four different methods,namely mineralogical analysis,three-stage BCR sequential extraction procedure,dynamic leaching test and Hakanson Potential Ecological Risk Index Method were used to access the environmental acti...Four different methods,namely mineralogical analysis,three-stage BCR sequential extraction procedure,dynamic leaching test and Hakanson Potential Ecological Risk Index Method were used to access the environmental activity and potential ecological risks of heavy metals in zinc leaching residue.The results demonstrate that the environmental activity of heavy metals declines in the following order：CdZnCuAsPb.Potential ecological risk indices for single heavy metal are CdZnCuAsPb.Cd has serious potential ecological risk to the ecological environment and contributes most to the potential toxicity response indices for various heavy metals in the residue.展开更多
Wetland is a unique habitat with great biodiversity and important ecological functions between land and water on the earth. With the irrational utilization of wetland resources, the ecological destruction and pollutio...Wetland is a unique habitat with great biodiversity and important ecological functions between land and water on the earth. With the irrational utilization of wetland resources, the ecological destruction and pollution of wetland are becoming more and more serious. To evaluate the pollution of heavy metals in the sediments of Longjiang Wetland in Binzhou City, chromium(Cr), copper(Cu), zinc(Zn), cadmium(Cd) and lead(Pb) were measured by inductively coupled plasma mass spectrometry. Concentrations of Cr, Cu, Zn, Cd and Pb in the sediments were 5.3–13.6, 5.6–15.0, 16.6–33.0, 0.1–0.4 and 7.9–24.9 mg/kg dry weight, respectively. The concentrations of heavy metals in Longjiang Wetland was lower than soil background values of Shandong Province and in lower level compared with those reported in sediments/soils of wetlands in some other locations. Based on geo-accumulation index(Igeo), Cr, Cu, Zn and Pb showed low levels of contamination at all stations, while Cd was observed at a moderate pollution degree. Potential ecological risk factor(E_r^i) and risk index(RI) values showed low ecological risk of heavy metals in sediments of the wetland.展开更多
Using inductively coupled plasma mass spectrometry(ICP-MS)to detect the Pb content in the multi-phase medium(water,sediment and large benthic organisms)in the artificial reef areas of Bohai Bay in Tianjin to analysis ...Using inductively coupled plasma mass spectrometry(ICP-MS)to detect the Pb content in the multi-phase medium(water,sediment and large benthic organisms)in the artificial reef areas of Bohai Bay in Tianjin to analysis its spatial distribution characteristics and potential ecological risk.Using different evaluation methods.The results showed that:the Pb content is varied from 0.003-0.024μg/L,mean 0.008±0.007μg/L,the highest values appear in the No.9 station;the minimum value is 5 stations.Pb content of sediment is varied from 0.003-0.024μg/L,mean 0.008±0.007μg/L,the highest values appear in the No.9 station;the minimum value is 5 stations.The vertical sediment distribution of Pb decreased in the order:lower>middle>upper layer in each station.Risk evaluation showed that potential ecological risk index of Pb is low in the reef sediments;accumulate partial index is belong to moderate pollution levels;enrichment factor is belong to the light^pollution-free.Pb content of organisms is rang from 0.004-0.519 mg/kg,mean 0.185±0.170 mg/kg in reef area;BCF value of Pb content in organisms is generally higher than BAF value;its health risk factor is far less than 1,indicating that Pb has no obvious health risks on exposure population.展开更多
A general prediction model for seven heavy metals was established using the heavy metal contents of 207soil samples measured by a portable X-ray fluorescence spectrometer(XRF)and six environmental factors as model cor...A general prediction model for seven heavy metals was established using the heavy metal contents of 207soil samples measured by a portable X-ray fluorescence spectrometer(XRF)and six environmental factors as model correction coefficients.The eXtreme Gradient Boosting(XGBoost)model was used to fit the relationship between the content of heavy metals and environment characteristics to evaluate the soil ecological risk of the smelting site.The results demonstrated that the generalized prediction model developed for Pb,Cd,and As was highly accurate with fitted coefficients(R^(2))values of 0.911,0.950,and 0.835,respectively.Topsoil presented the highest ecological risk,and there existed high potential ecological risk at some positions with different depths due to high mobility of Cd.Generally,the application of machine learning significantly increased the accuracy of pXRF measurements,and identified key environmental factors.The adapted potential ecological risk assessment emphasized the need to focus on Pb,Cd,and As in future site remediation efforts.展开更多
Assessing and managing ecological risks in ecologically fragile areas remain challenging at present.To get to know the ecological risk situation in Turpan City,China,this study constructed an ecological risk evaluatio...Assessing and managing ecological risks in ecologically fragile areas remain challenging at present.To get to know the ecological risk situation in Turpan City,China,this study constructed an ecological risk evaluation system to obtain the ecological risk level(ERL)and ecological risk index(ERI)based on the multi-objective linear programming-patch generation land use simulation(MOP-PLUS)model,analyzed the changes in land use and ecological risk in Turpan City from 2000 to 2020,and predicted the land use and ecological risk in 2030 under four different scenarios(business as usual(BAU),rapid economic development(RED),ecological protection priority(EPP),and eco-economic equilibrium,(EEB)).The results showed that the conversion of land use from 2000 to 2030 was mainly between unused land and the other land use types.The ERL of unused land was the highest among all the land use types.The ecological risk increased sharply from 2000 to 2010 and then decreased from 2010 to 2020.According to the value of ERI,we divided the ecological risk into seven levels by natural breakpoint method;the higher the level,the higher the ecological risk.For the four scenarios in 2030,under the EPP scenario,the area at VII level was zero,while the area at VII level reached the largest under the RED scenario.Comparing with 2020,the areas at I and II levels increased under the BAU,EPP,and EEB scenarios,while decreased under the RED scenario.The spatial distributions of ecological risk of BAU and EEB scenarios were similar,but the areas at I and II levels were larger and the areas at V and VI levels were smaller under the EEB scenario than under the BAU scenario.Therefore,the EEB scenario was the optimal development route for Turpan City.In addition,the results of spatial autocorrelation showed that the large area of unused land was the main reason affecting the spatial pattern of ecological risk under different scenarios.According to Geodetector,the dominant driving factors of ecological risk were gross domestic product rating(GDPR),soil type,population,temperature,and distance from riverbed(DFRD).The interaction between driving factor pairs amplified their influence on ecological risk.This research would help explore the low ecological risk development path for urban construction in the future.展开更多
The economy of West African countries is mainly based on agriculture. However, the trace metal(loid)s contamination status in rivers is relatively unknown in the region. In this work, 45 surface sediments collected fr...The economy of West African countries is mainly based on agriculture. However, the trace metal(loid)s contamination status in rivers is relatively unknown in the region. In this work, 45 surface sediments collected from the Bandama, Comoé, and Bia Rivers in south and south eastern Côte d’Ivoire (West Africa), were analyzed for total metal concentrations and chemical speciation. The results showed that the river sediments were considerably contaminated by Cd and moderately contaminated by As, Cu, Pb, and Zn. Significant spatial variations were observed among the stations but not between the rivers. Metals Cd and Cu were likely to cause more ecological risks. The speciation analysis unravelled that the metal(loid)s partitioned mainly in the residual fraction, with the potential mobile fraction varying from 14% to 28%. The study calls for establishment of strict policies relative to the application of fertilizers and agrochemicals and mining activities to protect the environment and human health risks.展开更多
基金Supported by Natural Science Foundation of Hainan Province (40879)Educational Commission of Hunan Province of China (HJKJ2010-28)+1 种基金Scientific Research Foundation for Returned Scholars,Ministry of Education of ChinaCo-financing of Key Subjects"Cartography and Geographic Information System" and "Physical Geography"of Hainan Normal University~~
文摘[Objective] The paper was to carry out ecological geochemical survey and ecological risk assessment on the heavy metals in latosol in western area of Hainan Island.[Method] The contents of six heavy metals including Cr,Cu,Zn,As,Cd and Pb in latosol in western area of Hainan Island were analyzed.Single-factor index method and Hakanson ecological risk index method were used to evaluate the integrated pollution effect of heavy metals in latosol.[Result] The average contents of Cr,Cu,Zn,As,Cd and Pb in latosol in western area of Hainan Island were 65.57,35.16,93.56,8.50,0.24 and 79.29 mg/kg,respectively.The major pollution factor of heavy metal was Pb.The sequence of influence factors of various heavy metals was PbCu = ZnCrAsCd.The potential ecological risk coefficient of various heavy metals was PbCdCuAsCrZn.The average value of potential ecological risk index（RI）was 45.14,belonging to low ecological risk range.[Conclusion] The heavy metal pollution in latosol in western area of Hainan Island belongs to slight pollution.
基金Projects (51039001, 50978087, 51009063, 50808071) supported by the National Natural Science Foundation of ChinaProject (SX2010-026) supported by State Council Three Gorges Project Construction Committee Executive Office,China+2 种基金Project (2009ZX07212-001) supported by Ministry of Environmental Protection of ChinaProject (BYHGLC-2010-02) supported by Guangzhou Water Authority,ChinaProject (CX2010B157) supported by Hunan Provincial Innovation Foundation for Postgraduate,China
文摘Modified potential ecological risk index （MRI） was proposed based on the potential ecological risk index （RI） and risk assessment code （RAC） by modifying an index. The modified index was relevant to the chemical speciation of heavy metals. Xiawan Port, a typical region contaminated by industrial production, was selected as a case study area. The total concentrations and chemical speciation of heavy metals in sediments of Xiawan Port were analyzed. The experimental data indicate that Xiawan Port is seriously polluted by heavy metals, especially by Cd. The risks of heavy metals are evaluated by RI, RAC and MRI, respectively. The resluts of MRI show that the risks of heavy metals are in the decreasing order of Cd〉Pb〉Cu〉Zn. Comparison of results by different methods reveals that MRI integrates the characters of RI and RAC. MRI is recognized to be useful for risk managemnt of heavy metals in sediments.
文摘Artisanal gold mining,a labor-intensive and antiquated technique,is a growing industry and the source of income for rural communities all over the world.However,artisanal gold mining has potential negative and long-term effects on economy,environment,and society.This study collected soil samples from 16 sample points including a control point to examine the pollution degrees and spatial distribution of heavy metals,as well as ecological and health risks associated with heavy metal pollution in the Ijero-Ekiti mining site,Nigeria.Geographical Information System(GIS)and remote sensing technologies were used to identify regions with high concentrations of heavy metals and assess the environmental impact of gold mining activities.The results show that the mean heavy metal concentrations of 16 soil pointa are 8.94(±5.97)mg/kg for As,0.18(±0.54)mg/kg for Cd,0.11(±1.06)mg/kg for Co,14.32(±3.43)mg/kg for Cr,6.89(±0.64)mg/kg for Cu,48.92(±11.77)mg/kg for Fe,135.81(±30.75)mg/kg for Mn,5.92(±0.96)mg/kg for Ni,5.72(±1.66)mg/kg for Pb,and 13.94(±1.38)mg/kg for Zn.The study reveals that heavy metal concentration in soils follows the order of Mn>Fe>Cr>Zn>As>Cu>Ni>Pb>Co>Cd.An analysis of soil samples indicates that 3 principal components(PCs)account for 70.008%of the total variance and there are strong positive correlations between various pairs of heavy metals.The total potential ecological risk index(309.599)in the study area is high.Non-carcinogenic risk suggests that there may be long-term health impacts on people who work in the mining areas due to chronic exposure to the environment.Based on the study,the hazard index of carcinogenic health risks associated with heavy metals through ingestion is 520.00×10^(–4).Dermal contact from As and Cr also increases the risk of cancer,with the highest hazard index value of 18.40×10^(–4).The lowest exposure pathway,with the hazard index value of 0.68×10^(–4),indicates that the inhalation of heavy metals has a comparatively low risk of cancer.This study recommends the formulation of policies to monitor the Ijero-Ekiti mining site and other regions in Nigeria where indiscriminate artisanal gold mining activities exist.
基金The Liaoning Province Natural Science Foundation under contract No.201602409the Public Science and Technology Research Funds Projects of Ocean under contract No.201505019
文摘The sources and ecological risk from sixteen polycyclic aromatic hydrocarbons in surface sediment in the Liaodong Bay were investigated from 2014 to 2015.The total concentrations of PAHs ranged from 88.5 to 347.1 ng/g,and the high value occurred in the central region of the Liaodong Bay.Cluster analysis identified two site clusters representing the coastal region affected by land-based pollution and the central region of the Liaodong Bay.Principal component analysis-multiple linear regression and diagnostic ratios suggested that PAHs contaminants originated from a mixture of combustion and petroleum sources,and the major was combustion sources.Based on sediment quality guideline,naphthalene,acenaphthylene,acenaphthene,phenanthrene and dibenz[a,h]anthracene may occasionally cause adverse biological effects in some stations.The toxic equivalent concentrations of carcinogenic PAHs indicated low carcinogenic risk for the Liaodong Bay.The ecological risk and toxic pollution levels of PAHs were higher in the central region than in the coastal region along the Liaodong Bay.
基金supported by the Marine Special Scientific Fund for the Non-profit Public Industry of China (200805031)Fund of Key Laboratory of Fishery Ecology and Environment, Guangdong Province (LFE-20144)Scientific Research Foundation for the Third Institute of Oceanography, State Oceanic Administration (No. 2013031)
文摘The distribution of hexachloroeyclohexanes （HCHs） and dichlorodiphenyltrichloroethanes （DDTs） in the surface sea- water and sediment of Jincheng Bay mariculture area were investigated in the present study. The concentration of total HCHs and DDTs ranged from 2.98 to 14.87ngL-l and were〈0.032ngL-1, respectively, in surface seawater, and ranged from 5.52 to 9.43 and from 4.11 to 6.72 ng g-l, respectively, in surface sediment. It was deduced from the composition profile of HCH isomers and DDT congeners that HCH residues derived from a mixture of technical-grade HCH and lindane whereas the DDT residues derived from technical-grade DDT and dicofol. Moreover, both HCH and DDT residues may mainly originate from historical inputs. The hazard quotient of α-HCH, β-HCH, γ-HCH and δ-HCH to marine species was 0.030, 0.157, 3.008 and 0.008, respectively. It was estimated that the overall probability of adverse biological effect from HCHs was less than 5%, indicating that its risk to seawater column spe- cies was low. The threshold effect concentration exceeding frequency of γ-HCH, p,p＇-DDD, p,p＇-DDE and p,p＇-DDT in sediment ranged from 8.3% to 100%, and the relative concentration of the HCH and DDT mixture exceeded their probable effect level in sediment. These findings indicated that the risk to marine benthos was high and potentially detrimental to the safety of aquatic prod- ucts, e.g., sea cucumber and benthic shellfish.
基金Financial support for this study was jointly provided by the National Natural Science Foundation of China(Grant No.41430750)National Key Basic Research Program of China(Grant Nos.2015CB452704,2016YFC0402301)the Chinese Academy of Sciences(Grant Nos.KFJ-EW-STS-008,KFJSW-STS-175)
文摘Surface soil/sediment samples were collected from the Water-Level Fluctuation Zone(WLFZ), cultivated land and forest land at 50 different grid points from Shenjia watershed, the Three Gorges Reservoir area in August 2013. The spatial distribution, sources and ecological risk assessment for Arsenic(As), Cadmium(Cd),Chromium(Cr), Copper(Cu), Nickel(Ni), Lead(Pb)and Zinc(Zn) were analyzed in this study. The results showed all tested metals had similar distribution patterns except Ni and Cr, with areas of high concentrations distributed in the southwest(WLFZ and watershed outlet) of the study area. Ni and Cr,which were highly positively correlated and present in high concentrations, were primarily distributed in the south and middle zones of the study area. Lower concentration areas of all metals were uniformly distributed west of the high-elevation zones and forest land. Factor analysis(FA) and factor analysismultiple linear regression(FA-MLR) showed that the major sources of Cd were fertilizer and traffic sources,which together accounted for 87% of Cd. As, Zn and Cu levels were primarily supplied by industrial and domestic sources, accounting for 76% of As, 75% of Cu and 67% of Zn. Surface soils/sediments of the study watershed contaminated by Cd represent a high ecological risk, whereas other metals represent low ecological risks. The potential ecological risk index(PERI) analysis indicated that it had a low(widerange) ecological risk and a moderate(small-range)ecological risk primarily distributed in the outlet of the study watershed. Fertilizers and traffic are the primary sources of Cd pollution, which should be more closely controlled for the purposes of water quality and ecological conservation.
基金supported by the Science and Technology Research Project to Henan Provincial Department of Natural Resources(Henan Natural Resources Letter[2019]373–10)。
文摘The Luanchuan molybdenum polymetallic mine concentration area is rich in mineral resources and has a long history of mining.The environmental impact of long-term mining activities cannot be ignored.It is of great significance to study the ecological risk and the accumulation trends of heavy metals in the soil of mining areas for scientific prevention and control of heavy metal pollution.Taking the Taowanbeigou River Basin in the mine concentration area as the research object,the ecological pollution risk and cumulative effect of heavy metals in the soil of the basin were studied by using the comprehensive pollution index method,potential ecological risk assessment method and geoaccumulation index method.On this basis,the cumulative exceeding years of specific heavy metals were predicted by using the early warning model.The comprehensive potential ecological risk of heavy metals in the soil near the Luanchuan mine concentration area is moderate,and the single element Cd is the main ecological risk factor,with a contribution rate of 53.6%.The overall cumulative degrees of Cu and Pb in the soil are“none-moderate”,Zn and Cd are moderate,Mo has reached an extremely strong cumulative level,Hg,As and Cr risks are not obvious,and the overall cumulative risks order is Mo>Cd>Zn>Cu>Pb>Hg.According to the current accumulation rate and taking the risk screening values for soil contamination of agricultural land as the reference standard,the locations over standard rates of Cu,Zn and Cd will exceed 78%in 90years,and the over standard rate of Pb will reach approximately 57%in 200 years.The cumulative exceeding standard periods of As,Cr and Hg are generally long,which basically indicates that these elements do not pose a significant potential threat to the ecological environment.Mining activities will accelerate the accumulation of heavy metals in soil.With the continuous development of mining activities,the potential pollution risk of heavy metals in the soil of mining areas will also increase.
基金The National Natural Science Foundation of China under contract No.41106089the National Key Technology Research and Development Program of the Ministry of Science and Technology of China under contract No.2010BAC69B01the Scientific Research Special Fund of Marine Public Welfare Industry under contract No.201005008-1
文摘Predicted no-effect concentration （PNEC） is often used in ecological risk assessment to determine low-risk concentrations for chemicals. In the present study, the chronic data from native saltwater species were used to calculated PNEC values using four methods： log-normal distribution （ETX 2.0）, log-triangle distribution （US EPA＇s water quality criteria procedure）, burr III distribution （BurrliOZ） and traditional assessment fac-tor （AF）. The PNECs that were calculated using four methods ranged from 0.08 μg/L to 1.8 μg/L. Three of the SSD-derived PNECs range from 0.94 to 1.8 μg/L, about a factor of two apart. To demonstrate the use of SSD-based PNEC values and comprehensively estimate the regional ecological risk for cadmium in surface water of the Bohai Sea, in the Liaodong Bay, Bohai Bay, and Laizhou Bay, China, the dissolved cadmium con-centrations were measured and obtained 753 valid data covering 190 stations from July 2006 to November 2007. Based on three ecological risk assessment approaches, namely hazard quotient （HQ）, probabilistic risk quotient and joint probability curve （JPC）, the potential ecological risk of cadmium in surface water of the Liaodong Bay, Bohai Bay, and Laizahou Bay were estimated. Overall, the ecological risk of cadmium to aquatic ecosystem in the whole Bohai Sea was at acceptable ecological risk level, the order of ecological risk was Liaodong Bay〉Bohai Bay〉Laizhou Bay. However, more concerns should be paid to aquatic ecological risk in the Liaodong Bay which is the home of many steel, metallurgy and petrochemical industrial in China.
基金supported by the Soft Science Project of Gansu province(1504ZKCA090-1)the National Natural Science Foundation of china(grant nos.41671516,41701623,51369003)+2 种基金the Foundation for Excellent Youth Scholars of NIEER,CAS,National Natural Science Foundation of China(Grant No.41661144046)supported by the Special Foundation for Gansu Province International Scientific Cooperation(1604WKCA002)the Fundamental Research Funds for the Central Universities(lzujbky-2015-K10,lzujbky-2016-862516,lzujbky-2017-it90)
文摘Desertification, soil salinization and grassland degradation are the major environmental hazards faced by the Gannan Plateau, northeastern Tibetan Plateau. Ecological risk assessment plays an important role in formulating environmental management strategies yet little attention to this region. In this study, we established an ecological risk assessment index system based on 30 evaluation indices in the categories of hydrometeorology, ecological environment, ground surface disturbance, and society and economy for the Gannan Plateau. An entropy method was used to calculate an index weight,and subsequently the matter-element method was used together with extension theory to establish a matter-element extension model of ecological risk. We assessed the ecological risk in this region by calculating the degree of association between index layer, system layer and target layer, and the cumulative ecological risk index. The degrees of ecological risk for the counties of the region were determined by using Arc GIS which would represent a spatial heterogeneity of the risk grade in production. Our results showed that the areas of high ecological risk were in Zhouqu County and Zhuoni County, and others were of low risk(Hezuo City, Diebu County, Xiahe County and Lintan County) or intermediate risk(Maqu County). The results of the assessment were in accord with the actual observed situation. Thus, our ecological risk assessment index system is appropriate for this region and suggests that high risk counties need a priori ecological protection. Such research could provide a technological support which would potentially prevent or reduce disasters by establishing an ecological barrier to promote the sustainable development of Gannan Plateau.
基金Under the auspices of the National Natural Science Foundation of China(No.42077343)the Major Science and Technology Program for Water Pollution Control and Treatment in China(No.2009ZX07207-001-03)+1 种基金the Science and Technology Development Program of Jilin Province(No.20200403020SF)the Natural Science Foundation of Changchun Normal University(No.2019009)。
文摘The Songhua River,one of the seven major rivers in China,locates in Northeast China with 1897 km long.This study aims to investigate the concentrations,distribution,source apportionment and ecological risk assessment of heavy metals including copper(Cu),zinc(Zn),cadmium(Cd),lead(Pb),nickel(Ni)and chromium(Cr)in main stream and tributaries of the Songhua River in Jilin Province,Northeast China.Surface sediment samples(0–15 cm)were collected from 39 sampling sites in the Songhua River in July 2012.Concentrations of Cu,Zn,Cd,Pb,Ni and Cr were analyzed.The mean concentrations of heavy metals were(24.0±9.2)mg/kg,(59.3±18.0)mg/kg,(4.0±2.1)mg/kg,(39.0±27.9)mg/kg,(18.5±8.6)mg/kg and(56.1±17.6)mg/kg for Cu,Zn,Cd,Pb,Cr and Ni,respectively.The average contents of Cu,Cd,Pb,Cr and Ni were higher than their background values.Higher concentrations of heavy metals were found in the lower reaches with industrial enterprises and cities along the Songhua River.Zn,Pb and Ni might come from industrial sewage and mineral processing,while Cu and Cd were derived from electroplating wastewater and agricultural non-point source sewage.Cr originated from lithogenic sources.The concentrations of Cu,Zn and Cr were below the effect range low(ERL)at all sites,while Cd,Pb and Ni concentrations were detected ranging from ERL to the effect range median(ERM)at more than 15%of samples.Concentrations of Ni exceeded ERM in more than 50%of samples.The mean toxic units of heavy metals in the Songhua River decreased following the order:Cd(6.7)>Pb(2.2)>Ni(1.6)>Cu(0.7)>Cr(0.5)=Zn(0.5).Potential ecological risk index was found to be higher in middle and lower reaches of the Songhua River,where Cd could impose an extremely high ecological risk.
基金the result of a research project with code 97361 approved by the Workplace Research Center of Rafsanjan University of Medical Sciences with the ethics code IR.RUMS.REC.1398.021 from the Vice Chancellor for Research of Rafsanjan University of Medical Sciencesowed to Rafsanjan University of Medical Sciences for its supports。
文摘In this study, the concentration and spatial distribution of potentially toxic metals(PTMs), including arsenic(As), cadmium(Cd), chromium(Cr), lead(Pb), copper(Cu), iron(Fe), manganese(Mn), and magnesium(Mg) in 23 wells and drinking groundwater distribution networks of Rafsanjan, located in southeast Iran were evaluated. Moreover, the assessment of carcinogenic and non-carcinogenic risks was estimated by Monte Carlo simulation(MCS). The results showed that the concentrations of As and Pb in more than 99% and 23.46% of the study area, respectively, were higher than the maximum concentration level(10 μg/L). The mean concentration of other metals, including Cd, Cr, Cu, Fe, Mg, and Mn in all drinking water resources was within the WHO standard level. The mean hazard quotient(HQ) for As in the age group of children was 9.246 and adults 2.972, indicating high non-carcinogenic risk of As in the study area. The lifetime cancer risk(LTCR) of As was 1.36 E-3 for adults and 1.52 E-2 for children, indicating high non-carcinogenic risk of As. The level of HQ and LTCR for Pb in both age groups was in the acceptable range. The results of sensitivity analysis showed that the most effective variables were pollutant concentration and body weight(BW), respectively. Finally, it can be concluded that exposure to PTMs, especially As through drinking water in the study area can have significant effects on people’s health living in the area;therefore, it is necessary to treat and remove As from groundwater resources before drinking or using for domestic purpose.
文摘Classical statistics,Inverse Distance Weighted and Hakasnson potential ecological index were used to study the distribution characteristics of 8 kinds of heavy metals( Cr,Ni,Cu,Zn,As,Cd,Pb and Hg) as well as their potential ecological risks in the topsoil( 0-20 cm) of cultivated land in Donghai County,a typical agricultural area along the Southeast Coast of China.The results showed that the average content of heavy metals in the cultivated soil of Donghai County was not over the risk screening values set in the Environmental Quality Standard for Soils.However,it was worth noting that in some of the sampling points,the content of Cr exceeded the risk screening value,and the standard exceeding points accounted for 24.74% of the total.In addition,the average content of Cr,Ni,As,Cd,Pb and Hg exceeded the soil background values of Jiangsu Province,and values for Cd,Cr and Pb were more than 1.5 times of the soil background value of Jiangsu Province.The heavy metals were at the medium integrated potential ecological risk level,and the potential ecological risk indices were high in the east and low in the west,and distributed in interlaced island shape.The potential ecological risk indices of the plains in the east were higher than those of the central gentle slope area and the western hillock area.The potential ecological risk was at a high level in Niushan Town which was situated the county center and in some regions with high urbanization levels.
基金Supported by the Science and Technology Project of North China Sea Branch of State Oceanic Administration(No.2014B02)
文摘At present, the methods widely applied to assess ecological risk of heavy metals are essentially single-point estimates in which exposure and toxicity data cannot be fully used and probabilities of adverse biological effects cannot be achieved. In this study, based on investigation of concentrations of six heavy metals(As, Hg, Pb, Cd, Cu, and Zn) in the surface seawater and sediment near the outlet of a zinc factory, located in Huludao City, Liaoning Province, China, a tiered approach consisting of several probabilistic options was used to refi ne ecological risk assessment for the individuals. A mixture of various heavy metals was detected in the surface seawater, and potential ecological risk index(PERI) was adopted to assess the potential ecological risk of heavy metals in the surface sediment. The results from all levels of aquatic ecological risk assessment in the tiered framework, ranging from comparison of single effects and exposure values to the use of distribution-based Hazard Quotient obtained through Monte Carlo simulation, are consistent with each other. Briefl y, aquatic Zn and Cu posed a clear ecological risk, while Cd, Pb, Hg, and As in the water column posed potential risk. As expected, combined ecological risk of heavy metal mixture in the surface seawater was proved signifi cantly higher than the risk caused by any individual heavy metal, calculated using the concept of total equivalent concentration. According to PERI, the severity of pollution by the six heavy metals in the surface sediment decreased in the following sequence: Cd>Hg>As>Pb>Cu>Zn, and the total heavy metals in the sediment posed a very high risk to the marine environment. This study provides a useful mathematical framework for ecological risk assessment of heavy metals.
基金This work is supported by Chinese National Programs for High Technology Research and Development （Grant No. 2001AA644020）；Natural Science Foundation of Hunan Province （Grant No. 04JJ3013）.
文摘The structure of Pb,Zn,Cu and Cd in lead zinc ore tailing soils in Yongzhou,Hunan is analyzed by the optimized BCR sequential extraction procedure.The content and proportion of heavy metals of the mine are measured.Meanwhile,the ecological risks are evaluated with the Lars Hakanson＇s potential ecological risk exponential method.The analysis shows that the content of heavy metals is very high,reaching the level of serious pollution.The order of metal pollution degrees are Cd〉Pb〉Cu〉Zn.On the other hand,it is very possible that the heavy metals may combine together as compounds or cling to the crystal form of clay.Since the form of soluble acid and free metals are very little,it is not an easy job for metal elating or restoration of plants.Yet it is possible to take out those heavy metals adopting the chemical extraction technology.DTPA and EDTA,indicated by a research,both have iterative value and strong conformity effect.So they are effective elutriants to restore the polluted soil.A chemical extraction method is put forward in this paper.
基金Project(50925417) supported by the National Natural Science Funds for Distinguished Young Scholar of ChinaProject(2010AA065203) supported by the High Technology Research and Development Program of China+2 种基金Project(2010-609) Supported by the Scientific Research Foundation for the Returned Overseas Chinese Scholars,Ministry of Education,ChinaProject(ncet-10-0840) supported by Program for New Century Excellent Talents in UniversityProject(2012FJ1080) supported by Key Projects of Science and Technology of Hunan Province,China
文摘Four different methods,namely mineralogical analysis,three-stage BCR sequential extraction procedure,dynamic leaching test and Hakanson Potential Ecological Risk Index Method were used to access the environmental activity and potential ecological risks of heavy metals in zinc leaching residue.The results demonstrate that the environmental activity of heavy metals declines in the following order：CdZnCuAsPb.Potential ecological risk indices for single heavy metal are CdZnCuAsPb.Cd has serious potential ecological risk to the ecological environment and contributes most to the potential toxicity response indices for various heavy metals in the residue.
基金Sponsored by the Natural Science Foundation of Shandong Province(ZR2018PD002)
文摘Wetland is a unique habitat with great biodiversity and important ecological functions between land and water on the earth. With the irrational utilization of wetland resources, the ecological destruction and pollution of wetland are becoming more and more serious. To evaluate the pollution of heavy metals in the sediments of Longjiang Wetland in Binzhou City, chromium(Cr), copper(Cu), zinc(Zn), cadmium(Cd) and lead(Pb) were measured by inductively coupled plasma mass spectrometry. Concentrations of Cr, Cu, Zn, Cd and Pb in the sediments were 5.3–13.6, 5.6–15.0, 16.6–33.0, 0.1–0.4 and 7.9–24.9 mg/kg dry weight, respectively. The concentrations of heavy metals in Longjiang Wetland was lower than soil background values of Shandong Province and in lower level compared with those reported in sediments/soils of wetlands in some other locations. Based on geo-accumulation index(Igeo), Cr, Cu, Zn and Pb showed low levels of contamination at all stations, while Cd was observed at a moderate pollution degree. Potential ecological risk factor(E_r^i) and risk index(RI) values showed low ecological risk of heavy metals in sediments of the wetland.
基金supported by the following funds,Monitoring and evaluation of Marine fishery resources restoration,proliferation and discharge in the 100 000 tons roadway project of Dagang port area of Tianjin portMarine fishery resources restoration of Tianjin liquefied natural gas (LNG) project+1 种基金Youth science and technology innovation project of Tianjin municipal bureau of aquatic industry (J-2014-08)Tianjin agricultural science and technology achievements transformation and promotion project (201304150)
文摘Using inductively coupled plasma mass spectrometry(ICP-MS)to detect the Pb content in the multi-phase medium(water,sediment and large benthic organisms)in the artificial reef areas of Bohai Bay in Tianjin to analysis its spatial distribution characteristics and potential ecological risk.Using different evaluation methods.The results showed that:the Pb content is varied from 0.003-0.024μg/L,mean 0.008±0.007μg/L,the highest values appear in the No.9 station;the minimum value is 5 stations.Pb content of sediment is varied from 0.003-0.024μg/L,mean 0.008±0.007μg/L,the highest values appear in the No.9 station;the minimum value is 5 stations.The vertical sediment distribution of Pb decreased in the order:lower>middle>upper layer in each station.Risk evaluation showed that potential ecological risk index of Pb is low in the reef sediments;accumulate partial index is belong to moderate pollution levels;enrichment factor is belong to the light^pollution-free.Pb content of organisms is rang from 0.004-0.519 mg/kg,mean 0.185±0.170 mg/kg in reef area;BCF value of Pb content in organisms is generally higher than BAF value;its health risk factor is far less than 1,indicating that Pb has no obvious health risks on exposure population.
基金financially supported from the National Key Research and Development Program of China(No.2019YFC1803601)the Fundamental Research Funds for the Central Universities of Central South University,China(No.2023ZZTS0801)+1 种基金the Postgraduate Innovative Project of Central South University,China(No.2023XQLH068)the Postgraduate Scientific Research Innovation Project of Hunan Province,China(No.QL20230054)。
文摘A general prediction model for seven heavy metals was established using the heavy metal contents of 207soil samples measured by a portable X-ray fluorescence spectrometer(XRF)and six environmental factors as model correction coefficients.The eXtreme Gradient Boosting(XGBoost)model was used to fit the relationship between the content of heavy metals and environment characteristics to evaluate the soil ecological risk of the smelting site.The results demonstrated that the generalized prediction model developed for Pb,Cd,and As was highly accurate with fitted coefficients(R^(2))values of 0.911,0.950,and 0.835,respectively.Topsoil presented the highest ecological risk,and there existed high potential ecological risk at some positions with different depths due to high mobility of Cd.Generally,the application of machine learning significantly increased the accuracy of pXRF measurements,and identified key environmental factors.The adapted potential ecological risk assessment emphasized the need to focus on Pb,Cd,and As in future site remediation efforts.
基金financed by the Third Comprehensive Scientific Survey Project of Xinjiang(2021xjkk1003)the Youth Innovation and Cultivation Talent Project of Shihezi University(CXFZ202201,CXPY202201)+1 种基金the Annual Youth Doctoral Program of Xinjiang Uygur Autonomous Region'Tianchi Elite'Introduction Plan(CZ002302,CZ002305)the High Level Talent Research Launch Project of Shihezi University(RCZK202316,RCZK202321).
文摘Assessing and managing ecological risks in ecologically fragile areas remain challenging at present.To get to know the ecological risk situation in Turpan City,China,this study constructed an ecological risk evaluation system to obtain the ecological risk level(ERL)and ecological risk index(ERI)based on the multi-objective linear programming-patch generation land use simulation(MOP-PLUS)model,analyzed the changes in land use and ecological risk in Turpan City from 2000 to 2020,and predicted the land use and ecological risk in 2030 under four different scenarios(business as usual(BAU),rapid economic development(RED),ecological protection priority(EPP),and eco-economic equilibrium,(EEB)).The results showed that the conversion of land use from 2000 to 2030 was mainly between unused land and the other land use types.The ERL of unused land was the highest among all the land use types.The ecological risk increased sharply from 2000 to 2010 and then decreased from 2010 to 2020.According to the value of ERI,we divided the ecological risk into seven levels by natural breakpoint method;the higher the level,the higher the ecological risk.For the four scenarios in 2030,under the EPP scenario,the area at VII level was zero,while the area at VII level reached the largest under the RED scenario.Comparing with 2020,the areas at I and II levels increased under the BAU,EPP,and EEB scenarios,while decreased under the RED scenario.The spatial distributions of ecological risk of BAU and EEB scenarios were similar,but the areas at I and II levels were larger and the areas at V and VI levels were smaller under the EEB scenario than under the BAU scenario.Therefore,the EEB scenario was the optimal development route for Turpan City.In addition,the results of spatial autocorrelation showed that the large area of unused land was the main reason affecting the spatial pattern of ecological risk under different scenarios.According to Geodetector,the dominant driving factors of ecological risk were gross domestic product rating(GDPR),soil type,population,temperature,and distance from riverbed(DFRD).The interaction between driving factor pairs amplified their influence on ecological risk.This research would help explore the low ecological risk development path for urban construction in the future.
文摘The economy of West African countries is mainly based on agriculture. However, the trace metal(loid)s contamination status in rivers is relatively unknown in the region. In this work, 45 surface sediments collected from the Bandama, Comoé, and Bia Rivers in south and south eastern Côte d’Ivoire (West Africa), were analyzed for total metal concentrations and chemical speciation. The results showed that the river sediments were considerably contaminated by Cd and moderately contaminated by As, Cu, Pb, and Zn. Significant spatial variations were observed among the stations but not between the rivers. Metals Cd and Cu were likely to cause more ecological risks. The speciation analysis unravelled that the metal(loid)s partitioned mainly in the residual fraction, with the potential mobile fraction varying from 14% to 28%. The study calls for establishment of strict policies relative to the application of fertilizers and agrochemicals and mining activities to protect the environment and human health risks.
