This research was carried out to identify the most effective plant species for air purification based on environmental factors. The existence of plants beside roadways can be considered a more efficient approach to im...This research was carried out to identify the most effective plant species for air purification based on environmental factors. The existence of plants beside roadways can be considered a more efficient approach to improving air quality and minimizing pollution exposure. The samples for this research were collected from various sites across the streets of Jeddah governorate. The primary sources of air pollution in the research area are vehicle traffic and emissions from cars. Eight species were gathered from various streets in Jeddah governorate, namely, Azadirachta indica, Senna sulfurea, Ziziphus spina-christi, Cordia sebestena, Tecoma stans, Bougainvillea spectabilis, Conocarpus lancifolius, and Ixora coccinea. The leaves of the studied plants were analyzed for secondary compounds using Gas chromatography-mass spectrometry (GC-MS) techniques. Gas-chromatographic analyses revealed that bis (2-ethylhexyl) phthalate was found in every plant. Bis-(2-ethylhexyl) phthalate, a widespread environmental pollutant. Moreover, Cordia sebestena was the sole plant that contained Phenol, 2,2’-methylenebis [6-(1,1-dimethylethyl)-4-methyl] which is part of the phenols category. Environmental conditions can affect the production of secondary metabolites. By tracking the concentrations of these substances, researchers can evaluate the well-being of ecosystems and identify pollution.展开更多
The hazard produced by natural phenomena on infrastructure and urban populations has been widely studied in the last 50 years. Researchers have recognised that the real danger posed by these phenomena depends on their...The hazard produced by natural phenomena on infrastructure and urban populations has been widely studied in the last 50 years. Researchers have recognised that the real danger posed by these phenomena depends on their extreme values. Most researchers focus on the extremes of natural phenomena considered in isolation, one variable at a time. However, what is relevant in hazard studies is coincident extremes of several climatic variables, i.e., the presence of compound extremes. The peak value of these extremes seldom coincides, but off-peak values located in the tail of the distributions are often concurrent and can lead to catastrophic events. What is essential in hazard studies is to calculate the probabilistic distribution of the extremes of coincident climatic variables. The presence of correlations between these variables complicates the problem. This paper presents a computationally efficient and robust mathematical methodology to solve the problem. The procedure is based on the convolution of the distributions of the climatic variables. Once the probabilistic distribution of the compound variables is found, it is possible to calculate the curves of the return period, which is the indicator of importance in hazard and risk studies. This compound Return Period is computed using the Statistics of Extreme Values. To illustrate the problem, the case of a cyclone landing close to a low-gradient coastal city is discussed, and its probability of flooding and recurrence period is calculated. We show that the failure to correctly model the correlation between variables can result in overestimating the Return Period curve, consequently increasing mitigation costs.展开更多
AIM:To compare the efficacy of different administration regimens of compound tropicamide eyedrops(CTE)for pupil dilation for children with dark iris.METHODS:A prospective,comparative,randomized interventional study wa...AIM:To compare the efficacy of different administration regimens of compound tropicamide eyedrops(CTE)for pupil dilation for children with dark iris.METHODS:A prospective,comparative,randomized interventional study was conducted.Children in Group 1 received CTE 3 times with a 3min interval between each application.Children in Group 2 received CTE 4 times with a 5min interval between each application.We measured their pupil diameters at baseline(pre-drug instillation)and 30min and 60min post-drug instillation and assessed the pupillary light reflex at 60min post-drug instillation.RESULTS:In total,194 eyes of 101 children were enrolled.The changes of pupil diameter at 30min and 60min post-drug instillation were 1.2±0.6 mm and 2.3±1.0 mm in Group 1,and 2.3±0.9 mm and 3.7±1.0 mm in Group 2,respectively.Group 2 showed a larger change in pupil size than Group 1 at 30min(P<0.01)and 60min(P<0.01).The effect of pupil dilation in Group 2 was 1.25 times that in Group 1.The change in pupil size was positively associated with age.A higher proportion of children in Group 1 had smaller pupil diameter and reactive pupils at the final time point,with only 33 children(33.7%)had final pupil size≥6.5 mm,and only 9 children(9.2%)had non-reactive pupils.Children in Group 2 achieved larger pupil diameter and more nonreactive pupils at the final time point,with 84 children(87.5%)had final pupil size≥6.5 mm,and only 22 children(22.9%)had reactive pupils.CONCLUSION:Increasing the frequency of compound tropicamide and lengthening the interval between eye drop applications can produce stronger mydriatic effects.展开更多
In this editorial,we discuss the findings reported by Wang et al in the latest issue of the World Journal of Gastrointestinal Oncology.Various research methodologies,including microbiome analysis,assert that the Tzu-C...In this editorial,we discuss the findings reported by Wang et al in the latest issue of the World Journal of Gastrointestinal Oncology.Various research methodologies,including microbiome analysis,assert that the Tzu-Chi Cancer-Antagonizing and Life-Protecting II Decoction of Chinese herbal compounds mitigates inflammatory responses by inhibiting the NF-κB signaling pathway.This action helps maintain the dynamic equilibrium of the intestinal microecology and lessens chemotherapy-induced gastrointestinal damage.The efficacy of these compounds is intimately linked to the composition of intestinal microbes.These compounds regulate intestinal microecology by virtue of their specific compatibility and effectiveness,thereby enhancing the overall therapeutic outcomes of cancer chemotherapy.Nonetheless,the exact mechanisms underlying these effects warrant further investigation.Multi-omics technologies offer a systematic approach to elucidate the mechanisms and effectiveness of Chinese herbal compounds in vivo.This manuscript reviews the application of multi-omics technologies to Chinese herbal compounds and explores their potential role in modulating the gastrointestinal microenvironment following cancer chemotherapy,thus providing a theoretical foundation for their continued use in adjunct cancer treatment.展开更多
Electrochemical nitrogen transformation techniques represent a burgeoning avenue for nitrogen pollutant remediation and synthesizing valuable nitrogenous products from atmospheric nitrogen.Intermetallic compounds(IMCs...Electrochemical nitrogen transformation techniques represent a burgeoning avenue for nitrogen pollutant remediation and synthesizing valuable nitrogenous products from atmospheric nitrogen.Intermetallic compounds(IMCs)nanocrystals,featured with unique geometric,electronic and functional properties,have emerged as promising candidates.The review discusses various synthesis approaches for IMCs,including thermal annealing,wet chemical synthesis,electrochemical synthesis,and other emerging methods,analyzing their advantages and limitations.Then we summarized the recent advances of IMCs in electrocatalytic nitrogen transformation reactions,such as nitrate reduction reaction,nitric oxide reduction reaction,nitrogen reduction reaction,and hydrazine oxidation reaction.Despite significant progress,challenges remain in the field,particularly in adopting more refined strategies to improve catalyst performance and stability.This review aims to comprehensively understand the structural properties of IMCs and their structure-performance relationship,guiding the development of more efficient and stable catalysts for future nitrogen electrochemistry.展开更多
The emergence of metalenses has impacted a wide variety of applications such as beam steering,imaging,depth sensing,and display projection.Optical distortion,an important metric among many optical design specification...The emergence of metalenses has impacted a wide variety of applications such as beam steering,imaging,depth sensing,and display projection.Optical distortion,an important metric among many optical design specifications,has however rarely been discussed in the context of meta-optics.Here,we present a generic approach for on-demand distortion engineering using compound metalenses.We show that the extra degrees of freedom afforded by a doublet metasurface architecture allow custom-tailored angle-dependent image height relations and hence distortion control while minimizing other monochromatic aberrations.Using this platform,we experimentally demonstrate a compound fisheye metalens with diffraction-limited performance across a wide field of view of 140°and a low barrel distortion of less than 2%,compared with up to 22%distortion in a reference metalens without compensation.The design strategy and compound metalens architecture presented herein are expected to broadly impact metasurface applications in consumer electronics,automotive and robotic sensing,medical imaging,and machine vision systems.展开更多
Sub-seasonal prediction of regional compound heatwaves and their predictability sources remain unclear.In this study,the underlying mechanisms for the long-lasting compound heatwave over Southern China during July 1–...Sub-seasonal prediction of regional compound heatwaves and their predictability sources remain unclear.In this study,the underlying mechanisms for the long-lasting compound heatwave over Southern China during July 1–18,2010,and the major sources of its sub-seasonal prediction skill are identified.The results show that both the development and decay of this compound heatwave are mainly dominated by atmospheric processes(i.e.,adiabatic heating associated with anticyclonic circulation),whereas land-atmosphere coupling processes play an important role in sustaining the heatwave.A further analysis indicates that by inducing anomalous anticyclonic circulations over Southern China,the tropical intraseasonal oscillations with periods of 30–60 days and 10–30 days facilitate the occurrence and maintenance of the heatwave during its entire and second half periods,respectively.The NCEP Climate Forecast System Version 2 shows a low skill in predicting the 2010 compound heatwave over Southern China when the lead time is longer than 2 pentads,which is largely attributed to the model’s bias in representing the intensity and phase of intra-seasonal oscillations.展开更多
In a warming world,climate extremes tend to be more frequent and intense.The exceptional response of ecosystems triggered by extreme climate events under a warmer and wetter climate in northwest China(NWC)has aroused ...In a warming world,climate extremes tend to be more frequent and intense.The exceptional response of ecosystems triggered by extreme climate events under a warmer and wetter climate in northwest China(NWC)has aroused growing concern.However,understanding the responses of vegetation to climate extremes from the compound events perspective remains challenging.In this study,we identify the climate dynamics in NWC during 1971–2020 based on daily meteorological observations,focusing on the changes in compound hot-dry events(CHDEs)during the warmer and wetter period.We further explore the effects of CHDEs on vegetation by examining vegetation anomalies and recovery time using daily gross primary productivity(GPP)data.The results show a clear warmer and wetter period in NWC during 2000–2020.No signs of a hiatus in CHDEs increase are observed during this period,and even the duration of CHDEs in western NWC keeps showing an increasing tendency.Vegetation in eastern NWC,with a lower probability of GPP anomalies,exhibits stronger resistance of ecosystems to CHDEs than in western NWC.In NWC,vegetation typically returns to its normal state in 5.50 days on average,but exhibits greater resilience in the western region,where it takes less recovery time(4.82 days).Vegetation in the central region shows the lowest probability of GPP anomalies and relatively longer recovery time,likely due to its higher altitudes.Our research underscores the imperative to address the considerable impacts of CHDEs on vegetation growth even as the regional climate becomes increasingly warmer and wetter.展开更多
Wide bandgap semiconductors are typically activated under ultraviolet(UV)light irradiation for volatile organic compounds(VOCs)degradation.However,our previous study discovered that certain VOCs can interact with some...Wide bandgap semiconductors are typically activated under ultraviolet(UV)light irradiation for volatile organic compounds(VOCs)degradation.However,our previous study discovered that certain VOCs can interact with some wide bandgap semiconductors,formatting an intermediate bandgap between the VOCs and the conduction band of wide bandgap semiconductor,thus inducing visible light activation of the system,and photo-generated electrons are excited by visible light and transferred from the VOCs to the conduction band of semiconductor.In this work,BaTiO_(3),traditionally is not active under visible light irradiation,however showed degradation rates of 100%and 20%for styrene and toluene under visible light,respectively.Density functional theory(DFT)calculations indicate that the adsorption of styrene or toluene on the BaTiO_(3)surface reduces its bandgap from 2.93 eV to 1.36 eV and 2.26 eV,respectively.The intermediate bandgap in this system is primarily formed by the valence band of BaTiO_(3)and the VOCs,and indicating that photo-generated electrons directly transfer from BaTiO_(3)to the VOCs under visible light,inducing degradation reactions of VOCs,i.e.,this work discovered a new transfer pathway of photo-electrons direct from the valence band of BaTiO_(3)to VOCs,while photo-electrons are from VOCs to the conductive band of wide-bandgap semiconductors in our previous work.展开更多
Medicinal and dietary plants provide numerous nutritional and functional compounds and also have various potential health benefits to humanity.The specific and efficient techniques for accurate identification of nutri...Medicinal and dietary plants provide numerous nutritional and functional compounds and also have various potential health benefits to humanity.The specific and efficient techniques for accurate identification of nutritional compounds and functional metabolites is crucial for the development of functional foods from medicinal and dietary plants.Nuclear magnetic resonance(NMR)and mass spectrometry(MS)are indispensable and essential technologies that provide an unsurpassed wealth of untargeted identification,quantitative and qualitative analysis,and structural information in the study of food and plant products.In the past decade,the rapid development of modern analytical technology has led to the emergence of new approaches and strategies for natural products discovery.Especially the application of novel NMRand MS-based identification and dereplication strategies aided by artificial intelligence and machine learning algorithms have brought about a significant shift in the natural products discovery process.These developments and changes in the natural products filed have given us insights into how to accurately target and mining nutritional,functional,and bioactive compounds.Thus,we have summarized recent research on novel NMR and MS based strategies and methods focusing on functional compounds,accurate identification and efficient discovery mainly in medicinal and dietary plants.This review could provide a comprehensive perspective for a better understanding of novel strategies and methods based on NMR and MS technologies,which could provide valuable insights and ideas for functional compounds mining.展开更多
Compound eyes(CEs)that feature ultra-compact structures and extraordinary versatility have revealed great potential for cutting-edge applications.However,the optoelectronic integration of CEs with available photodetec...Compound eyes(CEs)that feature ultra-compact structures and extraordinary versatility have revealed great potential for cutting-edge applications.However,the optoelectronic integration of CEs with available photodetectors is still challenging because the planar charge-coupled device(CCD)/complementary metal oxide semiconductor(CMOS)detector cannot match the spatially distributed images formed by CE ommatidia.To reach this end,we report here the optoelectronic integration of CEs by manufacturing 3D nonuniform ommatidia for developing an ultra-compact on-chip camera.As a proof-of-concept,we fabricated microscale CEs with uniform and nonuniform ommatidia through femtosecond laser two-photon photopolymerization,and compared their focusing/imaging performance both theoretically and experimentally.By engineering the surface profiles of the ommatidia at different positions of the CE,the images formed by all the ommatidia can be tuned on a plane.In this way,the nonuniform CE can be directly integrated with a commercial CMOS photodetector,forming an ultra-compact CE camera.Additionally,we further combine the CE camera with a microfluidic chip,which can further serve as an on-chip microscopic monitoring system.We anticipate that such an ultra-compact CE camera may find broad applications in microfluidics,robotics,and micro-optics.展开更多
Solar interfacial evaporation(SIE),is currently one of the most potential water supply technologies in the remote,insular,and disaster-stricken areas.However,the existence of volatile organic compounds(VOCs)in water d...Solar interfacial evaporation(SIE),is currently one of the most potential water supply technologies in the remote,insular,and disaster-stricken areas.However,the existence of volatile organic compounds(VOCs)in water deteriorates the distillate quality,threatening human health.Herein,we constructed a carbonbased bimetallic(C/FeCo)photothermal membrane by electrospinning technique.Results illustrated that the membrane can catalytically degrade VOCs during SIE with persulfate(PDS)mediation.PDS,as well as phenol,was mainly reacted on the interface of the photothermal membrane instead of in the bulk solution.The interception efficiency of phenol achieved nearly 100%using the C/FeCo membrane during SIE.Hydroxyl radical(•OH),sulfate radical(SO_(4)•−),superoxide radical(O_(2)•−),and singlet oxygen(^(1)O_(2))were identified as the main active substances to degrade VOCs.We also conducted SIE experiments using actual river water to evaluate the practical performance of the C/FeCo membrane.This work holds the promise of VOCs interception during SIE and enlarges the application of solar distillation in water/wastewater treatment.展开更多
[Objectives]This study was conducted to establish a detection method for the simultaneous determination of 18 perfluorinated compounds(PFCs)in milk tea by ultra-high performance liquid chromatography-tandem mass spect...[Objectives]This study was conducted to establish a detection method for the simultaneous determination of 18 perfluorinated compounds(PFCs)in milk tea by ultra-high performance liquid chromatography-tandem mass spectrometry(UHPLC-MS/MS).[Methods]The samples were first subjected to precipitation of proteins by potassium ferrocyanide solution and zinc acetate solution,and then extracted by acetonitrile and detected by LC-MS/MS.Next,sodium chloride was added,and after vortex centrifugation,the acetonitrile layer was dried by blowing with nitrogen.Subsequently,1 ml of methanol was added to prepare a test solution.An ACQUITY UPLC BEH C18(2.6 m,2.1 mm×100 mm)chromatographic column was used for liquid phase separation,and gradient elution was performed using 10 mmol ammonium acetate solution-acetonitrile as the mobile phase.The MS detection adopted the MRM mode for acquisition,positive and negative ion mode switching for simultaneous determination,and external standard method for quantification.[Results]In the linear ranges of the target substances,the correlation coefficients R^(2)were all greater than 0.99.The detection limits of the method was in the range of 0.001-0.05μg/kg,and the quantitation limits were in the range of 0.03-0.20 ng/L.The recovery values ranged from 72.8%to 110.5%.[Conclusions]This method has high sensitivity and good accuracy,and thus strong practical value.展开更多
In response to the current situation of practical teaching and the main problems in the teaching process of cultivating composite talents in the characteristic demonstration software college,this paper analyzes the im...In response to the current situation of practical teaching and the main problems in the teaching process of cultivating composite talents in the characteristic demonstration software college,this paper analyzes the importance of digital reform in practical teaching,introduces the work foundation,main work,reform characteristics,and effects of digital reform in practical teaching of composite talents in Software College of Northeastern University and lays the foundation for future in-depth research,providing reference for the digital reform of practical teaching in related majors of other colleges.展开更多
Lemon oils are broadly used as flavoring agents in beverages,foods,cosmetics and pharmaceuticals,yet the adulteration of natural,particularly cold pressed lemon oils is very common in the industry due to its unmet dem...Lemon oils are broadly used as flavoring agents in beverages,foods,cosmetics and pharmaceuticals,yet the adulteration of natural,particularly cold pressed lemon oils is very common in the industry due to its unmet demand and high cost.Nowadays,most quality control(QC)analysis of lemon oils is conducted by gas chromatography(GC)analysis,which is far from a reliable method.Oxygen heterocyclic compounds(OHCs)in non-volatile fraction are gaining increasing attention in authentication process because of the nearly finger-printing profiles of OHCs in cold pressed citrus essential oils.Our goal in this study was to identify OHCs using high performance liquid chromatography(HPLC)in lemon oils,establish OHC profiles,perform stepwise logistic regression analysis(SLRA)and build effective predicting model and further determine adulterated lemon oils by referencing the OHC profiles and established models.After HPLC analyses,profiling and SLRA modeling of 154 OHCs samples of industrial lemon oils,we found that the combination of isopimpinellin and total OHC concentration are essential and robust predictors to differentiate authentic samples from adulterated lemon oils with a success rate of 98%from the 5-fold cross validation.This study provided a reliable and efficient method in determining the authenticity of lemon oils.展开更多
In the Mei-yu region,there has been noticeable increase in the occurrence of compound hot drought(CHD)events in recent years.However,the underlying causes of these occurrences remain poorly understood.To address this ...In the Mei-yu region,there has been noticeable increase in the occurrence of compound hot drought(CHD)events in recent years.However,the underlying causes of these occurrences remain poorly understood.To address this knowledge gap,we conducted a comprehensive study utilizing observational datasets,reanalysis datasets,and four numerical experiments to investigate the associated physical mechanisms.Our findings indicated that the prevalence of CHD events in the Mei-yu region is influenced strongly by two key factors:the decline in Barents Sea ice during February and the presence of a La Ni?alike pattern of sea surface temperature(SST)in April.The decline in Barents Sea ice generates an anomalous Rossby wave in the Arctic that propagates southeastward.The La Ni?a-like SST pattern regulates a Rossby wave over western America,propagating along the subtropical jet stream.These two Rossby waves induce northward movement and strengthened intensity of the subtropical westerly jet in East Asia.The local circulation patterns in the Mei-yu region are influenced by the position and intensity of the subtropical jet,leading to downward motion in accordance with the secondary circulation theory for high-altitude jet streams.Consequently,these local circulation patterns might contribute to occurrence of CHD events.Moreover,our analysis revealed that the impact of Barents Sea ice and the La Nina-like SST pattern can explain approximately two-thirds of the mild CHD events in the Mei-yu region,and that the influence of each is relatively independent.This research underscores influences of polartropical systems on climate extremes in eastern Asia.展开更多
In this paper,the effect of vibration intensity on the spatial distribution of sulfur content in bed particles was studied.The effects of vibration and airflow on the mechanical characteristics of particles were studi...In this paper,the effect of vibration intensity on the spatial distribution of sulfur content in bed particles was studied.The effects of vibration and airflow on the mechanical characteristics of particles were studied,the collision behavior mode of particles was determined,the spatial saltation law of particles was investigated,the spatial functional axis of beds was determined,and the saltation separation period of particles was determined.The test results show that:When separation bed provides inlet airflow velocity(U_(in)) is 2.55 m/s,the airflow distribution interval of I,II and III areas were U_(I)=2.55-2.57 m/s,U_(II)=1.33-1.35 m/s,U_(III)=0.35-0.38 m/s,respectively;when separation bed vibration amplitude (A)A=2.4-2.5 mm,separation bed vibration frequency (f) f=23-24 Hz,the desulfurization effect is the best.When vibration intensity (Γ)Γ=1.22,U_(in)=1.05 m/s,the particles have disordered contact and collision behavior.WhenΓ=14.89,U_(in)=3.18 m/s,the particles have a transition cataclastic collision.WhenΓ=5.80,U_(in)=2.55 m/s,the particles have directional collision behavior.It is determined that the OX axis is the transverse stable diffusion axis of the material,the OY axis is the longitudinal gradient transport axis of the material,and the OZ axis is the vertical density cascade distribution axis of the material.When separation time (T) T=0-10 s was the period of disorderly diffusion and mixing of particles,T=10-20 s was the period of directional migration and stratification of particles,and T=20-30 s was the period of cascade distribution and separation of particles.Finally,separation experiments conducted under optimal operating parameters demonstrated that the clean coal yield was 72.02%with a sulfur content of 0.98%.展开更多
Numerous arthropods evolve and optimize sensory systems, enabling them to effectively adapt complex and competitive habitats. Typically, scorpions can precisely perceive the prey location with the lowest metabolic rat...Numerous arthropods evolve and optimize sensory systems, enabling them to effectively adapt complex and competitive habitats. Typically, scorpions can precisely perceive the prey location with the lowest metabolic rate among invertebrates. This biological phenomenon contrasts sharply with engineered systems, which generally associates high accuracy with substantial energy consumption. Inspired by the Scorpion Compound Slit Sensilla (SCSS) with a stress field modulation strategy, a bionic positioning sensor with superior precision and minimal power consumption is developed for the first time, which utilizes the particular Minimum Positioning Units (MPUs) to efficiently locate vibration signals. The single MPU of the SCSS can recognize the direction of collinear loads by regulating the stress field distribution and further, the coupling action of three MPUs can realize all-angle vibration monitoring in plane. Experiments demonstrate that the bionic positioning sensor achieves 1.43 degrees of angle-error-free accuracy without additional energy supply. As a proof of concept, two bionic positioning sensors and machine learning algorithm are integrated to provide centimeter (cm)-accuracy target localization, ideally suited for the man-machine interaction. The novel design offers a new mechanism for the design of traditional positioning devices, improving precision and efficiency in both the meta-universe and real-world Internet-connected systems.展开更多
To provide new insights into the development and utilization of Douchi artificial starters,three common strains(Aspergillus oryzae,Mucor racemosus,and Rhizopus oligosporus)were used to study their influence on the fer...To provide new insights into the development and utilization of Douchi artificial starters,three common strains(Aspergillus oryzae,Mucor racemosus,and Rhizopus oligosporus)were used to study their influence on the fermentation of Douchi.The results showed that the biogenic amine contents of the three types of Douchi were all within the safe range and far lower than those of traditional fermented Douchi.Aspergillus-type Douchi produced more free amino acids than the other two types of Douchi,and its umami taste was more prominent in sensory evaluation(P<0.01),while Mucor-type and Rhizopus-type Douchi produced more esters and pyrazines,making the aroma,sauce,and Douchi flavor more abundant.According to the Pearson and PLS analyses results,sweetness was significantly negatively correlated with phenylalanine,cysteine,and acetic acid(P<0.05),bitterness was significantly negatively correlated with malic acid(P<0.05),the sour taste was significantly positively correlated with citric acid and most free amino acids(P<0.05),while astringency was significantly negatively correlated with glucose(P<0.001).Thirteen volatile compounds such as furfuryl alcohol,phenethyl alcohol,and benzaldehyde caused the flavor difference of three types of Douchi.This study provides theoretical basis for the selection of starting strains for commercial Douchi production.展开更多
文摘This research was carried out to identify the most effective plant species for air purification based on environmental factors. The existence of plants beside roadways can be considered a more efficient approach to improving air quality and minimizing pollution exposure. The samples for this research were collected from various sites across the streets of Jeddah governorate. The primary sources of air pollution in the research area are vehicle traffic and emissions from cars. Eight species were gathered from various streets in Jeddah governorate, namely, Azadirachta indica, Senna sulfurea, Ziziphus spina-christi, Cordia sebestena, Tecoma stans, Bougainvillea spectabilis, Conocarpus lancifolius, and Ixora coccinea. The leaves of the studied plants were analyzed for secondary compounds using Gas chromatography-mass spectrometry (GC-MS) techniques. Gas-chromatographic analyses revealed that bis (2-ethylhexyl) phthalate was found in every plant. Bis-(2-ethylhexyl) phthalate, a widespread environmental pollutant. Moreover, Cordia sebestena was the sole plant that contained Phenol, 2,2’-methylenebis [6-(1,1-dimethylethyl)-4-methyl] which is part of the phenols category. Environmental conditions can affect the production of secondary metabolites. By tracking the concentrations of these substances, researchers can evaluate the well-being of ecosystems and identify pollution.
文摘The hazard produced by natural phenomena on infrastructure and urban populations has been widely studied in the last 50 years. Researchers have recognised that the real danger posed by these phenomena depends on their extreme values. Most researchers focus on the extremes of natural phenomena considered in isolation, one variable at a time. However, what is relevant in hazard studies is coincident extremes of several climatic variables, i.e., the presence of compound extremes. The peak value of these extremes seldom coincides, but off-peak values located in the tail of the distributions are often concurrent and can lead to catastrophic events. What is essential in hazard studies is to calculate the probabilistic distribution of the extremes of coincident climatic variables. The presence of correlations between these variables complicates the problem. This paper presents a computationally efficient and robust mathematical methodology to solve the problem. The procedure is based on the convolution of the distributions of the climatic variables. Once the probabilistic distribution of the compound variables is found, it is possible to calculate the curves of the return period, which is the indicator of importance in hazard and risk studies. This compound Return Period is computed using the Statistics of Extreme Values. To illustrate the problem, the case of a cyclone landing close to a low-gradient coastal city is discussed, and its probability of flooding and recurrence period is calculated. We show that the failure to correctly model the correlation between variables can result in overestimating the Return Period curve, consequently increasing mitigation costs.
基金Supported by the National Natural Science Foundation of China(No.82371093,No.72342015)R&D Program of Beijing Municipal Education Commission(No.KZ202110025039).
文摘AIM:To compare the efficacy of different administration regimens of compound tropicamide eyedrops(CTE)for pupil dilation for children with dark iris.METHODS:A prospective,comparative,randomized interventional study was conducted.Children in Group 1 received CTE 3 times with a 3min interval between each application.Children in Group 2 received CTE 4 times with a 5min interval between each application.We measured their pupil diameters at baseline(pre-drug instillation)and 30min and 60min post-drug instillation and assessed the pupillary light reflex at 60min post-drug instillation.RESULTS:In total,194 eyes of 101 children were enrolled.The changes of pupil diameter at 30min and 60min post-drug instillation were 1.2±0.6 mm and 2.3±1.0 mm in Group 1,and 2.3±0.9 mm and 3.7±1.0 mm in Group 2,respectively.Group 2 showed a larger change in pupil size than Group 1 at 30min(P<0.01)and 60min(P<0.01).The effect of pupil dilation in Group 2 was 1.25 times that in Group 1.The change in pupil size was positively associated with age.A higher proportion of children in Group 1 had smaller pupil diameter and reactive pupils at the final time point,with only 33 children(33.7%)had final pupil size≥6.5 mm,and only 9 children(9.2%)had non-reactive pupils.Children in Group 2 achieved larger pupil diameter and more nonreactive pupils at the final time point,with 84 children(87.5%)had final pupil size≥6.5 mm,and only 22 children(22.9%)had reactive pupils.CONCLUSION:Increasing the frequency of compound tropicamide and lengthening the interval between eye drop applications can produce stronger mydriatic effects.
基金Supported by 2023 Government-funded Project of the Outstanding Talents Training Program in Clinical Medicine,No.ZF2023165Key Research and Development Projects of Hebei Province,No.18277731DNatural Science Foundation of Hebei Province,No.H202423105.
文摘In this editorial,we discuss the findings reported by Wang et al in the latest issue of the World Journal of Gastrointestinal Oncology.Various research methodologies,including microbiome analysis,assert that the Tzu-Chi Cancer-Antagonizing and Life-Protecting II Decoction of Chinese herbal compounds mitigates inflammatory responses by inhibiting the NF-κB signaling pathway.This action helps maintain the dynamic equilibrium of the intestinal microecology and lessens chemotherapy-induced gastrointestinal damage.The efficacy of these compounds is intimately linked to the composition of intestinal microbes.These compounds regulate intestinal microecology by virtue of their specific compatibility and effectiveness,thereby enhancing the overall therapeutic outcomes of cancer chemotherapy.Nonetheless,the exact mechanisms underlying these effects warrant further investigation.Multi-omics technologies offer a systematic approach to elucidate the mechanisms and effectiveness of Chinese herbal compounds in vivo.This manuscript reviews the application of multi-omics technologies to Chinese herbal compounds and explores their potential role in modulating the gastrointestinal microenvironment following cancer chemotherapy,thus providing a theoretical foundation for their continued use in adjunct cancer treatment.
基金funded by the National Natural Science Foundation of China(No.22405173)the Shanghai Pujiang Program(No.23PJ1409100)the Project of Overseas Leading Talent of Shanghai.
文摘Electrochemical nitrogen transformation techniques represent a burgeoning avenue for nitrogen pollutant remediation and synthesizing valuable nitrogenous products from atmospheric nitrogen.Intermetallic compounds(IMCs)nanocrystals,featured with unique geometric,electronic and functional properties,have emerged as promising candidates.The review discusses various synthesis approaches for IMCs,including thermal annealing,wet chemical synthesis,electrochemical synthesis,and other emerging methods,analyzing their advantages and limitations.Then we summarized the recent advances of IMCs in electrocatalytic nitrogen transformation reactions,such as nitrate reduction reaction,nitric oxide reduction reaction,nitrogen reduction reaction,and hydrazine oxidation reaction.Despite significant progress,challenges remain in the field,particularly in adopting more refined strategies to improve catalyst performance and stability.This review aims to comprehensively understand the structural properties of IMCs and their structure-performance relationship,guiding the development of more efficient and stable catalysts for future nitrogen electrochemistry.
文摘The emergence of metalenses has impacted a wide variety of applications such as beam steering,imaging,depth sensing,and display projection.Optical distortion,an important metric among many optical design specifications,has however rarely been discussed in the context of meta-optics.Here,we present a generic approach for on-demand distortion engineering using compound metalenses.We show that the extra degrees of freedom afforded by a doublet metasurface architecture allow custom-tailored angle-dependent image height relations and hence distortion control while minimizing other monochromatic aberrations.Using this platform,we experimentally demonstrate a compound fisheye metalens with diffraction-limited performance across a wide field of view of 140°and a low barrel distortion of less than 2%,compared with up to 22%distortion in a reference metalens without compensation.The design strategy and compound metalens architecture presented herein are expected to broadly impact metasurface applications in consumer electronics,automotive and robotic sensing,medical imaging,and machine vision systems.
基金Guangdong Major Project of Basic and Applied Basic Research(2020B0301030004)National Natural Science Foundation of China(42105015)+3 种基金Guangdong Basic and Applied Basic Research Foundation(2022A1515010659)Southern Marine Science and Engineering Guangdong Laboratory(Zhuhai)(SML2023SP209)Innovation Group Project of Southern Marine Science and Engineering Guangdong Laboratory(Zhuhai)(311021001)Guangdong Province Key Laboratory for Climate Change and Natural Disaster Studies(2020B1212060025)。
文摘Sub-seasonal prediction of regional compound heatwaves and their predictability sources remain unclear.In this study,the underlying mechanisms for the long-lasting compound heatwave over Southern China during July 1–18,2010,and the major sources of its sub-seasonal prediction skill are identified.The results show that both the development and decay of this compound heatwave are mainly dominated by atmospheric processes(i.e.,adiabatic heating associated with anticyclonic circulation),whereas land-atmosphere coupling processes play an important role in sustaining the heatwave.A further analysis indicates that by inducing anomalous anticyclonic circulations over Southern China,the tropical intraseasonal oscillations with periods of 30–60 days and 10–30 days facilitate the occurrence and maintenance of the heatwave during its entire and second half periods,respectively.The NCEP Climate Forecast System Version 2 shows a low skill in predicting the 2010 compound heatwave over Southern China when the lead time is longer than 2 pentads,which is largely attributed to the model’s bias in representing the intensity and phase of intra-seasonal oscillations.
基金supported by the National Natural Science Foundation of China(Grant No.42371423)the Fundamental Research Funds for the Central Universities(Grant No.2042023kfyq04)+1 种基金the China Postdoctoral Science Foundation(Grant No.2023M742682)the Postdoctoral Fellowship Program of CPSF(Grant No.GZB20230539).
文摘In a warming world,climate extremes tend to be more frequent and intense.The exceptional response of ecosystems triggered by extreme climate events under a warmer and wetter climate in northwest China(NWC)has aroused growing concern.However,understanding the responses of vegetation to climate extremes from the compound events perspective remains challenging.In this study,we identify the climate dynamics in NWC during 1971–2020 based on daily meteorological observations,focusing on the changes in compound hot-dry events(CHDEs)during the warmer and wetter period.We further explore the effects of CHDEs on vegetation by examining vegetation anomalies and recovery time using daily gross primary productivity(GPP)data.The results show a clear warmer and wetter period in NWC during 2000–2020.No signs of a hiatus in CHDEs increase are observed during this period,and even the duration of CHDEs in western NWC keeps showing an increasing tendency.Vegetation in eastern NWC,with a lower probability of GPP anomalies,exhibits stronger resistance of ecosystems to CHDEs than in western NWC.In NWC,vegetation typically returns to its normal state in 5.50 days on average,but exhibits greater resilience in the western region,where it takes less recovery time(4.82 days).Vegetation in the central region shows the lowest probability of GPP anomalies and relatively longer recovery time,likely due to its higher altitudes.Our research underscores the imperative to address the considerable impacts of CHDEs on vegetation growth even as the regional climate becomes increasingly warmer and wetter.
基金financially supported by the National Natural Science Foundation of China(No.22176041,T2421005)National Key R&D Program of China(No.2022YFC3901800)+1 种基金the Fundamental Research Funds for the Central Universities(No.2243200011)Guangzhou Science and Technology Planning Project(No.2023A04J0918).
文摘Wide bandgap semiconductors are typically activated under ultraviolet(UV)light irradiation for volatile organic compounds(VOCs)degradation.However,our previous study discovered that certain VOCs can interact with some wide bandgap semiconductors,formatting an intermediate bandgap between the VOCs and the conduction band of wide bandgap semiconductor,thus inducing visible light activation of the system,and photo-generated electrons are excited by visible light and transferred from the VOCs to the conduction band of semiconductor.In this work,BaTiO_(3),traditionally is not active under visible light irradiation,however showed degradation rates of 100%and 20%for styrene and toluene under visible light,respectively.Density functional theory(DFT)calculations indicate that the adsorption of styrene or toluene on the BaTiO_(3)surface reduces its bandgap from 2.93 eV to 1.36 eV and 2.26 eV,respectively.The intermediate bandgap in this system is primarily formed by the valence band of BaTiO_(3)and the VOCs,and indicating that photo-generated electrons directly transfer from BaTiO_(3)to the VOCs under visible light,inducing degradation reactions of VOCs,i.e.,this work discovered a new transfer pathway of photo-electrons direct from the valence band of BaTiO_(3)to VOCs,while photo-electrons are from VOCs to the conductive band of wide-bandgap semiconductors in our previous work.
基金financially supported by the National Key R&D Program of China(2022YFF1100301)Major Science and Technology Project of Henan Province(231100310200)+1 种基金National Natural Science Foundation of China(32370426)Yunnan Province Science and Technology Department(202305AH340005),and Dr Plant。
文摘Medicinal and dietary plants provide numerous nutritional and functional compounds and also have various potential health benefits to humanity.The specific and efficient techniques for accurate identification of nutritional compounds and functional metabolites is crucial for the development of functional foods from medicinal and dietary plants.Nuclear magnetic resonance(NMR)and mass spectrometry(MS)are indispensable and essential technologies that provide an unsurpassed wealth of untargeted identification,quantitative and qualitative analysis,and structural information in the study of food and plant products.In the past decade,the rapid development of modern analytical technology has led to the emergence of new approaches and strategies for natural products discovery.Especially the application of novel NMRand MS-based identification and dereplication strategies aided by artificial intelligence and machine learning algorithms have brought about a significant shift in the natural products discovery process.These developments and changes in the natural products filed have given us insights into how to accurately target and mining nutritional,functional,and bioactive compounds.Thus,we have summarized recent research on novel NMR and MS based strategies and methods focusing on functional compounds,accurate identification and efficient discovery mainly in medicinal and dietary plants.This review could provide a comprehensive perspective for a better understanding of novel strategies and methods based on NMR and MS technologies,which could provide valuable insights and ideas for functional compounds mining.
基金financial supports from Natural Science Foundation of China(Grant No.61935008,T2325014,62205174 and 62275100)。
文摘Compound eyes(CEs)that feature ultra-compact structures and extraordinary versatility have revealed great potential for cutting-edge applications.However,the optoelectronic integration of CEs with available photodetectors is still challenging because the planar charge-coupled device(CCD)/complementary metal oxide semiconductor(CMOS)detector cannot match the spatially distributed images formed by CE ommatidia.To reach this end,we report here the optoelectronic integration of CEs by manufacturing 3D nonuniform ommatidia for developing an ultra-compact on-chip camera.As a proof-of-concept,we fabricated microscale CEs with uniform and nonuniform ommatidia through femtosecond laser two-photon photopolymerization,and compared their focusing/imaging performance both theoretically and experimentally.By engineering the surface profiles of the ommatidia at different positions of the CE,the images formed by all the ommatidia can be tuned on a plane.In this way,the nonuniform CE can be directly integrated with a commercial CMOS photodetector,forming an ultra-compact CE camera.Additionally,we further combine the CE camera with a microfluidic chip,which can further serve as an on-chip microscopic monitoring system.We anticipate that such an ultra-compact CE camera may find broad applications in microfluidics,robotics,and micro-optics.
基金the National Natural Science Foundation of China(No.52070052)the National Natural Science Foundation of China(No.52300082)+3 种基金National Key Research and Development Program of China(No.2022YFB3805903)the State Key Laboratory of Urban Water Resource and Environment in HIT of China(No.2022TS14)the China Postdoctoral Science Foundation(No.2023M730881)Postdoctoral Fellowship Program of CPSF(No.GZB20230964)。
文摘Solar interfacial evaporation(SIE),is currently one of the most potential water supply technologies in the remote,insular,and disaster-stricken areas.However,the existence of volatile organic compounds(VOCs)in water deteriorates the distillate quality,threatening human health.Herein,we constructed a carbonbased bimetallic(C/FeCo)photothermal membrane by electrospinning technique.Results illustrated that the membrane can catalytically degrade VOCs during SIE with persulfate(PDS)mediation.PDS,as well as phenol,was mainly reacted on the interface of the photothermal membrane instead of in the bulk solution.The interception efficiency of phenol achieved nearly 100%using the C/FeCo membrane during SIE.Hydroxyl radical(•OH),sulfate radical(SO_(4)•−),superoxide radical(O_(2)•−),and singlet oxygen(^(1)O_(2))were identified as the main active substances to degrade VOCs.We also conducted SIE experiments using actual river water to evaluate the practical performance of the C/FeCo membrane.This work holds the promise of VOCs interception during SIE and enlarges the application of solar distillation in water/wastewater treatment.
基金Supported by Natural Science Foundation of Hunan Province(2024JJ8266).
文摘[Objectives]This study was conducted to establish a detection method for the simultaneous determination of 18 perfluorinated compounds(PFCs)in milk tea by ultra-high performance liquid chromatography-tandem mass spectrometry(UHPLC-MS/MS).[Methods]The samples were first subjected to precipitation of proteins by potassium ferrocyanide solution and zinc acetate solution,and then extracted by acetonitrile and detected by LC-MS/MS.Next,sodium chloride was added,and after vortex centrifugation,the acetonitrile layer was dried by blowing with nitrogen.Subsequently,1 ml of methanol was added to prepare a test solution.An ACQUITY UPLC BEH C18(2.6 m,2.1 mm×100 mm)chromatographic column was used for liquid phase separation,and gradient elution was performed using 10 mmol ammonium acetate solution-acetonitrile as the mobile phase.The MS detection adopted the MRM mode for acquisition,positive and negative ion mode switching for simultaneous determination,and external standard method for quantification.[Results]In the linear ranges of the target substances,the correlation coefficients R^(2)were all greater than 0.99.The detection limits of the method was in the range of 0.001-0.05μg/kg,and the quantitation limits were in the range of 0.03-0.20 ng/L.The recovery values ranged from 72.8%to 110.5%.[Conclusions]This method has high sensitivity and good accuracy,and thus strong practical value.
文摘In response to the current situation of practical teaching and the main problems in the teaching process of cultivating composite talents in the characteristic demonstration software college,this paper analyzes the importance of digital reform in practical teaching,introduces the work foundation,main work,reform characteristics,and effects of digital reform in practical teaching of composite talents in Software College of Northeastern University and lays the foundation for future in-depth research,providing reference for the digital reform of practical teaching in related majors of other colleges.
文摘Lemon oils are broadly used as flavoring agents in beverages,foods,cosmetics and pharmaceuticals,yet the adulteration of natural,particularly cold pressed lemon oils is very common in the industry due to its unmet demand and high cost.Nowadays,most quality control(QC)analysis of lemon oils is conducted by gas chromatography(GC)analysis,which is far from a reliable method.Oxygen heterocyclic compounds(OHCs)in non-volatile fraction are gaining increasing attention in authentication process because of the nearly finger-printing profiles of OHCs in cold pressed citrus essential oils.Our goal in this study was to identify OHCs using high performance liquid chromatography(HPLC)in lemon oils,establish OHC profiles,perform stepwise logistic regression analysis(SLRA)and build effective predicting model and further determine adulterated lemon oils by referencing the OHC profiles and established models.After HPLC analyses,profiling and SLRA modeling of 154 OHCs samples of industrial lemon oils,we found that the combination of isopimpinellin and total OHC concentration are essential and robust predictors to differentiate authentic samples from adulterated lemon oils with a success rate of 98%from the 5-fold cross validation.This study provided a reliable and efficient method in determining the authenticity of lemon oils.
基金supported by the National Natural Science Foundation of China(42088101)the National Key Research and Development Program of China(2022YFF0801704)the Innovation Group Project of Southern Marine Science and Engineering Guangdong Laboratory(Zhuhai)(316323005)。
文摘In the Mei-yu region,there has been noticeable increase in the occurrence of compound hot drought(CHD)events in recent years.However,the underlying causes of these occurrences remain poorly understood.To address this knowledge gap,we conducted a comprehensive study utilizing observational datasets,reanalysis datasets,and four numerical experiments to investigate the associated physical mechanisms.Our findings indicated that the prevalence of CHD events in the Mei-yu region is influenced strongly by two key factors:the decline in Barents Sea ice during February and the presence of a La Ni?alike pattern of sea surface temperature(SST)in April.The decline in Barents Sea ice generates an anomalous Rossby wave in the Arctic that propagates southeastward.The La Ni?a-like SST pattern regulates a Rossby wave over western America,propagating along the subtropical jet stream.These two Rossby waves induce northward movement and strengthened intensity of the subtropical westerly jet in East Asia.The local circulation patterns in the Mei-yu region are influenced by the position and intensity of the subtropical jet,leading to downward motion in accordance with the secondary circulation theory for high-altitude jet streams.Consequently,these local circulation patterns might contribute to occurrence of CHD events.Moreover,our analysis revealed that the impact of Barents Sea ice and the La Nina-like SST pattern can explain approximately two-thirds of the mild CHD events in the Mei-yu region,and that the influence of each is relatively independent.This research underscores influences of polartropical systems on climate extremes in eastern Asia.
基金supported by Science and Technology Project of Hebei Education Department (No. ZD2022128)Tangshan Science and Technology Plan Project (No. 22130226H)。
文摘In this paper,the effect of vibration intensity on the spatial distribution of sulfur content in bed particles was studied.The effects of vibration and airflow on the mechanical characteristics of particles were studied,the collision behavior mode of particles was determined,the spatial saltation law of particles was investigated,the spatial functional axis of beds was determined,and the saltation separation period of particles was determined.The test results show that:When separation bed provides inlet airflow velocity(U_(in)) is 2.55 m/s,the airflow distribution interval of I,II and III areas were U_(I)=2.55-2.57 m/s,U_(II)=1.33-1.35 m/s,U_(III)=0.35-0.38 m/s,respectively;when separation bed vibration amplitude (A)A=2.4-2.5 mm,separation bed vibration frequency (f) f=23-24 Hz,the desulfurization effect is the best.When vibration intensity (Γ)Γ=1.22,U_(in)=1.05 m/s,the particles have disordered contact and collision behavior.WhenΓ=14.89,U_(in)=3.18 m/s,the particles have a transition cataclastic collision.WhenΓ=5.80,U_(in)=2.55 m/s,the particles have directional collision behavior.It is determined that the OX axis is the transverse stable diffusion axis of the material,the OY axis is the longitudinal gradient transport axis of the material,and the OZ axis is the vertical density cascade distribution axis of the material.When separation time (T) T=0-10 s was the period of disorderly diffusion and mixing of particles,T=10-20 s was the period of directional migration and stratification of particles,and T=20-30 s was the period of cascade distribution and separation of particles.Finally,separation experiments conducted under optimal operating parameters demonstrated that the clean coal yield was 72.02%with a sulfur content of 0.98%.
基金supported by the National Natural Science Foundation of China(No.52175269)the Foundation for Innovative Research Groups of the National Natural Science Foundation of China(No.52021003)+2 种基金Science and Technology Research Project of Education Department of Jilin Province(JJKH20231146KJ,JJKH20241262KJ)Project ZR2024ME104 supported by Shandong Provincial Natural Science FoundationChina Postdoctoral Science Foundation(No.2024M751086).
文摘Numerous arthropods evolve and optimize sensory systems, enabling them to effectively adapt complex and competitive habitats. Typically, scorpions can precisely perceive the prey location with the lowest metabolic rate among invertebrates. This biological phenomenon contrasts sharply with engineered systems, which generally associates high accuracy with substantial energy consumption. Inspired by the Scorpion Compound Slit Sensilla (SCSS) with a stress field modulation strategy, a bionic positioning sensor with superior precision and minimal power consumption is developed for the first time, which utilizes the particular Minimum Positioning Units (MPUs) to efficiently locate vibration signals. The single MPU of the SCSS can recognize the direction of collinear loads by regulating the stress field distribution and further, the coupling action of three MPUs can realize all-angle vibration monitoring in plane. Experiments demonstrate that the bionic positioning sensor achieves 1.43 degrees of angle-error-free accuracy without additional energy supply. As a proof of concept, two bionic positioning sensors and machine learning algorithm are integrated to provide centimeter (cm)-accuracy target localization, ideally suited for the man-machine interaction. The novel design offers a new mechanism for the design of traditional positioning devices, improving precision and efficiency in both the meta-universe and real-world Internet-connected systems.
基金supported by Special key project of technological innovation and application development in Yongchuan District,Chongqing(2021yc-cxfz20002)the special funds of central government for guiding local science and technology developmentthe funds for the platform projects of professional technology innovation(CSTC2018ZYCXPT0006).
文摘To provide new insights into the development and utilization of Douchi artificial starters,three common strains(Aspergillus oryzae,Mucor racemosus,and Rhizopus oligosporus)were used to study their influence on the fermentation of Douchi.The results showed that the biogenic amine contents of the three types of Douchi were all within the safe range and far lower than those of traditional fermented Douchi.Aspergillus-type Douchi produced more free amino acids than the other two types of Douchi,and its umami taste was more prominent in sensory evaluation(P<0.01),while Mucor-type and Rhizopus-type Douchi produced more esters and pyrazines,making the aroma,sauce,and Douchi flavor more abundant.According to the Pearson and PLS analyses results,sweetness was significantly negatively correlated with phenylalanine,cysteine,and acetic acid(P<0.05),bitterness was significantly negatively correlated with malic acid(P<0.05),the sour taste was significantly positively correlated with citric acid and most free amino acids(P<0.05),while astringency was significantly negatively correlated with glucose(P<0.001).Thirteen volatile compounds such as furfuryl alcohol,phenethyl alcohol,and benzaldehyde caused the flavor difference of three types of Douchi.This study provides theoretical basis for the selection of starting strains for commercial Douchi production.
