Molecular chaperones are widely employed as additives in nature to trap proteins in the kinetic state,which inspire the development of kinetically trapped artificial supramolecular systems.Till now,such additive-contr...Molecular chaperones are widely employed as additives in nature to trap proteins in the kinetic state,which inspire the development of kinetically trapped artificial supramolecular systems.Till now,such additive-controlled approaches have enabled the stabilization of extended supramolecular structures in the kinetically trapped state,while discrete assemblies with sufficient kinetic persistence are scarce.In this study,a Pt(Ⅱ)-based discrete supramolecular system has been constructed by taking advantage of Cu+-bridged ions as chaperone-like additives.展开更多
基金sup-ported by the National Natural Science Foundation of China(nos.21922110,21871245,21674106,and 21704075)the Fundamental Research Funds for the Central Univer-sities(no.WK3450000005)the CAS Youth Innova-tion Promotion Association(no.Y201986).
文摘Molecular chaperones are widely employed as additives in nature to trap proteins in the kinetic state,which inspire the development of kinetically trapped artificial supramolecular systems.Till now,such additive-controlled approaches have enabled the stabilization of extended supramolecular structures in the kinetically trapped state,while discrete assemblies with sufficient kinetic persistence are scarce.In this study,a Pt(Ⅱ)-based discrete supramolecular system has been constructed by taking advantage of Cu+-bridged ions as chaperone-like additives.
