The global energy-related CO_(2) emissions have rapidly increased as the world economy heavily relied on fossil fuels.This paper explores the pressing challenge of CO_(2) emissions and highlights the role of porous me...The global energy-related CO_(2) emissions have rapidly increased as the world economy heavily relied on fossil fuels.This paper explores the pressing challenge of CO_(2) emissions and highlights the role of porous metal oxide materials in the electrocatalytic reduction of CO_(2)(CO_(2)RR).The focus is on the development of robust and selective catalysts,particularly metal and metal-oxide-based materials.Porous metal oxides offer high surface area,enhancing the accessibility to active sites and improving reaction kinetics.The tunability of these materials allows for tailored catalytic behavior,targeting optimized reaction mechanisms for CO_(2)RR.The work also discusses the various synthesis strategies and identifies key structural and compositional features,addressing challenges like high overpotential,poor selectivity,and low stability.Based on these insights,we suggest avenues for future research on porous metal oxide materials for electrochemical CO_(2) reduction.展开更多
Water scarcity is a global challenge,and solar evaporation technology offers a promising and eco-friendly solution for freshwater production.Photothermal conversion materials(PCMs)are crucial for solar evaporation.Imp...Water scarcity is a global challenge,and solar evaporation technology offers a promising and eco-friendly solution for freshwater production.Photothermal conversion materials(PCMs)are crucial for solar evaporation.Improving photothermal conversion efficiency and reducing water evaporation enthalpy are the two key strategies for the designing of PCMs.The desired PCMs that combine both of these properties remain a challenging task,even with the latest advancements in the field.Herein,we developed copper nanoparticles(NPs)with different conjugated nitrogen-doped microporous carbon coatings(Cu@C–N)as PCMs.The microporous carbon enveloping layer provides a highly efficient pathway for water transport and a nanoconfined environment that protects Cu NPs and facilitates the evaporation of water clusters,reducing the enthalpy of water evaporation.Meanwhile,the conjugated nitrogen nodes form strong metal-organic coordination bonds with the surface of copper NPs,acting as an energy bridge to achieve rapid energy transfer and provide high solar-to-vapor conversion efficiency.The Cu@C–N exhibited up to 89.4%solar-to-vapor conversion efficiency and an evaporation rate of 1.94 kgm^(−2) h^(−1) under one sun irradiation,outperforming conventional PCMs,including carbon-based materials and semiconductor materials.These findings offer an efficient design scheme for high-performance PCMs essential for solar evaporators to address global water scarcity.展开更多
Among central nervous system-associated malignancies,glioblastoma(GBM)is the most common and has the highest mortality rate.The high heterogeneity of GBM cell types and the complex tumor microenvironment frequently le...Among central nervous system-associated malignancies,glioblastoma(GBM)is the most common and has the highest mortality rate.The high heterogeneity of GBM cell types and the complex tumor microenvironment frequently lead to tumor recurrence and sudden relapse in patients treated with temozolomide.In precision medicine,research on GBM treatment is increasingly focusing on molecular subtyping to precisely characterize the cellular and molecular heterogeneity,as well as the refractory nature of GBM toward therapy.Deep understanding of the different molecular expression patterns of GBM subtypes is critical.Researchers have recently proposed tetra fractional or tripartite methods for detecting GBM molecular subtypes.The various molecular subtypes of GBM show significant differences in gene expression patterns and biological behaviors.These subtypes also exhibit high plasticity in their regulatory pathways,oncogene expression,tumor microenvironment alterations,and differential responses to standard therapy.Herein,we summarize the current molecular typing scheme of GBM and the major molecular/genetic characteristics of each subtype.Furthermore,we review the mesenchymal transition mechanisms of GBM under various regulators.展开更多
Hydrogen is known for its elevated energy density and environmental compatibility and is a promising alternative to fossil fuels.Alkaline water electrolysis utilizing renewable energy sources has emerged as a means to...Hydrogen is known for its elevated energy density and environmental compatibility and is a promising alternative to fossil fuels.Alkaline water electrolysis utilizing renewable energy sources has emerged as a means to obtain high-purity hydrogen.Nevertheless,electrocatalysts used in the process are fabricated using conventional wet chemical synthesis methods,such as sol-gel,hydrothermal,or surfactantassisted approaches,which often necessitate intricate pretreatment procedures and are vulnerable to post-treatment contamination.Therefore,this study introduces a streamlined and environmentally conscious one-step potential-cycling approach to generate a highly efficient trimetallic nickel-iron-copper electrocatalyst in situ on nickel foam.The synthesized material exhibited remarkable performance,requiring a mere 476 mV to drive electrochemical water splitting at 100 mA cm^(-2)current density in alkaline solution.Furthermore,this material was integrated into an anion exchange membrane watersplitting device and achieved an exceptionally high current density of 1 A cm^(-2)at a low cell voltage of2.13 V,outperforming the noble-metal benchmark(2.51 V).Additionally,ex situ characterizations were employed to detect transformations in the active sites during the catalytic process,revealing the structural transformations and providing inspiration for further design of electrocatalysts.展开更多
In High-Speed Railways(HSRs),the Train Control and Management System(TCMS)plays a crucial role.However,as the demand for train networks grows,the limitations of traditional wired connections have become apparent.This ...In High-Speed Railways(HSRs),the Train Control and Management System(TCMS)plays a crucial role.However,as the demand for train networks grows,the limitations of traditional wired connections have become apparent.This paper designs and implements a Wireless Train Communication Network(WTCN)to enhance the existing train network infrastructure.To address the challenges that wireless communication technology faces in the unique environment of high-speed rail,this study first analyzes various onboard environments and simulates several typical scenarios in the laboratory.Integrating the specific application scenarios and service characteristics of the high-speed train control network,we conduct measurements and validations of WiFi performance,exploring the specific impacts of different factors on throughput and delay.展开更多
Wild relatives possess potential genetic diversity for maize (<i><span style="font-family:Verdana;">Zea mays</span></i><span style="font-family:Verdana;"> L.) improvem...Wild relatives possess potential genetic diversity for maize (<i><span style="font-family:Verdana;">Zea mays</span></i><span style="font-family:Verdana;"> L.) improvement. Characterization of maize-</span><i><span style="font-family:Verdana;">mexicana</span></i><span style="font-family:Verdana;"> introgression lines (ILs) is of great value to diversify the genetic base and improve the maize germplasm. Four maize-</span><i><span style="font-family:Verdana;">mexicana</span></i><span style="font-family:Verdana;"> IL generations, </span><i><span style="font-family:Verdana;">i.e.</span></i><span style="font-family:Verdana;"> BC1, BC2, BC3, and RIL, were constructed under the elite inbred background of 48-2, elite inbred line that is widely used in maize breeding in Southwestern China, and were phenotyped in different years and genotyped with 56110 SNPs. The results indicated that 48-2 had higher phenotypic performances than all the characterized ILs on most of the agronomic traits. Compared with other ILs, BC2 individuals exhibited more similar performance to 48-2 on most traits and possessed the highest kernel ratio (66.5%). Population structure and principal component analysis indicated that BC3 individuals gathered closer to 48-2 and exhibited the lowest </span><i><span style="font-family:Verdana;">mexicana</span></i><span style="font-family:Verdana;">-introgression frequency (0.50%), while BC2 (29.06%) and RIL (18.52%) showed higher introgression frequency. The high level of genetic diversity observed in the maize-</span><i><span style="font-family:Verdana;">mexicana</span></i><span style="font-family:Verdana;"> ILs demonstrated that </span><i><span style="font-family:Verdana;">Z</span></i><span style="font-family:Verdana;">. </span><i><span style="font-family:Verdana;">mays</span></i><span style="font-family:Verdana;"> ssp. </span><i><span style="font-family:Verdana;">mexicana </span></i><span style="font-family:Verdana;">can serve as a potential source for the enrichment of maize germplasm.</span>展开更多
In the Southeast Margin of the Tibetan Plateau, low-velocity sedimentary layers that would significantly affect the accuracy of the H-κ stacking of receiver functions are widely distributed.In this study, we use tele...In the Southeast Margin of the Tibetan Plateau, low-velocity sedimentary layers that would significantly affect the accuracy of the H-κ stacking of receiver functions are widely distributed.In this study, we use teleseismic waveform data of 475 events from 97 temporary broadband seismometers deployed by ChinArray Phase I to obtain crustal thicknesses and Poisson's ratios within the Chuxiong-Simao Basin and adjacent area, employing an improved method in which the receiver functions are processed through a resonance-removal filter, and the H-κ stacking is time-corrected.Results show that the crustal thickness ranges from 30 to 55 km in the study area, reaching its thickest value in the northwest and thinning toward southwest, southeast and northeast.The apparent variation of crustal thickness around the Red River Fault supports the view of southeastern escape of the Tibetan Plateau.Relatively thin crustal thickness in the zone between Chuxiong City and the Red River Fault indicates possible uplift of mantle in this area.The positive correlation between crustal thickness and Poisson's ratio is likely to be related to lower crust thickening.Comparison of results obtained from different methods shows that the improved method used in our study can effectively remove the reverberation effect of sedimentary layers.展开更多
Due to the increasingly depleted limited fossil fuel resources,the development of renewable energy is the key to promote sustainable development which is an important part of the energy strategy[1].NH3 is one of most ...Due to the increasingly depleted limited fossil fuel resources,the development of renewable energy is the key to promote sustainable development which is an important part of the energy strategy[1].NH3 is one of most important and largest chemical productions in the world,it can be used as a feedstock for nitrogen fertilizer productions[2,3]or as a carbon-free energy carrier[4,5].展开更多
All-solid-state(ASS)Na-S batteries are promising for large-scale energy storage because of the incombustible solid electrolyte and avoiding the dissolution of intermediates.However,the poor contact between the active ...All-solid-state(ASS)Na-S batteries are promising for large-scale energy storage because of the incombustible solid electrolyte and avoiding the dissolution of intermediates.However,the poor contact between the active material and the solid electrolyte in the positive electrode leads to poor electrochemical performance.Here,we report an aqueous solution approach to fabricate Na3SbS4-coated SexS-based active materials for a Na-S battery working at room temperature.Compared with the Na3SbS4 and SexS mixed cathode,the coated cathode achieves significantly improved Na-ion diffusion kinetics and reduced impedance resistance.Additionally,the nanoparticle coating sustains the volume expansion of the cathode during cycling.The resulting batteries deliver an intensively enhanced specific capacity at various rates.Regardless of the mass loading,the Na3SbS4-coated cathode maintains a decent reversible capacity for the long-term discharge/charge cycling.The best battery achieves an initial discharge capacity of509 mAh g^-1 at a current density of 437.4 mA g^-1 and capacity retention of 98.9%for 100 cycles.To the best of our knowledge,this is one of the best room temperature ASS Na-S battery so far.This work demonstrates that Na3SbS4 is very promising for the cathode coating purpose for ASS Na-S batteries.展开更多
Solid/solid interface is the major challenge for high-performance solid-state batteries.Solid electrolytes(SEs)play a crucial role in the fabrication of effective interfaces in solid-state batteries.Herein,the electro...Solid/solid interface is the major challenge for high-performance solid-state batteries.Solid electrolytes(SEs)play a crucial role in the fabrication of effective interfaces in solid-state batteries.Herein,the electrolyte distribution with varied particle sizes is tuned to construct solid-state batteries with excellent performance at different operating temperatures.Solid-state batteries with the configuration S/L(small-sized SE in composite cathode and large-sized SE in electrolyte layer)show the best performance at room temperature(168 mA h g^(−1) at 0.2 C,retention of 99%,100 cycles)and−20°C(89 mA h g^(−1) at 0.05 C),while the configuration S/S displays better performance at elevated temperature.The superior performance of S/L battery is associated with faster lithium-ion dynamics due to the better solid/solid interface between active materials and electrolytes.Moreover,the inferior performance at 60℃is caused by the formation of voids and cracks in the electrolyte layer during cycling.In contrast,the S/S battery delivers superior performance at elevated operating temperature because of the integrated structure.This work confirms that tailoring electrolyte size has significant effect on fabricating all-climate solid-state batteries.展开更多
At present,the proportion of new energy in the power grid is increasing,and the random fluctuations in power output increase the risk of cascading failures in the power grid.In this paper,we propose a method for ident...At present,the proportion of new energy in the power grid is increasing,and the random fluctuations in power output increase the risk of cascading failures in the power grid.In this paper,we propose a method for identifying high-risk scenarios of interlocking faults in new energy power grids based on a deep embedding clustering(DEC)algorithm and apply it in a risk assessment of cascading failures in different operating scenarios for new energy power grids.First,considering the real-time operation status and system structure of new energy power grids,the scenario cascading failure risk indicator is established.Based on this indicator,the risk of cascading failure is calculated for the scenario set,the scenarios are clustered based on the DEC algorithm,and the scenarios with the highest indicators are selected as the significant risk scenario set.The results of simulations with an example power grid show that our method can effectively identify scenarios with a high risk of cascading failures from a large number of scenarios.展开更多
All-solid-state Li batteries(ASSLBs)using solid electrolytes(SEs)have gained significant attention in recent years considering the safety issue and their high energy density.Despite these advantages,the commercializat...All-solid-state Li batteries(ASSLBs)using solid electrolytes(SEs)have gained significant attention in recent years considering the safety issue and their high energy density.Despite these advantages,the commercialization of ASSLBs still faces challenges regarding the electrolyte/electrodes interfaces and growth of Li dendrites.Elemental doping is an effective and direct method to enhance the performance of SEs.Here,we report an Al-F co-doping strategy to improve the overall properties including ion conductivity,high voltage stability,and cathode and anode compatibility.Particularly,the Al-F co-doping enables the formation of a thin Li-Al alloy layer and fluoride interphases,thereby constructing a relatively stable interface and promoting uniform Li deposition.The similar merits of Al-F co-doping are also revealed in the Li-argyrodite series.ASSLBs assembled with these optimized electrolytes gain good electrochemical performance,demonstrating the universality of Al-F co-doping towards advanced SEs.展开更多
To meet the growing demand for wearable smart electronic devices,the development of flexible lithium-ion batteries(LIBs)is essential.Silicon is an ideal candidate for the anode material of flexible lithium-ion batteri...To meet the growing demand for wearable smart electronic devices,the development of flexible lithium-ion batteries(LIBs)is essential.Silicon is an ideal candidate for the anode material of flexible lithium-ion batteries due to its high specific capacity,low working potential,and earth abundance.The largest challenge in developing a flexible silicon anode is how to maintain structural integrity and ensure stable electrochemical reactions during external deformation.In this work,we propose a novel design for fabricating core–shell electrodes based on a copper nanowire(CuNW)array core and magnetron sputtered Si/C shell.The nanowire array structure has characteristics of bending under longitudinal stress and twisting under transverse stress,which helps to maintain the mechanical stability of the structure during electrode bending and cycling.The low-temperature annealing generates a small amount of Cu3Si alloy,which enhances the connection strength between Si and the conductive network and solves the poor conductivity problem of Si,which is known as a semiconductor material.This unique configuration design of CuNW@Si@C-400℃ leads to stable long cycle performance of 1109 mAh∙g^(-1) after 1000 cycles and excellent rate performance of 500 mAh∙g^(-1) at a current density of 10 A∙g^(-1).Furthermore,the CuNW@Si@C-400℃||LiFePO_(4)(LFP)full battery demonstrates excellent flexibility,with a capacity retention of more than 96%after 100 bends.This study provides a promising strategy for the development of flexible lithium-ion batteries.展开更多
Alkaline water electrolysis is an environmentally friendly and promising approach to produce hydrogen.However,high cost,low efficiency,and poor stability are roadblocks to commercialization of electrocatalysts.This wo...Alkaline water electrolysis is an environmentally friendly and promising approach to produce hydrogen.However,high cost,low efficiency,and poor stability are roadblocks to commercialization of electrocatalysts.This work aims to design and develop a highly efficient,durable,and cost-effective electrocatalyst toward water splitting through modifying metal–organic frameworks.The electrocatalytic performance and stability surpass those of noble metal benchmarks at high current density(1–10 A·cm^(−2)).Theoretical calculations and in situ Raman spectra reveal the electronic structure of the synthesized catalyst and the mechanism of the catalytic reaction process,which rationalizes that the high catalytic activity and stability at high current are attributed to the unique electronic structure of cobalt regulated by copper and the protection provided by carbon nanotubes formed in situ,respectively.In addition,this paper proposes that the desorption ability of the catalyst toward the products(H_(2)and O_(2)),rather than the adsorption ability toward the reactants(H^(+)or OH^(−)),is more important to the sustainable and stable electrochemical water splitting progress at high current density,which is a kinetic rather than thermodynamic dominating process.The findings provide alternative insights to design and employ high performance catalysts to fuel hydrogen production as a clean energy source to tackle the global energy crisis.展开更多
The battery management system is employed to monitor the external temperature of the lithium-ion battery in order to detect any potential overheating.However,this outside–in detection method often suffers from a lag ...The battery management system is employed to monitor the external temperature of the lithium-ion battery in order to detect any potential overheating.However,this outside–in detection method often suffers from a lag and is therefore unable to accurately predict the battery’s real-time state.Herein,an inside–out frequency response approach is used to accurately monitor the battery’s state at various temperatures in real-time and correlate it with the solid electrolyte interphase(SEI)evolution of the graphite electrode.The SEI evolution at temperatures of−15,25,60,and 90℃exhibits certain regular characteristics with temperature change.At a temperature of−15℃,the Li^(+)-solvent interaction of lithium-ion slowed down,resulting in a significant reduction in performance.At 25℃,a LiF-rich inorganic SEI was identified as forming,which facilitated lithium-ion transportation.However,high temperatures would induce decomposition of lithium hexafluorophosphate(LiPF_(6))and lithium-ion electrolyte.At the extreme temperature of 90℃,the SEI would be organic-rich,and Li_(x)P_(y)F_(z),a decomposition product of lithium salts,was further oxidized to Li_(x)PO_(y)F_(z),which led to a surge in the charge-transfer resistance at SEI(R_(sei))and a reduction in Coulombic efficiency(CE).This changing relationship can be recorded in real time from the inside out by electrochemical impedance spectroscopy(EIS)testing.This provides a new theoretical basis for the structural evolution of lithium-ion batteries and the regular characterization of EIS.展开更多
LiNi_(0.8)Co_(0.15)Al_(0.05)O_(2)(NCA) is a promising cathode for sulfide-based solid-state lithium batteries(ASSLBs)profiting from its high specific capacity and voltage plateau, which yielding high energy density. H...LiNi_(0.8)Co_(0.15)Al_(0.05)O_(2)(NCA) is a promising cathode for sulfide-based solid-state lithium batteries(ASSLBs)profiting from its high specific capacity and voltage plateau, which yielding high energy density. However, the inferior interfacial stability between the bare NCA and sulfides limits its electrochemical performance. Hereien, the dual-electrolyte layer is proposed to mitigate this effect and enhance the battery performances of NCA-based ASSLIBs. The Li_(3)InCl_6 wih high conductivity and excellent electrochemcial stability act both as an ion additives to promote Li-ion diffusion across the interface in the cathode and as a buffer layer between the cathode layer and the solid electrolyte layer to avoid side reactions and improve the interface stability. The corresponding battery exhibits high discharge capacities and superior cyclabilities at both room and elevated temperatures. It exhibits discharge performance of 237.04 and216.07 m Ah/g at 0.1 and 0.5 C, respectively, when cycled at 60 ℃, and sustains 95.9% of the capacity after100 cycles at 0.5 C. The work demonstrates a simple strategy to ensure the superior performances of NCA in sulfide-based ASSLBs.展开更多
Check dams are widely used throughout the world to tackle soil and water lOSS.However,the ffequency of extreme rainfall events has increased owing to global climate change and the main structure of check dam is gradua...Check dams are widely used throughout the world to tackle soil and water lOSS.However,the ffequency of extreme rainfall events has increased owing to global climate change and the main structure of check dam is gradually aging.which lead to an increase in the failure risk ofcheck dams.Thus.it is necessary to carry out the study on failure risk diagnosis and assessment of check dams.In the study,machine learning algorithms(ML).including random forests(RF).support vector machine(SVM),and logistic regression(LR).were used to integrate the environmental and engineering factors and then assess the risk of check dam failure due to the“7.26”rainstorm on Iuly 26.2017,in the Chabagou watershed.10cated in the hilly—gully region of the Loess Plateau.China.To veri~the generalizability of the model in this study。these models were used for the Wangmaogou catchment north of the Loess Plateau.The accuracy assessment by the receiver operating Characteristic fROCl curve indicated that the RF model with an area under the ROC curve fAUCl greater than 0.89 was the most precise model and had a higher general—ization ability.In addition.the model dataset was relatively smalI and easy to obtain.which make the risk modeling of check dam failure in the study has the potential for application in other regions.In the RF model.each factor selected was confirmed to be important,and the importance values for engineering factors were generally higher than those for the environmental factors.The risk map of check dam failure in the RF modelindicated that 56.34%of check dams in the study area had very high and high risks of dam failure under high—intensity rainfall in 2017.Based on the importance of factors and the risk map of check dam failure.the prevention and control measures for reducing the risk of check dam failure and promoting the construction of check dam are proposed.These proposals provide a scientific basis for the reinforcement of check dams and the future layout of check dams in the Chinese Loess Plateau.展开更多
AlGaN-based light-emitting diodes(LEDs)operating in the deep-ultraviolet(DUV)spectral range(210–280 nm)have demonstrated potential applications in physical sterilization.However,the poor external quantum efficiency(E...AlGaN-based light-emitting diodes(LEDs)operating in the deep-ultraviolet(DUV)spectral range(210–280 nm)have demonstrated potential applications in physical sterilization.However,the poor external quantum efficiency(EQE)hinders further advances in the emission performance of AlGaN-based DUV LEDs.Here,we demonstrate the performance of 270-nm AlGaN-based DUV LEDs beyond the state-of-the-art by exploiting the innovative combination of bandgap engineering and device craft.By adopting tailored multiple quantum wells(MQWs),a reflective Al reflector,a low-optical-loss tunneling junction(TJ)and a dielectric SiO_(2)insertion structure(IS-SiO_(2)),outstanding light output powers(LOPs)of 140.1 mW are achieved in our DUV LEDs at 850 mA.The EQEs of our DUV LEDs are 4.5 times greater than those of their conventional counterparts.This comprehensive approach overcomes the major difficulties commonly faced in the pursuit of high-performance AlGaN-based DUV LEDs,such as strong quantum-confined Stark effect(QCSE),severe optical absorption in the p-electrode/ohmic contact layer and poor transverse magnetic(TM)-polarized light extraction.Furthermore,the on-wafer electroluminescence characterization validated the scalability of our DUV LEDs to larger production scales.Our work is promising for the development of highly efficient AlGaN-based DUV LEDs.展开更多
The Scandinavian(SCA)pattern is an important climate signal in regulating the variability of summer extreme precipitation(SEP)over the eastern slopes of the Tibetan Plateau(ESTP).There is a strong negative correlation...The Scandinavian(SCA)pattern is an important climate signal in regulating the variability of summer extreme precipitation(SEP)over the eastern slopes of the Tibetan Plateau(ESTP).There is a strong negative correlation between the SCA pattern and SEP over the ESTP,with a correlation coefficient of-0.57.Moisture budget analysis showed that the dynamic component anomalies of both the zonal and vertical moisture advection induced by the SCA pattern play the dominant roles in extreme precipitation variability over the ESTP.These anomalies are solely linked to variations in zonal wind and vertical velocity.The anomalies of the SCA pattern propagate downstream through Rossby waves,leading to the formation of cyclonic circulations over northern East Asia and the Iranian Plateau.The westerlies on the southern side of these cyclonic circulations play a crucial role in influencing the development of significant anomalous westerlies over the ESTP.The anomalous westerlies bring climatologically moist air from the Tibetan Plateau(TP)to the ESTP,resulting in positive zonal moisture advection anomalies over the area.Furthermore,these anomalous westerlies transport climatologically warm air from the TP to the ESTP,leading to significant warm advection anomalies and vertical upward motion anomalies over the ESTP.The upward motion carries lower-tropospheric moisture upward,resulting in positive vertical moisture advection anomalies over the ESTP.The combination of these positive zonal and vertical moisture advection anomalies eventually leads to excessive SEP.展开更多
As environmental crises such as global warming become more and more serious due to the large amount of carbon dioxide emitted by the burning of fossil fuels,much attention has been paid to carbon neutrality.Hydrogen,w...As environmental crises such as global warming become more and more serious due to the large amount of carbon dioxide emitted by the burning of fossil fuels,much attention has been paid to carbon neutrality.Hydrogen,with zero carbon content,is a clean and renewable energy carrier having a large energy density.It is considered as one of the most desirable alternatives to fossil fuels.Electrochemical water splitting,unlike the steam reforming process accelerating fossil fuels depletion and CO_(2) emissions,can produce H_(2) powered by renewable energy such as solar or wind.As a promising way to promote carbon neutralization,hydrogen production by electrolysis of water is meaningful both in terms of scientific research and practical application.In order to drive electrochemical water splitting with low power consumption,efficient,durable and affordable electrocatalysts with low overpotentials are in urgent need.Therefore,this mini-review briefly introduces the current development status and mainstream obstacles of carbon-based materials used in electrochemical water splitting.展开更多
基金funded by the National Natural Science Foundation of China,China (Nos.52272303 and 52073212)the General Program of Municipal Natural Science Foundation of Tianjin,China (Nos.17JCYBJC22700 and 17JCYBJC17000)the State Scholarship Fund of China Scholarship Council,China (Nos.201709345012 and 201706255009)。
文摘The global energy-related CO_(2) emissions have rapidly increased as the world economy heavily relied on fossil fuels.This paper explores the pressing challenge of CO_(2) emissions and highlights the role of porous metal oxide materials in the electrocatalytic reduction of CO_(2)(CO_(2)RR).The focus is on the development of robust and selective catalysts,particularly metal and metal-oxide-based materials.Porous metal oxides offer high surface area,enhancing the accessibility to active sites and improving reaction kinetics.The tunability of these materials allows for tailored catalytic behavior,targeting optimized reaction mechanisms for CO_(2)RR.The work also discusses the various synthesis strategies and identifies key structural and compositional features,addressing challenges like high overpotential,poor selectivity,and low stability.Based on these insights,we suggest avenues for future research on porous metal oxide materials for electrochemical CO_(2) reduction.
基金supported by the National Natural Science Foundation of China(Grant Nos.52162012,52262014,22368019)Key Research and Development Project of Hainan Province(Grant Nos.ZDYF2022SHFZ053,ZDYF2021GXJS209)+1 种基金Science and Technology Innovation Talent Platform Fund for South China Sea New Star of Hainan Province(Grant No.NHXXRCXM202305)Open Research Project of State Key Laboratory of Marine Resource Utilization in South China Sea(Grant No.MRUKF2023020).
文摘Water scarcity is a global challenge,and solar evaporation technology offers a promising and eco-friendly solution for freshwater production.Photothermal conversion materials(PCMs)are crucial for solar evaporation.Improving photothermal conversion efficiency and reducing water evaporation enthalpy are the two key strategies for the designing of PCMs.The desired PCMs that combine both of these properties remain a challenging task,even with the latest advancements in the field.Herein,we developed copper nanoparticles(NPs)with different conjugated nitrogen-doped microporous carbon coatings(Cu@C–N)as PCMs.The microporous carbon enveloping layer provides a highly efficient pathway for water transport and a nanoconfined environment that protects Cu NPs and facilitates the evaporation of water clusters,reducing the enthalpy of water evaporation.Meanwhile,the conjugated nitrogen nodes form strong metal-organic coordination bonds with the surface of copper NPs,acting as an energy bridge to achieve rapid energy transfer and provide high solar-to-vapor conversion efficiency.The Cu@C–N exhibited up to 89.4%solar-to-vapor conversion efficiency and an evaporation rate of 1.94 kgm^(−2) h^(−1) under one sun irradiation,outperforming conventional PCMs,including carbon-based materials and semiconductor materials.These findings offer an efficient design scheme for high-performance PCMs essential for solar evaporators to address global water scarcity.
基金supported by grants from the National Natural Science Foundation of China(Grant No.82172660)Hebei Province Graduate Student Innovation Project(Grant No.CXZZBS2023001)Baoding Natural Science Foundation(Grant No.H2272P015).
文摘Among central nervous system-associated malignancies,glioblastoma(GBM)is the most common and has the highest mortality rate.The high heterogeneity of GBM cell types and the complex tumor microenvironment frequently lead to tumor recurrence and sudden relapse in patients treated with temozolomide.In precision medicine,research on GBM treatment is increasingly focusing on molecular subtyping to precisely characterize the cellular and molecular heterogeneity,as well as the refractory nature of GBM toward therapy.Deep understanding of the different molecular expression patterns of GBM subtypes is critical.Researchers have recently proposed tetra fractional or tripartite methods for detecting GBM molecular subtypes.The various molecular subtypes of GBM show significant differences in gene expression patterns and biological behaviors.These subtypes also exhibit high plasticity in their regulatory pathways,oncogene expression,tumor microenvironment alterations,and differential responses to standard therapy.Herein,we summarize the current molecular typing scheme of GBM and the major molecular/genetic characteristics of each subtype.Furthermore,we review the mesenchymal transition mechanisms of GBM under various regulators.
基金financially supported by the National Natural Science Foundation of China(21975100).
文摘Hydrogen is known for its elevated energy density and environmental compatibility and is a promising alternative to fossil fuels.Alkaline water electrolysis utilizing renewable energy sources has emerged as a means to obtain high-purity hydrogen.Nevertheless,electrocatalysts used in the process are fabricated using conventional wet chemical synthesis methods,such as sol-gel,hydrothermal,or surfactantassisted approaches,which often necessitate intricate pretreatment procedures and are vulnerable to post-treatment contamination.Therefore,this study introduces a streamlined and environmentally conscious one-step potential-cycling approach to generate a highly efficient trimetallic nickel-iron-copper electrocatalyst in situ on nickel foam.The synthesized material exhibited remarkable performance,requiring a mere 476 mV to drive electrochemical water splitting at 100 mA cm^(-2)current density in alkaline solution.Furthermore,this material was integrated into an anion exchange membrane watersplitting device and achieved an exceptionally high current density of 1 A cm^(-2)at a low cell voltage of2.13 V,outperforming the noble-metal benchmark(2.51 V).Additionally,ex situ characterizations were employed to detect transformations in the active sites during the catalytic process,revealing the structural transformations and providing inspiration for further design of electrocatalysts.
基金support from the Beijing Engineering Research Center of High-speed Railway Broadband Mobile Communications(BHRC-2024-1)Beijing Jiaotong University,the National Natural Science Foundation of China(U21A20445).
文摘In High-Speed Railways(HSRs),the Train Control and Management System(TCMS)plays a crucial role.However,as the demand for train networks grows,the limitations of traditional wired connections have become apparent.This paper designs and implements a Wireless Train Communication Network(WTCN)to enhance the existing train network infrastructure.To address the challenges that wireless communication technology faces in the unique environment of high-speed rail,this study first analyzes various onboard environments and simulates several typical scenarios in the laboratory.Integrating the specific application scenarios and service characteristics of the high-speed train control network,we conduct measurements and validations of WiFi performance,exploring the specific impacts of different factors on throughput and delay.
文摘Wild relatives possess potential genetic diversity for maize (<i><span style="font-family:Verdana;">Zea mays</span></i><span style="font-family:Verdana;"> L.) improvement. Characterization of maize-</span><i><span style="font-family:Verdana;">mexicana</span></i><span style="font-family:Verdana;"> introgression lines (ILs) is of great value to diversify the genetic base and improve the maize germplasm. Four maize-</span><i><span style="font-family:Verdana;">mexicana</span></i><span style="font-family:Verdana;"> IL generations, </span><i><span style="font-family:Verdana;">i.e.</span></i><span style="font-family:Verdana;"> BC1, BC2, BC3, and RIL, were constructed under the elite inbred background of 48-2, elite inbred line that is widely used in maize breeding in Southwestern China, and were phenotyped in different years and genotyped with 56110 SNPs. The results indicated that 48-2 had higher phenotypic performances than all the characterized ILs on most of the agronomic traits. Compared with other ILs, BC2 individuals exhibited more similar performance to 48-2 on most traits and possessed the highest kernel ratio (66.5%). Population structure and principal component analysis indicated that BC3 individuals gathered closer to 48-2 and exhibited the lowest </span><i><span style="font-family:Verdana;">mexicana</span></i><span style="font-family:Verdana;">-introgression frequency (0.50%), while BC2 (29.06%) and RIL (18.52%) showed higher introgression frequency. The high level of genetic diversity observed in the maize-</span><i><span style="font-family:Verdana;">mexicana</span></i><span style="font-family:Verdana;"> ILs demonstrated that </span><i><span style="font-family:Verdana;">Z</span></i><span style="font-family:Verdana;">. </span><i><span style="font-family:Verdana;">mays</span></i><span style="font-family:Verdana;"> ssp. </span><i><span style="font-family:Verdana;">mexicana </span></i><span style="font-family:Verdana;">can serve as a potential source for the enrichment of maize germplasm.</span>
基金supported by the National Natural Science Foundation of China (Project 41730212)the Basic Research Project of the Institute of Earthquake Forecasting, China Earthquake Administration (2017IES0102)
文摘In the Southeast Margin of the Tibetan Plateau, low-velocity sedimentary layers that would significantly affect the accuracy of the H-κ stacking of receiver functions are widely distributed.In this study, we use teleseismic waveform data of 475 events from 97 temporary broadband seismometers deployed by ChinArray Phase I to obtain crustal thicknesses and Poisson's ratios within the Chuxiong-Simao Basin and adjacent area, employing an improved method in which the receiver functions are processed through a resonance-removal filter, and the H-κ stacking is time-corrected.Results show that the crustal thickness ranges from 30 to 55 km in the study area, reaching its thickest value in the northwest and thinning toward southwest, southeast and northeast.The apparent variation of crustal thickness around the Red River Fault supports the view of southeastern escape of the Tibetan Plateau.Relatively thin crustal thickness in the zone between Chuxiong City and the Red River Fault indicates possible uplift of mantle in this area.The positive correlation between crustal thickness and Poisson's ratio is likely to be related to lower crust thickening.Comparison of results obtained from different methods shows that the improved method used in our study can effectively remove the reverberation effect of sedimentary layers.
基金supported by the National Key R&D Program of China(No.2016YFC1102802)the Natural Science Foundation of Jilin Province(No.20200201020JC)the Open Project of State Key Laboratory of Supramolecular Structure and Materials(No.sklssm202011)。
文摘Due to the increasingly depleted limited fossil fuel resources,the development of renewable energy is the key to promote sustainable development which is an important part of the energy strategy[1].NH3 is one of most important and largest chemical productions in the world,it can be used as a feedstock for nitrogen fertilizer productions[2,3]or as a carbon-free energy carrier[4,5].
基金supported by the National Key R&D Program of China(grant no.2018YFB0104300)the Natural Science Foundation of Hebei Province(E2018203301)。
文摘All-solid-state(ASS)Na-S batteries are promising for large-scale energy storage because of the incombustible solid electrolyte and avoiding the dissolution of intermediates.However,the poor contact between the active material and the solid electrolyte in the positive electrode leads to poor electrochemical performance.Here,we report an aqueous solution approach to fabricate Na3SbS4-coated SexS-based active materials for a Na-S battery working at room temperature.Compared with the Na3SbS4 and SexS mixed cathode,the coated cathode achieves significantly improved Na-ion diffusion kinetics and reduced impedance resistance.Additionally,the nanoparticle coating sustains the volume expansion of the cathode during cycling.The resulting batteries deliver an intensively enhanced specific capacity at various rates.Regardless of the mass loading,the Na3SbS4-coated cathode maintains a decent reversible capacity for the long-term discharge/charge cycling.The best battery achieves an initial discharge capacity of509 mAh g^-1 at a current density of 437.4 mA g^-1 and capacity retention of 98.9%for 100 cycles.To the best of our knowledge,this is one of the best room temperature ASS Na-S battery so far.This work demonstrates that Na3SbS4 is very promising for the cathode coating purpose for ASS Na-S batteries.
基金supported by the National Natural Science Foundation of China(No.51821005)。
文摘Solid/solid interface is the major challenge for high-performance solid-state batteries.Solid electrolytes(SEs)play a crucial role in the fabrication of effective interfaces in solid-state batteries.Herein,the electrolyte distribution with varied particle sizes is tuned to construct solid-state batteries with excellent performance at different operating temperatures.Solid-state batteries with the configuration S/L(small-sized SE in composite cathode and large-sized SE in electrolyte layer)show the best performance at room temperature(168 mA h g^(−1) at 0.2 C,retention of 99%,100 cycles)and−20°C(89 mA h g^(−1) at 0.05 C),while the configuration S/S displays better performance at elevated temperature.The superior performance of S/L battery is associated with faster lithium-ion dynamics due to the better solid/solid interface between active materials and electrolytes.Moreover,the inferior performance at 60℃is caused by the formation of voids and cracks in the electrolyte layer during cycling.In contrast,the S/S battery delivers superior performance at elevated operating temperature because of the integrated structure.This work confirms that tailoring electrolyte size has significant effect on fabricating all-climate solid-state batteries.
基金funded by the State Grid Limited Science and Technology Project of China,Grant Number SGSXDK00DJJS2200144.
文摘At present,the proportion of new energy in the power grid is increasing,and the random fluctuations in power output increase the risk of cascading failures in the power grid.In this paper,we propose a method for identifying high-risk scenarios of interlocking faults in new energy power grids based on a deep embedding clustering(DEC)algorithm and apply it in a risk assessment of cascading failures in different operating scenarios for new energy power grids.First,considering the real-time operation status and system structure of new energy power grids,the scenario cascading failure risk indicator is established.Based on this indicator,the risk of cascading failure is calculated for the scenario set,the scenarios are clustered based on the DEC algorithm,and the scenarios with the highest indicators are selected as the significant risk scenario set.The results of simulations with an example power grid show that our method can effectively identify scenarios with a high risk of cascading failures from a large number of scenarios.
基金supported by the National Natural Science Foundation of China(Nos.52172243,52371215)。
文摘All-solid-state Li batteries(ASSLBs)using solid electrolytes(SEs)have gained significant attention in recent years considering the safety issue and their high energy density.Despite these advantages,the commercialization of ASSLBs still faces challenges regarding the electrolyte/electrodes interfaces and growth of Li dendrites.Elemental doping is an effective and direct method to enhance the performance of SEs.Here,we report an Al-F co-doping strategy to improve the overall properties including ion conductivity,high voltage stability,and cathode and anode compatibility.Particularly,the Al-F co-doping enables the formation of a thin Li-Al alloy layer and fluoride interphases,thereby constructing a relatively stable interface and promoting uniform Li deposition.The similar merits of Al-F co-doping are also revealed in the Li-argyrodite series.ASSLBs assembled with these optimized electrolytes gain good electrochemical performance,demonstrating the universality of Al-F co-doping towards advanced SEs.
基金Financial supports from the National Natural Science Foundation of China(No.22209075)the Natural Science Foundation of Chongqing(No.2022NSCQ-MSX4268)+1 种基金the Postdoctoral Innovation Talents Support Plan of Chongqing(No.CQBX2021012)the Scientific Research Project of Fujian Provincial Department of Education(No.JAT220530)are acknowledged.
文摘To meet the growing demand for wearable smart electronic devices,the development of flexible lithium-ion batteries(LIBs)is essential.Silicon is an ideal candidate for the anode material of flexible lithium-ion batteries due to its high specific capacity,low working potential,and earth abundance.The largest challenge in developing a flexible silicon anode is how to maintain structural integrity and ensure stable electrochemical reactions during external deformation.In this work,we propose a novel design for fabricating core–shell electrodes based on a copper nanowire(CuNW)array core and magnetron sputtered Si/C shell.The nanowire array structure has characteristics of bending under longitudinal stress and twisting under transverse stress,which helps to maintain the mechanical stability of the structure during electrode bending and cycling.The low-temperature annealing generates a small amount of Cu3Si alloy,which enhances the connection strength between Si and the conductive network and solves the poor conductivity problem of Si,which is known as a semiconductor material.This unique configuration design of CuNW@Si@C-400℃ leads to stable long cycle performance of 1109 mAh∙g^(-1) after 1000 cycles and excellent rate performance of 500 mAh∙g^(-1) at a current density of 10 A∙g^(-1).Furthermore,the CuNW@Si@C-400℃||LiFePO_(4)(LFP)full battery demonstrates excellent flexibility,with a capacity retention of more than 96%after 100 bends.This study provides a promising strategy for the development of flexible lithium-ion batteries.
基金support by the program for JLU Science and Technology Innovative Research Team(JLUSTIRT).
文摘Alkaline water electrolysis is an environmentally friendly and promising approach to produce hydrogen.However,high cost,low efficiency,and poor stability are roadblocks to commercialization of electrocatalysts.This work aims to design and develop a highly efficient,durable,and cost-effective electrocatalyst toward water splitting through modifying metal–organic frameworks.The electrocatalytic performance and stability surpass those of noble metal benchmarks at high current density(1–10 A·cm^(−2)).Theoretical calculations and in situ Raman spectra reveal the electronic structure of the synthesized catalyst and the mechanism of the catalytic reaction process,which rationalizes that the high catalytic activity and stability at high current are attributed to the unique electronic structure of cobalt regulated by copper and the protection provided by carbon nanotubes formed in situ,respectively.In addition,this paper proposes that the desorption ability of the catalyst toward the products(H_(2)and O_(2)),rather than the adsorption ability toward the reactants(H^(+)or OH^(−)),is more important to the sustainable and stable electrochemical water splitting progress at high current density,which is a kinetic rather than thermodynamic dominating process.The findings provide alternative insights to design and employ high performance catalysts to fuel hydrogen production as a clean energy source to tackle the global energy crisis.
基金supported by Natural Science Foundation of Chongqing(No.2022NSCQ-MSX4268)National Natural Science Foundation of China(No.22209075).
文摘The battery management system is employed to monitor the external temperature of the lithium-ion battery in order to detect any potential overheating.However,this outside–in detection method often suffers from a lag and is therefore unable to accurately predict the battery’s real-time state.Herein,an inside–out frequency response approach is used to accurately monitor the battery’s state at various temperatures in real-time and correlate it with the solid electrolyte interphase(SEI)evolution of the graphite electrode.The SEI evolution at temperatures of−15,25,60,and 90℃exhibits certain regular characteristics with temperature change.At a temperature of−15℃,the Li^(+)-solvent interaction of lithium-ion slowed down,resulting in a significant reduction in performance.At 25℃,a LiF-rich inorganic SEI was identified as forming,which facilitated lithium-ion transportation.However,high temperatures would induce decomposition of lithium hexafluorophosphate(LiPF_(6))and lithium-ion electrolyte.At the extreme temperature of 90℃,the SEI would be organic-rich,and Li_(x)P_(y)F_(z),a decomposition product of lithium salts,was further oxidized to Li_(x)PO_(y)F_(z),which led to a surge in the charge-transfer resistance at SEI(R_(sei))and a reduction in Coulombic efficiency(CE).This changing relationship can be recorded in real time from the inside out by electrochemical impedance spectroscopy(EIS)testing.This provides a new theoretical basis for the structural evolution of lithium-ion batteries and the regular characterization of EIS.
基金supported by the National Key Research and Development Program (No.2021YFB2500200)the National Natural Science Foundation of China (No.52177214)supported by China Fujian Energy Devices Science and Technology Innovation Laboratory Open Fund (No.21C-OP202211)。
文摘LiNi_(0.8)Co_(0.15)Al_(0.05)O_(2)(NCA) is a promising cathode for sulfide-based solid-state lithium batteries(ASSLBs)profiting from its high specific capacity and voltage plateau, which yielding high energy density. However, the inferior interfacial stability between the bare NCA and sulfides limits its electrochemical performance. Hereien, the dual-electrolyte layer is proposed to mitigate this effect and enhance the battery performances of NCA-based ASSLIBs. The Li_(3)InCl_6 wih high conductivity and excellent electrochemcial stability act both as an ion additives to promote Li-ion diffusion across the interface in the cathode and as a buffer layer between the cathode layer and the solid electrolyte layer to avoid side reactions and improve the interface stability. The corresponding battery exhibits high discharge capacities and superior cyclabilities at both room and elevated temperatures. It exhibits discharge performance of 237.04 and216.07 m Ah/g at 0.1 and 0.5 C, respectively, when cycled at 60 ℃, and sustains 95.9% of the capacity after100 cycles at 0.5 C. The work demonstrates a simple strategy to ensure the superior performances of NCA in sulfide-based ASSLBs.
基金financial support was provided by National Natural Science Foundation of China(U2243213)Jianqiao Han reports financial support was provided by National Natural Science Foundation of China(42177327)Jianqiao Han reports financial support was provided by National Natural Science Foundation of China(U2243212).
文摘Check dams are widely used throughout the world to tackle soil and water lOSS.However,the ffequency of extreme rainfall events has increased owing to global climate change and the main structure of check dam is gradually aging.which lead to an increase in the failure risk ofcheck dams.Thus.it is necessary to carry out the study on failure risk diagnosis and assessment of check dams.In the study,machine learning algorithms(ML).including random forests(RF).support vector machine(SVM),and logistic regression(LR).were used to integrate the environmental and engineering factors and then assess the risk of check dam failure due to the“7.26”rainstorm on Iuly 26.2017,in the Chabagou watershed.10cated in the hilly—gully region of the Loess Plateau.China.To veri~the generalizability of the model in this study。these models were used for the Wangmaogou catchment north of the Loess Plateau.The accuracy assessment by the receiver operating Characteristic fROCl curve indicated that the RF model with an area under the ROC curve fAUCl greater than 0.89 was the most precise model and had a higher general—ization ability.In addition.the model dataset was relatively smalI and easy to obtain.which make the risk modeling of check dam failure in the study has the potential for application in other regions.In the RF model.each factor selected was confirmed to be important,and the importance values for engineering factors were generally higher than those for the environmental factors.The risk map of check dam failure in the RF modelindicated that 56.34%of check dams in the study area had very high and high risks of dam failure under high—intensity rainfall in 2017.Based on the importance of factors and the risk map of check dam failure.the prevention and control measures for reducing the risk of check dam failure and promoting the construction of check dam are proposed.These proposals provide a scientific basis for the reinforcement of check dams and the future layout of check dams in the Chinese Loess Plateau.
基金financial support from the National Natural Science Foundation of China(Nos.52075394 and 51675386)the National Key Research and Development Program of China(Nos.2021YFB3600200 and 2022YFB3603603)+1 种基金the Key Research and Development Program of Hubei Province(No.2023BAB137)the Knowledge Innovation Program of Wuhan-Basic Research,the Fundamental Research Funds for the Central Universities,and the National Youth Talent Support Program.
文摘AlGaN-based light-emitting diodes(LEDs)operating in the deep-ultraviolet(DUV)spectral range(210–280 nm)have demonstrated potential applications in physical sterilization.However,the poor external quantum efficiency(EQE)hinders further advances in the emission performance of AlGaN-based DUV LEDs.Here,we demonstrate the performance of 270-nm AlGaN-based DUV LEDs beyond the state-of-the-art by exploiting the innovative combination of bandgap engineering and device craft.By adopting tailored multiple quantum wells(MQWs),a reflective Al reflector,a low-optical-loss tunneling junction(TJ)and a dielectric SiO_(2)insertion structure(IS-SiO_(2)),outstanding light output powers(LOPs)of 140.1 mW are achieved in our DUV LEDs at 850 mA.The EQEs of our DUV LEDs are 4.5 times greater than those of their conventional counterparts.This comprehensive approach overcomes the major difficulties commonly faced in the pursuit of high-performance AlGaN-based DUV LEDs,such as strong quantum-confined Stark effect(QCSE),severe optical absorption in the p-electrode/ohmic contact layer and poor transverse magnetic(TM)-polarized light extraction.Furthermore,the on-wafer electroluminescence characterization validated the scalability of our DUV LEDs to larger production scales.Our work is promising for the development of highly efficient AlGaN-based DUV LEDs.
基金financially supported by the National Natural Science Foundation of China(Grant Nos.U20A2097,U2442210 and 42175042)Natural Science Foundation of Sichuan Province(Grant No.2024NSFTD0017)。
文摘The Scandinavian(SCA)pattern is an important climate signal in regulating the variability of summer extreme precipitation(SEP)over the eastern slopes of the Tibetan Plateau(ESTP).There is a strong negative correlation between the SCA pattern and SEP over the ESTP,with a correlation coefficient of-0.57.Moisture budget analysis showed that the dynamic component anomalies of both the zonal and vertical moisture advection induced by the SCA pattern play the dominant roles in extreme precipitation variability over the ESTP.These anomalies are solely linked to variations in zonal wind and vertical velocity.The anomalies of the SCA pattern propagate downstream through Rossby waves,leading to the formation of cyclonic circulations over northern East Asia and the Iranian Plateau.The westerlies on the southern side of these cyclonic circulations play a crucial role in influencing the development of significant anomalous westerlies over the ESTP.The anomalous westerlies bring climatologically moist air from the Tibetan Plateau(TP)to the ESTP,resulting in positive zonal moisture advection anomalies over the area.Furthermore,these anomalous westerlies transport climatologically warm air from the TP to the ESTP,leading to significant warm advection anomalies and vertical upward motion anomalies over the ESTP.The upward motion carries lower-tropospheric moisture upward,resulting in positive vertical moisture advection anomalies over the ESTP.The combination of these positive zonal and vertical moisture advection anomalies eventually leads to excessive SEP.
基金supported by the Natural Science Foundation of Jilin Province(No.20200201020JC)Key Research Project of the Education Department of Jilin Province of China(No.JJKH20211046KJ)。
文摘As environmental crises such as global warming become more and more serious due to the large amount of carbon dioxide emitted by the burning of fossil fuels,much attention has been paid to carbon neutrality.Hydrogen,with zero carbon content,is a clean and renewable energy carrier having a large energy density.It is considered as one of the most desirable alternatives to fossil fuels.Electrochemical water splitting,unlike the steam reforming process accelerating fossil fuels depletion and CO_(2) emissions,can produce H_(2) powered by renewable energy such as solar or wind.As a promising way to promote carbon neutralization,hydrogen production by electrolysis of water is meaningful both in terms of scientific research and practical application.In order to drive electrochemical water splitting with low power consumption,efficient,durable and affordable electrocatalysts with low overpotentials are in urgent need.Therefore,this mini-review briefly introduces the current development status and mainstream obstacles of carbon-based materials used in electrochemical water splitting.
