Titania nanowires(TiO2-NW)with tunable aspect ratios and morphologies were directly synthesized using a simple alcohol-thermal technique.Specifically,ethanol and acetic acid were used as solvents and lithium ion was u...Titania nanowires(TiO2-NW)with tunable aspect ratios and morphologies were directly synthesized using a simple alcohol-thermal technique.Specifically,ethanol and acetic acid were used as solvents and lithium ion was used as the capping agent to promote the conversion of titanium butoxide into TiO2-NW.The morphologies and crystal phases of TiO2-NW were determined by the molar ratio of solvents and the content(mol%)of lithium ion.The band gap of TiO2-NW with pure anatase phase is slightly bigger than that of TiO2-NW with a mixture of anatase and rutile phases.All TiO2-NW could achieve effective decolorization of methyl blue(the decolorization rate is over 95%)after 35-min ultraviolet(UV)irradiation.展开更多
基金financially supported by the National Natural Science Foundation of China (No. 51408528)the Natural Science Foundation of Hebei Province, China (No. E2014203089)
文摘Titania nanowires(TiO2-NW)with tunable aspect ratios and morphologies were directly synthesized using a simple alcohol-thermal technique.Specifically,ethanol and acetic acid were used as solvents and lithium ion was used as the capping agent to promote the conversion of titanium butoxide into TiO2-NW.The morphologies and crystal phases of TiO2-NW were determined by the molar ratio of solvents and the content(mol%)of lithium ion.The band gap of TiO2-NW with pure anatase phase is slightly bigger than that of TiO2-NW with a mixture of anatase and rutile phases.All TiO2-NW could achieve effective decolorization of methyl blue(the decolorization rate is over 95%)after 35-min ultraviolet(UV)irradiation.