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BODIPY荧光探针的合成及次氯酸检测的综合实验
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作者 刘振波 肖佳月 +4 位作者 刘爽 姜文硕 兰欣宇 贾文萱 李天愉 《大学化学》 CAS 2023年第5期193-201,共9页
有机实验和仪器分析实验是本科生阶段化学教学的重点内容,虽然现有的教学实验内容已十分丰富与完善,但缺少两者之间的融合以及与科研领域的联系。针对上述不足,我们将科学研究前沿和热点的荧光检测技术引入教学实践。实验通过对BODIPY ... 有机实验和仪器分析实验是本科生阶段化学教学的重点内容,虽然现有的教学实验内容已十分丰富与完善,但缺少两者之间的融合以及与科研领域的联系。针对上述不足,我们将科学研究前沿和热点的荧光检测技术引入教学实践。实验通过对BODIPY (氟硼二吡咯)荧光染料结构的设计改良,合成一种具有快速响应、选择性高和灵敏度好的新型次氯酸荧光探针,对荧光探针结构进行表征,并测定荧光探针的荧光性质。通过对探针结构与荧光性质之间关系的研究,有助于加深学生荧光发光原理的理解。实验内容涵盖有机合成、产物仪器表征、光谱分析等方面,综合性强且易于学生操作。教学实践过程有助于培养学生的科学思维、理论与实践相结合的能力。 展开更多
关键词 荧光探针 有机实验 仪器分析实验 综合性
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Reinforcement of Lignin-Based Phenol-Formaldehyde Adhesive with Nano-Crystalline Cellulose (NCC): Curing Behavior and Bonding Property of Plywood 被引量:1
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作者 zhenbo liu Yaolin Zhang +1 位作者 Xiangming Wang Denis Rodrigue 《Materials Sciences and Applications》 2015年第6期567-575,共9页
The curing behavior of lignin-based phenol-formaldehyde (LPF) resin with different contents of nano-crystalline cellulose (NCC) was studied by differential scanning calorimetry (DSC) at different heating rates (5, 10 ... The curing behavior of lignin-based phenol-formaldehyde (LPF) resin with different contents of nano-crystalline cellulose (NCC) was studied by differential scanning calorimetry (DSC) at different heating rates (5, 10 and 20&degC/min) and the bonding property was evaluated by the wet shear strength and wood failure of two-ply plywood panels after soaking in water (48 hours at room temperature and followed by 1-hour boiling). The test results indicated that the NCC content had little influence on the peak temperature, activation energy and the total heat of reaction of LPF resin at 5 and 10&degC/min. But at 20&degC/min, LPF0.00% (LPF resin without NCC) showed the highest total heat of reaction, while LPF0.25% (LPF resin containing 0.25% NCC content) and LPF0.50% (LPF resin containing 0.50% NCC content) gave the lowest value. The wet shear strength was affected by the NCC content to a certain extent. With regard to the results of one-way analysis of variance, the bonding quality could be improved by NCC and the optimum NCC content ranged from 0.25% to 0.50%. The wood failure was also affected by the NCC content, but the trend with respect to NCC content was not clear. 展开更多
关键词 Lignin-Based Phenol-Formaldehyde Resin (LPF) NANO-CRYSTALLINE CELLULOSE (NCC) Curing Behavior Bonding Properties PLYWOOD
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Prediction of lute acoustic quality based on soundboard vibration performance using multiple choice model
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作者 Yang Yang zhenbo liu Yixing liu 《Journal of Forestry Research》 SCIE CAS CSCD 2017年第4期855-861,共7页
The vibrational performance of wood materials critical affects the acoustic quality of a lute. The purpose of this research was to apply a multiple choice model to predict the quality of musical instruments based on d... The vibrational performance of wood materials critical affects the acoustic quality of a lute. The purpose of this research was to apply a multiple choice model to predict the quality of musical instruments based on data on lute soundboard vibrational properties of Paulownia wood. In the lute production, lute material selection mainly depends on the subjective evaluation of technicians, which is not only inefficient, but inaccurate. In this study, nine lutes were fabricated. Using the multiple selection model, the lute tone quality was predicted by the soundboard wood vibration data. Compared with the actual value, the dependent value predicted by the count of observations with the maximum probability had 22 erroneous judgments. The model precision is 87.78%. The results confirmed that the prediction model can be used as a guideline for the selection of the soundboard wood in musical instrument plants. 展开更多
关键词 Multiple choice model Musical instrument quality Normal distribution Vibration performance
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Flexible Nanopaper Composed of Wood-Derived Nanofibrillated Cellulose and Graphene Building Blocks
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作者 Qing Li Ming Dai +13 位作者 Xueren Qian Tian liu zhenbo liu Yu liu Ming Chen Wang He Suqing Zeng Yu Meng Chenchen Dai Jing Shen Yingtao liu Wenshuai Chen Wenbo liu Ping Lu 《Journal of Renewable Materials》 SCIE EI 2021年第3期451-461,共11页
Nanopaper has attracted considerable interest in the fields of films and paper research.However,the challenge of integrating the many advantages of nanopaper still remains.Herein,we developed a facile strategy to fabr... Nanopaper has attracted considerable interest in the fields of films and paper research.However,the challenge of integrating the many advantages of nanopaper still remains.Herein,we developed a facile strategy to fabricate multifunctional nanocomposite paper(NGCP)composed of wood-derived nanofibrillated cellulose(NFC)and graphene as building blocks.NFC suspension was consisted of long and entangled NFCs(10–30 nm in width)and their aggregates.Before NGCP formation,NFC was chemically modified with a silane coupling agent to ensure that it could interact strongly with graphene in NGCP.The resulting NGCP samples were flexible and could be bent repeatedly without any structural damage.Within the NGCP samples,the high aspect ratio of NFC made a major contribution to its high mechanical strength,whereas the sheet-like graphene endowed the NGCP with electrical resistance and electrochemical activity.The mechanical strength of the NGCP samples decreased as their graphene content increased.However,the electrical resistance and electrochemical activity of the NGCP samples both rose with increasing content of graphene.The NGCPs still kept advantageous mechanical properties even at high temperatures around 300℃ because of the high thermal stability of NFCs and their strong entangled web-like structures.In view of its sustainable building blocks and multifunctional characteristics,the NGCP developed in this work is promising as low-cost and high-performance nanopaper. 展开更多
关键词 Nanofibrillated cellulose GRAPHENE flexible nanopaper mechanical strength electrical resistance
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Complete transthoracic resection of giant posterior mediastinal goiter: A case report and review of the surgical approaches
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作者 Gaoyang Lin Dadeng Gao +2 位作者 Fang Yuan Yingyi Lv zhenbo liu 《Oncology and Translational Medicine》 2018年第1期26-30,共5页
Intrathoracic goiter(IG) is commonly located in the anterior mediastinum. Here, we report the case of a 54-year-old Chinese woman with successful removal of an intrathoracic goiter and improvement of dyspnea by a righ... Intrathoracic goiter(IG) is commonly located in the anterior mediastinum. Here, we report the case of a 54-year-old Chinese woman with successful removal of an intrathoracic goiter and improvement of dyspnea by a right posterolateral thoracotomy approach. Conclusion: Posterior mediastinal thyroid goiter with mediastinal compressive symptoms is an indication for surgery. 展开更多
关键词 intrathoracic goiter(IG) posterior mediastinum goiter(PMG) thoracotomy Abbreviations
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The Role of DNA Methylation Reprogramming During Sex Determination and Transition in Zebrafish 被引量:4
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作者 Xinxin Wang Xin Ma +13 位作者 Gaobo Wei Weirui Ma Zhen Zhang Xuepeng Chen Lei Gao zhenbo liu Yue Yuan Lizhi Yi Jun Wang Toshinobu Tokumoto Junjiu Huang Dahua Chen Jian Zhang Jiang liu 《Genomics, Proteomics & Bioinformatics》 SCIE CAS CSCD 2021年第1期48-63,共16页
DNA methylation is a prevalent epigenetic modification in vertebrates,and it has been shown to be involved the regulation of gene expression and embryo development.However,it remains unclear how DNA methylation regula... DNA methylation is a prevalent epigenetic modification in vertebrates,and it has been shown to be involved the regulation of gene expression and embryo development.However,it remains unclear how DNA methylation regulates sexual development,especially in species without sex chromosomes.To determine this,we utilized zebrafish to investigate DNA methylation reprogramming during juvenile germ cell development and adult female-to-male sex transition.We reveal that primordial germ cells(PGCs)undergo significant DNA methylation reprogramming during germ cell development,and the methylome of PGCs is reset to an oocyte/ovary-like pattern at 9 days post fertilization(9 dpf).When DNA methyltransferase(DNMT)activity in juveniles was blocked after 9 dpf,the zebrafish developed into females.We also show that Tet3 is involved in PGC development.Notably,we find that DNA methylome reprogramming during adult zebrafish sex transition is similar to the reprogramming during the sex differentiation from 9 dpf PGCs to sperm.Furthermore,inhibiting DNMT activity can prevent the female-to-male sex transition,suggesting that methylation reprogramming is required for zebrafish sex transition.In summary,DNA methylation plays important roles in zebrafish germ cell development and sexual plasticity. 展开更多
关键词 Germ cell DNA methylation Sex determination Sex transition Sexual plasticity
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