Vanadium-based electrodes are regarded as attractive cathode materials in aqueous zinc ion batteries(ZIBs)caused by their high capacity and unique layered structure.However,it is extremely challenging to acquire high ...Vanadium-based electrodes are regarded as attractive cathode materials in aqueous zinc ion batteries(ZIBs)caused by their high capacity and unique layered structure.However,it is extremely challenging to acquire high electrochemical performance owing to the limited electronic conductivity,sluggish ion kinetics,and severe volume expansion during the insertion/extraction process of Zn^(2+).Herein,a series of V_(2)O_(3)nanospheres embedded N-doped carbon nanofiber structures with various V_(2)O_(3)spherical morphologies(solid,core-shell,hollow)have been designed for the first time by an electrospinning technique followed thermal treatments.The N-doped carbon nanofibers not only improve the electrical conductivity and the structural stability,but also provides encapsulating shells to prevent the vanadium dissolution and aggregation of V_(2)O_(3)particles.Furthermore,the varied morphological structures of V_(2)O_(3)with abundant oxygen vacancies can alleviate the volume change and increase the Zn^(2+)pathway.Besides,the phase transition between V_(2)O_(3)and Zn_XV_(2)O_(5-m)·n H_(2)O in the cycling was also certified.As a result,the as-obtained composite delivers excellent long-term cycle stability and enhanced rate performance for coin cells,which is also confirmed through density functional theory(DFT)calculations.Even assembled into flexible ZIBs,the sample still exhibits superior electrochemical performance,which may afford new design concept for flexible cathode materials of ZIBs.展开更多
Iron oxide(Fe_(2)O_(3))emerges as a highly attractive anode candidate among rapidly expanding energy storage market.Nonethe-less,its considerable volume changes during cycling as an electrode material result in a vast...Iron oxide(Fe_(2)O_(3))emerges as a highly attractive anode candidate among rapidly expanding energy storage market.Nonethe-less,its considerable volume changes during cycling as an electrode material result in a vast reduced battery cycle life.In this work,an ap-proach is pioneered for preparing high-performance Fe_(2)O_(3)anode materials,by innovatively synthesizing a triple-layer yolk-shell Fe_(2)O_(3)uniformly coated with a conductive polypyrrole(Ppy)layer(Fe_(2)O_(3)@Ppy-TLY).The uniform polypyrrole coating introduces more reac-tion sites and adsorption sites,and maintains structure stability through charge-discharge process.In the uses as lithium-ion battery elec-trodes,Fe_(2)O_(3)@Ppy-TLY demonstrates high reversible specific capacity(maintaining a discharge capacity of 1375.11 mAh·g^(−1)after 500 cycles at 1 C),exceptional cycling stability(retaining the steady charge-discharge performance at 544.33 mAh·g^(−1)after 6000 ultrafast charge-discharge cycles at a 10 C current density),and outstanding high current charge-discharge performance(retaining a reversible ca-pacity of 156.75 mAh·g^(−1)after 10000 cycles at 15 C),thereby exhibiting superior lithium storage performance.This work introduces in-novative advancements for Fe_(2)O_(3)anode design,aiming to enhance its performance in energy storage fields.展开更多
Tin sulfide(SnS_(2))anodes have garnered significant attention within emerging energy storage technologies.However,the application of SnS_(2)is curtailed due to its inherent limitations,including poor cyclic stability...Tin sulfide(SnS_(2))anodes have garnered significant attention within emerging energy storage technologies.However,the application of SnS_(2)is curtailed due to its inherent limitations,including poor cyclic stability and inevitable volumetric expansion upon cycling.This study reports the successful fabrication of an innovative SnS_(2)-based composite,featuring an eggshell-like structured nitrogen-doped carbon coating,referred to as SnS_(2)@NxC.This novel architecture,wherein SnS_(2)acts as the core encapsulated by a nitrogen-doped carbon shell,characterized by a void space between the shell and core,is crucial in mitigating volumetric expansion.This configuration contributes to maintaining the structural integrity of the composite materials,even under the stresses of continuous cycling.Nitrogen within the carbon matrix enhances conductivity and promotes the formation of a more robust and stable solid electrolyte interphase(SEI)layer.Experimental investigations have substantiated the electrochemical superiority of the SnS_(2)@NxC electrode,demonstrating a specific capacity of 701.8 mA·h·g^(-1)after 1000 cycles at 0.5 A·g^(-1)and maintaining a capacity of 597.2mA·h·g^(-1)after 400 cycles at a heightened current density of 2 A·g^(-1).These findings underscore the exceptional cyclic performance and durability of the SnS_(2)@NxC electrode.展开更多
[Objectives] The aim was to clarify the target and approach to purifying and selecting Baoshan Touxinlv broad bean. [Methods] In 2012,5 homozygous strains were selected successfully as the material,and completely rand...[Objectives] The aim was to clarify the target and approach to purifying and selecting Baoshan Touxinlv broad bean. [Methods] In 2012,5 homozygous strains were selected successfully as the material,and completely randomized block arrangement was adopted with 3 repeated trials to analyze the effects of plant height,effective length of podding branches,branch number per plant,pod number per plant,grain number per pod and 100-grain weight on the yield of each plant in the system. [Results] The results showed that the effects of the various factors on the yield of Baoshan broad beans were in the order of grain number per pod 〉 effective length of podding branches 〉 100-grain weight 〉 pod number per plant 〉 branch number per plant 〉 plant height. [Conclusions]In breeding new strains of Baoshan broad beans,under the premise of ensuring the seed nature and quality of the original variety,priority should be given to the gain number per pod and the increment of effective length of podding branches,followed by the pod number per plant,branch number per plant,plant height,which is the best way to breed new strains of Baoshan Touxinlv broad beans.展开更多
Using the gray system theory and gray relational analysis method,the relationship between added value of hybrid corn,hogs,Juglans sigillata,Pisum Sativum L.,safflower and that of farmers' net income in Bailongjing...Using the gray system theory and gray relational analysis method,the relationship between added value of hybrid corn,hogs,Juglans sigillata,Pisum Sativum L.,safflower and that of farmers' net income in Bailongjing Village,Wafang Township,Longyang District,Baoshan City,Yunnan Province was analyzed,and the ways to increase farmers' per capita net income were studied. The results showed that economic income of farmers by structure adjustment of agriculture is Juglans sigillata > Pisum Sativum L. > safflower > hogs > hybrid corn. The study can provide scientific basis for optimizing agricultural industrial structure in Baoshan City,and promoting the rapid growth of farmers' economic income.展开更多
To meet the wishes and demands of the majority of farmers,it is necessary to steadily build a new socialist countryside,and actively promote urban-rural integration. With the guidance for new countryside construction ...To meet the wishes and demands of the majority of farmers,it is necessary to steadily build a new socialist countryside,and actively promote urban-rural integration. With the guidance for new countryside construction as an opportunity,this paper studies and explores the working practice of new countryside construction instructors sent by Longyang Agricultural Technique Extension Station for various village committees( or offices) during 2007- 2013. This paper analyzes and summarizes the results achieved and the main problems,and puts forth the corresponding recommendations. The results of the analysis can provide a reference for the instructors to carry out the guiding work for new countryside construction.展开更多
In order to further strengthen the construction and improvement of villager autonomy system with democratic election,democratic decision making,democratic management,and democratic supervision of rural two committees ...In order to further strengthen the construction and improvement of villager autonomy system with democratic election,democratic decision making,democratic management,and democratic supervision of rural two committees with Chinese characteristics,experience of work team of Longyang District Agricultural Technology Extension Station dispatched to villager committees( or offices) and their guidance on election of rural two committees in 2007-2016 were used,and exploration was made for election of rural two committees from the third to the sixth committees. It summarized achievements and main problems in election of rural two committees and came up with pertinent recommendations.The results of this study are expected to provide certain reference for theory and practice of future villager autonomy.展开更多
[ Objectives] The aim was to provide technical supports for the popularization and application of gray skin chewing sugarcane in large areas in suitable regions. [ Methods] Field planting tests were conducted in 2012 ...[ Objectives] The aim was to provide technical supports for the popularization and application of gray skin chewing sugarcane in large areas in suitable regions. [ Methods] Field planting tests were conducted in 2012 -2016 to study the yield, major economic traits, disease resistances, growth periods, adaptability and cultivation techniques of gray skin chewing sugarcane. [ Results] The characteristics and a set of precise cultivation techniques for gray skin chewing sugarcane were summarized. [ Conclusions] The technology can be widely applied in the areas with altitude of less than 1 500 m and areas with similar climate in Yunnan Province.展开更多
基金supported financially by the Natural Science Foundation of Shandong Province,China(grant numbers ZR2020QE067,ZR2020QB117,and ZR2022MB143)the New Colleges and Universities Twenty Foundational Projects of Jinan City,China(grant number 2021GXRC068)+2 种基金the National Natural Science Foundation of China,China(grant number 22208174)The Scientific Research Foundation in Qilu University of Technology(Shandong Academy of Sciences),China(grant numbers 2023PY002)The Talent research project of Qilu University of Technology(Shandong Academy of Sciences),China(grant numbers 2023RCKY013)。
文摘Vanadium-based electrodes are regarded as attractive cathode materials in aqueous zinc ion batteries(ZIBs)caused by their high capacity and unique layered structure.However,it is extremely challenging to acquire high electrochemical performance owing to the limited electronic conductivity,sluggish ion kinetics,and severe volume expansion during the insertion/extraction process of Zn^(2+).Herein,a series of V_(2)O_(3)nanospheres embedded N-doped carbon nanofiber structures with various V_(2)O_(3)spherical morphologies(solid,core-shell,hollow)have been designed for the first time by an electrospinning technique followed thermal treatments.The N-doped carbon nanofibers not only improve the electrical conductivity and the structural stability,but also provides encapsulating shells to prevent the vanadium dissolution and aggregation of V_(2)O_(3)particles.Furthermore,the varied morphological structures of V_(2)O_(3)with abundant oxygen vacancies can alleviate the volume change and increase the Zn^(2+)pathway.Besides,the phase transition between V_(2)O_(3)and Zn_XV_(2)O_(5-m)·n H_(2)O in the cycling was also certified.As a result,the as-obtained composite delivers excellent long-term cycle stability and enhanced rate performance for coin cells,which is also confirmed through density functional theory(DFT)calculations.Even assembled into flexible ZIBs,the sample still exhibits superior electrochemical performance,which may afford new design concept for flexible cathode materials of ZIBs.
基金supported by the Natural Science Foundation of Jiangsu Province of China(No.BK20201008).
文摘Iron oxide(Fe_(2)O_(3))emerges as a highly attractive anode candidate among rapidly expanding energy storage market.Nonethe-less,its considerable volume changes during cycling as an electrode material result in a vast reduced battery cycle life.In this work,an ap-proach is pioneered for preparing high-performance Fe_(2)O_(3)anode materials,by innovatively synthesizing a triple-layer yolk-shell Fe_(2)O_(3)uniformly coated with a conductive polypyrrole(Ppy)layer(Fe_(2)O_(3)@Ppy-TLY).The uniform polypyrrole coating introduces more reac-tion sites and adsorption sites,and maintains structure stability through charge-discharge process.In the uses as lithium-ion battery elec-trodes,Fe_(2)O_(3)@Ppy-TLY demonstrates high reversible specific capacity(maintaining a discharge capacity of 1375.11 mAh·g^(−1)after 500 cycles at 1 C),exceptional cycling stability(retaining the steady charge-discharge performance at 544.33 mAh·g^(−1)after 6000 ultrafast charge-discharge cycles at a 10 C current density),and outstanding high current charge-discharge performance(retaining a reversible ca-pacity of 156.75 mAh·g^(−1)after 10000 cycles at 15 C),thereby exhibiting superior lithium storage performance.This work introduces in-novative advancements for Fe_(2)O_(3)anode design,aiming to enhance its performance in energy storage fields.
文摘Tin sulfide(SnS_(2))anodes have garnered significant attention within emerging energy storage technologies.However,the application of SnS_(2)is curtailed due to its inherent limitations,including poor cyclic stability and inevitable volumetric expansion upon cycling.This study reports the successful fabrication of an innovative SnS_(2)-based composite,featuring an eggshell-like structured nitrogen-doped carbon coating,referred to as SnS_(2)@NxC.This novel architecture,wherein SnS_(2)acts as the core encapsulated by a nitrogen-doped carbon shell,characterized by a void space between the shell and core,is crucial in mitigating volumetric expansion.This configuration contributes to maintaining the structural integrity of the composite materials,even under the stresses of continuous cycling.Nitrogen within the carbon matrix enhances conductivity and promotes the formation of a more robust and stable solid electrolyte interphase(SEI)layer.Experimental investigations have substantiated the electrochemical superiority of the SnS_(2)@NxC electrode,demonstrating a specific capacity of 701.8 mA·h·g^(-1)after 1000 cycles at 0.5 A·g^(-1)and maintaining a capacity of 597.2mA·h·g^(-1)after 400 cycles at a heightened current density of 2 A·g^(-1).These findings underscore the exceptional cyclic performance and durability of the SnS_(2)@NxC electrode.
基金Supported by the Project for Longyang Agricultural Technique Extension Station of Modern Agricultural Technology System for Rice Industry of Yunnan[Yunnongke(2009)No.53,Yuncainong(2009)No.171]
文摘[Objectives] The aim was to clarify the target and approach to purifying and selecting Baoshan Touxinlv broad bean. [Methods] In 2012,5 homozygous strains were selected successfully as the material,and completely randomized block arrangement was adopted with 3 repeated trials to analyze the effects of plant height,effective length of podding branches,branch number per plant,pod number per plant,grain number per pod and 100-grain weight on the yield of each plant in the system. [Results] The results showed that the effects of the various factors on the yield of Baoshan broad beans were in the order of grain number per pod 〉 effective length of podding branches 〉 100-grain weight 〉 pod number per plant 〉 branch number per plant 〉 plant height. [Conclusions]In breeding new strains of Baoshan broad beans,under the premise of ensuring the seed nature and quality of the original variety,priority should be given to the gain number per pod and the increment of effective length of podding branches,followed by the pod number per plant,branch number per plant,plant height,which is the best way to breed new strains of Baoshan Touxinlv broad beans.
基金Supported by Xishan"3+2"Poverty Reduction Project in Longyang District of Baoshan City(200507)Modern Corn Industry Technology System Project in Yunnan Province(2009-532009-171)
文摘Using the gray system theory and gray relational analysis method,the relationship between added value of hybrid corn,hogs,Juglans sigillata,Pisum Sativum L.,safflower and that of farmers' net income in Bailongjing Village,Wafang Township,Longyang District,Baoshan City,Yunnan Province was analyzed,and the ways to increase farmers' per capita net income were studied. The results showed that economic income of farmers by structure adjustment of agriculture is Juglans sigillata > Pisum Sativum L. > safflower > hogs > hybrid corn. The study can provide scientific basis for optimizing agricultural industrial structure in Baoshan City,and promoting the rapid growth of farmers' economic income.
基金Supported by National Grassroots Agricultural Technical Extension System Reform and Construction Subsidy Project(200630200785)+1 种基金Modern Maize Industry Technology System Project in Yunnan Province(2009532009171)
文摘To meet the wishes and demands of the majority of farmers,it is necessary to steadily build a new socialist countryside,and actively promote urban-rural integration. With the guidance for new countryside construction as an opportunity,this paper studies and explores the working practice of new countryside construction instructors sent by Longyang Agricultural Technique Extension Station for various village committees( or offices) during 2007- 2013. This paper analyzes and summarizes the results achieved and the main problems,and puts forth the corresponding recommendations. The results of the analysis can provide a reference for the instructors to carry out the guiding work for new countryside construction.
基金Supported by Reform and Construction Subsidy Project of National Grassroots Agricultural Extension System[Guo Fa(2006)30Yun Zheng Fa(2007)85]+1 种基金Project for Construction of Modern Agricultural Rice and Maize Industry Technology System in Yunnan Province[Yun Nong Ke Zi(2009)53Yun Cai Nong(2009)171]
文摘In order to further strengthen the construction and improvement of villager autonomy system with democratic election,democratic decision making,democratic management,and democratic supervision of rural two committees with Chinese characteristics,experience of work team of Longyang District Agricultural Technology Extension Station dispatched to villager committees( or offices) and their guidance on election of rural two committees in 2007-2016 were used,and exploration was made for election of rural two committees from the third to the sixth committees. It summarized achievements and main problems in election of rural two committees and came up with pertinent recommendations.The results of this study are expected to provide certain reference for theory and practice of future villager autonomy.
基金Supported by the Modern Agricultural Technology System for Corn Industry of the Regional Promotion Station of Longyang District,Yunnan Province[Yunnongke(2009)53,Yuncainong(2009)171]
文摘[ Objectives] The aim was to provide technical supports for the popularization and application of gray skin chewing sugarcane in large areas in suitable regions. [ Methods] Field planting tests were conducted in 2012 -2016 to study the yield, major economic traits, disease resistances, growth periods, adaptability and cultivation techniques of gray skin chewing sugarcane. [ Results] The characteristics and a set of precise cultivation techniques for gray skin chewing sugarcane were summarized. [ Conclusions] The technology can be widely applied in the areas with altitude of less than 1 500 m and areas with similar climate in Yunnan Province.
