Microalgae cultivation has gained tremendous attention in recent years due to its great potential in green biofuel production and wastewater treatment application. Membrane technology is a great solution in separating...Microalgae cultivation has gained tremendous attention in recent years due to its great potential in green biofuel production and wastewater treatment application. Membrane technology is a great solution in separating the microalgae biomass while producing high quality of permeate for recycling. The main objective of this study was to investigate the filtration performance of Ag/GO-PVDF(silver/graphene oxide-polyvinylidene fluoride) membrane in an algalmembrane photoreactor(A-MPR) by benchmarking with a commercial PVDF(com-PVDF) membrane. In this study, Chlorella vulgaris microalgae was cultivated in synthetic wastewater in an A-MPR for ammoniacal-nitrogen and phosphorus recovery and the wastewater was further filtered using Ag/GO-PVDF and com-PVDF membranes to obtain high quality water. Spectrophotometer was used to analyze the chemical oxidation demand(COD), ammoniacal nitrogen(NH3-N) and phosphate(PO43-). The concentration of proteins and carbohydrates was measured using Bradford method and phenol-sulfuric acid method, respectively. The COD of the synthetic wastewater was reduced from(180.5 ± 5.6) ppm to(82 ± 2.6) ppm due to nutrient uptake by microalgae. Then, the Ag/GO-PVDF membrane was used to further purify the microalgae cultivated wastewater, resulting in a low COD permeate of(31 ± 4.6) ppm. The high removal rate of proteins(100%) and carbohydrates(86.6%) as the major foulant in microalgae filtration, with low membrane fouling propensity of Ag/GO-PVDF membrane is advantageous for the sustainable development of the microalgae production. Hence, the integrated A-MPR system is highly recommended as a promising approach for microalgae cultivation and wastewater polishing treatment.展开更多
基金supported by Universiti Kebangsaan Malaysia [Grant No.DIP-2016-031]CRIM(Center for Research and Instrumentation Management,UKM)for sponsoring the postgraduate study of W.C.Chong via Research University Zamalah Scheme and the technical supports in this work.
文摘Microalgae cultivation has gained tremendous attention in recent years due to its great potential in green biofuel production and wastewater treatment application. Membrane technology is a great solution in separating the microalgae biomass while producing high quality of permeate for recycling. The main objective of this study was to investigate the filtration performance of Ag/GO-PVDF(silver/graphene oxide-polyvinylidene fluoride) membrane in an algalmembrane photoreactor(A-MPR) by benchmarking with a commercial PVDF(com-PVDF) membrane. In this study, Chlorella vulgaris microalgae was cultivated in synthetic wastewater in an A-MPR for ammoniacal-nitrogen and phosphorus recovery and the wastewater was further filtered using Ag/GO-PVDF and com-PVDF membranes to obtain high quality water. Spectrophotometer was used to analyze the chemical oxidation demand(COD), ammoniacal nitrogen(NH3-N) and phosphate(PO43-). The concentration of proteins and carbohydrates was measured using Bradford method and phenol-sulfuric acid method, respectively. The COD of the synthetic wastewater was reduced from(180.5 ± 5.6) ppm to(82 ± 2.6) ppm due to nutrient uptake by microalgae. Then, the Ag/GO-PVDF membrane was used to further purify the microalgae cultivated wastewater, resulting in a low COD permeate of(31 ± 4.6) ppm. The high removal rate of proteins(100%) and carbohydrates(86.6%) as the major foulant in microalgae filtration, with low membrane fouling propensity of Ag/GO-PVDF membrane is advantageous for the sustainable development of the microalgae production. Hence, the integrated A-MPR system is highly recommended as a promising approach for microalgae cultivation and wastewater polishing treatment.