Vanadium redox flow battery(VRFB)is one of the most promising large-scale energy storage systems,which ranges from kilowatt to megawatt.Nevertheless,poor electrochemical activity of electrode for two redox couples sti...Vanadium redox flow battery(VRFB)is one of the most promising large-scale energy storage systems,which ranges from kilowatt to megawatt.Nevertheless,poor electrochemical activity of electrode for two redox couples still restricts the extensive applications of VRFB.Compared with V^(2+)/V^(3+)redox reaction,V^(2+)/V^(3+)reaction plays a more significant role in voltage loss of VRFB owing to slow heterogeneous electron transfer rate.Herein,N-doped carbon materials derived from scaphium scaphigerum have been developed as negative electrocatalyst by hydrothermal carbonization and high-temperature nitridation treatments.The undoped carbon material hardly has electrocatalytic ability for V^(2+)/V^(3+)reaction.Based on this,N-doped carbon materials with urea as nitrogen source exhibit excellent electrocatalytic properties.And the material nitrided at 850°C(SSC/N-850)exhibits the best performance among those from700 to 1000℃.SSC/N-850 can accelerate the electrode process including V^(2+)/V^(3+)reaction and mass transfer of active ions due to the large reaction place,more active sites,and good hydrophilicity.The effect of catalyst on comprehensive performance of cell was evaluated.SSC/N-850 can improve the charge-discharge performance greatly.Utilization of SSC/N-850 can lessen the electrochemical polarization of cell,further resulting in increased discharge capacity and energy efficiency.Discharge capacity and energy efficiency increase by 81.5%and 9.8%by using SSC/N-850 as negative catalyst at 150 m A cm^(-2),respectively.Our study reveals that the developed biomass-derived carbon materials are the low-cost and efficient negative electrocatalyst for VRFB system.展开更多
This paper provides a mathematical model for Three Gorges-Gezhou dam co-scheduling problem, based on full analysis of Three Corges-Gezhou dam＇s actual needs, to maximize the total throughput of Three Gorges-Cezhou da...This paper provides a mathematical model for Three Gorges-Gezhou dam co-scheduling problem, based on full analysis of Three Corges-Gezhou dam＇s actual needs, to maximize the total throughput of Three Gorges-Cezhou dam and the utilization ratio of shiplock area and minimize the total navigation shiplock waiting time under multiple constraints. This paper proposes a series queuing network （SQN） scheduling algorithm to divide the total ships that intend to pass through the shiplocks into four queues and calculate dynamically the weight of priority for each ship. The SQN scheduling algorithm schedules ships according to their priority weights which is determined by the characteristics of each ship, such as length, width, affiliation, waiting time, and so on. In the process, the operation conditions of Gezhou dam related to the navigable shiplocks and the task balancing among different shiplocks also should be considered. The SQN algorithm schedules ships circularly and optimizes the results step by step. Real operation data from our project shows that our SQN scheduling algorithm outperforms the traditional manual scheduling in which the less computational time is taken, the area utilization ratio of the five shiplocks is increased, the waiting time of high-prioritized ships is shorten, and a better balanced and alternating run-mode is provided for the three shiplocks in the Gezhou dam.展开更多
基金financially supported by the National Natural Science Foundation of China(No.51772097)Hebei Natural Science Fund for Distinguished Young Scholar(No.E2019209433)Training Program of Innovation and Entrepreneurship for Undergraduates(No.X2018156,North China University of Science and Technology)。
文摘Vanadium redox flow battery(VRFB)is one of the most promising large-scale energy storage systems,which ranges from kilowatt to megawatt.Nevertheless,poor electrochemical activity of electrode for two redox couples still restricts the extensive applications of VRFB.Compared with V^(2+)/V^(3+)redox reaction,V^(2+)/V^(3+)reaction plays a more significant role in voltage loss of VRFB owing to slow heterogeneous electron transfer rate.Herein,N-doped carbon materials derived from scaphium scaphigerum have been developed as negative electrocatalyst by hydrothermal carbonization and high-temperature nitridation treatments.The undoped carbon material hardly has electrocatalytic ability for V^(2+)/V^(3+)reaction.Based on this,N-doped carbon materials with urea as nitrogen source exhibit excellent electrocatalytic properties.And the material nitrided at 850°C(SSC/N-850)exhibits the best performance among those from700 to 1000℃.SSC/N-850 can accelerate the electrode process including V^(2+)/V^(3+)reaction and mass transfer of active ions due to the large reaction place,more active sites,and good hydrophilicity.The effect of catalyst on comprehensive performance of cell was evaluated.SSC/N-850 can improve the charge-discharge performance greatly.Utilization of SSC/N-850 can lessen the electrochemical polarization of cell,further resulting in increased discharge capacity and energy efficiency.Discharge capacity and energy efficiency increase by 81.5%and 9.8%by using SSC/N-850 as negative catalyst at 150 m A cm^(-2),respectively.Our study reveals that the developed biomass-derived carbon materials are the low-cost and efficient negative electrocatalyst for VRFB system.
基金supported by the National Natural Science Foundation of China under Grant No. 60904074the Natural Science Foundation of Hubei Province of China under Grant No. 2008CDB012the Specialized Research Fund for the Doctoral Program of Higher Education of China under Grant No. 200804871150
文摘This paper provides a mathematical model for Three Gorges-Gezhou dam co-scheduling problem, based on full analysis of Three Corges-Gezhou dam＇s actual needs, to maximize the total throughput of Three Gorges-Cezhou dam and the utilization ratio of shiplock area and minimize the total navigation shiplock waiting time under multiple constraints. This paper proposes a series queuing network （SQN） scheduling algorithm to divide the total ships that intend to pass through the shiplocks into four queues and calculate dynamically the weight of priority for each ship. The SQN scheduling algorithm schedules ships according to their priority weights which is determined by the characteristics of each ship, such as length, width, affiliation, waiting time, and so on. In the process, the operation conditions of Gezhou dam related to the navigable shiplocks and the task balancing among different shiplocks also should be considered. The SQN algorithm schedules ships circularly and optimizes the results step by step. Real operation data from our project shows that our SQN scheduling algorithm outperforms the traditional manual scheduling in which the less computational time is taken, the area utilization ratio of the five shiplocks is increased, the waiting time of high-prioritized ships is shorten, and a better balanced and alternating run-mode is provided for the three shiplocks in the Gezhou dam.
