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Characterization, preparation, and reuse of metallic powders for laser powder bed fusion: a review 被引量:3
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作者 Xiaoyu Sun Minan Chen +4 位作者 Tingting Liu Kai Zhang Huiliang Wei Zhiguang Zhu wenhe liao 《International Journal of Extreme Manufacturing》 SCIE EI CAS CSCD 2024年第1期52-91,共40页
Laser powder bed fusion(L-PBF) has attracted significant attention in both the industry and academic fields since its inception, providing unprecedented advantages to fabricate complex-shaped metallic components. The ... Laser powder bed fusion(L-PBF) has attracted significant attention in both the industry and academic fields since its inception, providing unprecedented advantages to fabricate complex-shaped metallic components. The printing quality and performance of L-PBF alloys are infuenced by numerous variables consisting of feedstock powders, manufacturing process,and post-treatment. As the starting materials, metallic powders play a critical role in infuencing the fabrication cost, printing consistency, and properties. Given their deterministic roles, the present review aims to retrospect the recent progress on metallic powders for L-PBF including characterization, preparation, and reuse. The powder characterization mainly serves for printing consistency while powder preparation and reuse are introduced to reduce the fabrication costs.Various powder characterization and preparation methods are presented in the beginning by analyzing the measurement principles, advantages, and limitations. Subsequently, the effect of powder reuse on the powder characteristics and mechanical performance of L-PBF parts is analyzed, focusing on steels, nickel-based superalloys, titanium and titanium alloys, and aluminum alloys. The evolution trends of powders and L-PBF parts vary depending on specific alloy systems, which makes the proposal of a unified reuse protocol infeasible. Finally,perspectives are presented to cater to the increased applications of L-PBF technologies for future investigations. The present state-of-the-art work can pave the way for the broad industrial applications of L-PBF by enhancing printing consistency and reducing the total costs from the perspective of powders. 展开更多
关键词 laser powder bed fusion powder characterization powder preparation powder reuse
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Ignition processes and characteristics of charring conductive polymers with a cavity geometry in precombustion chamber for applications in micro/nano satellite hybrid rocket motors
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作者 Zhiyuan Zhang Hanyu Deng +2 位作者 wenhe liao Bin Yu Zai Yu 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2024年第2期55-66,共12页
The arc ignition system based on charring polymers has advantages of simple structure,low ignition power consumption and multiple ignitions,which bringing it broadly application prospect in hybrid propulsion system of... The arc ignition system based on charring polymers has advantages of simple structure,low ignition power consumption and multiple ignitions,which bringing it broadly application prospect in hybrid propulsion system of micro/nano satellite.However,charring polymers alone need a relatively high input voltage to achieve pyrolysis and ignition,which increases the burden and cost of the power system of micro/nano satellite in practical application.Adding conductive substance into charring polymers can effectively decrease the conducting voltage which can realize low voltage and low power consumption repeated ignition of arc ignition system.In this paper,a charring conductive polymer ignition grain with a cavity geometry in precombustion chamber,which is composed of PLA and multiwall carbon nanotubes(MWCNT)was proposed.The detailed ignition processes were analyzed and two different ignition mechanisms in the cavity of charring conductive polymers were revealed.The ignition characteristics of charring conductive polymers were also investigated at different input voltages,ignition grain structures,ignition locations and injection schemes in a visual ignition combustor.The results demonstrated that the ignition delay and external energy required for ignition were inversely correlated with the voltages applied to ignition grain.Moreover,the incremental depth of cavity shortened the ignition delay and external energy required for ignition while accelerated the propagation of flame.As the depth of cavity increased from 2 to 6 mm(at 50 V),the time of flame propagating out of ignition grain changed from 235.6 to 108 ms,and values of mean ignition delay time and mean external energy required for ignition decreased from 462.8 to 320 ms and 16.2 to 10.75 J,respectively.The rear side of the cavity was the ideal ignition position which had a shorter ignition delay and a faster flame propagation speed in comparison to other ignition positions.Compared to direct injection scheme,swirling injection provided a more favorable flow field environment in the cavity,which was beneficial to ignition and initial flame propagation,but the ignition position needed to be away from the outlet of swirling injector.At last,the repeated ignition characteristic of charring conductive polymers was also investigated.The ignition delay time and external energy required for ignition decreased with repeated ignition times but the variation was decreasing gradually. 展开更多
关键词 Micro/nano satellite hybrid propulsion Arc ignition Charring conductive polymer Ignition mechanism Ignition characteristic Repeated ignition
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Investigation of the Laser Powder Bed Fusion Process of Ti-6.5Al-3.5Mo-1.5Zr-0.3Si Alloy 被引量:1
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作者 Changchun Zhang Tingting Liu +2 位作者 wenhe liao Huiliang Wei Ling Zhang 《Chinese Journal of Mechanical Engineering》 SCIE EI CAS CSCD 2023年第2期78-90,共13页
Laser powder bed fusion(LPBF)is an advanced manufacturing technology;however,inappropriate LPBF process parameters may cause printing defects in materials.In the present work,the LPBF process of Ti-6.5Al-3.5Mo-1.5Zr-0... Laser powder bed fusion(LPBF)is an advanced manufacturing technology;however,inappropriate LPBF process parameters may cause printing defects in materials.In the present work,the LPBF process of Ti-6.5Al-3.5Mo-1.5Zr-0.3Si alloy was investigated by a two-step optimization approach.Subsequently,heat transfer and liquid flow behaviors during LPBF were simulated by a well-tested phenomenological model,and the defect formation mechanisms in the as-fabricated alloy were discussed.The optimized process parameters for LPBF were detected as laser power changed from 195 W to 210 W,with scanning speed of 1250 mm/s.The LPBF process was divided into a laser irradiation stage,a spreading flow stage,and a solidification stage.The morphologies and defects of deposited tracks were affected by liquid flow behavior caused by rapid cooling rates.The findings of this research can provide valuable support for printing defect-free metal components. 展开更多
关键词 Laser powder bed fusion Ti-6.5Al-3.5Mo-1.5Zr-0.3Si alloy Process parameters Heat transfer and liquid flow DEFECTS
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Improvement of Orbit Prediction Algorithm for Spacecraft Through Simplified Precession-Nutation Model Using Cubic Spline Interpolation Method 被引量:1
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作者 Gen Xu Danhe Chen +1 位作者 Xiang Zhang wenhe liao 《Computer Modeling in Engineering & Sciences》 SCIE EI 2020年第11期865-878,共14页
For the on-orbit flight missions,the model of orbit prediction is critical for the tasks with high accuracy requirement and limited computing resources of spacecraft.The precession-nutation model,as the main part of e... For the on-orbit flight missions,the model of orbit prediction is critical for the tasks with high accuracy requirement and limited computing resources of spacecraft.The precession-nutation model,as the main part of extended orbit prediction,affects the efficiency and accuracy of on-board operation.In this paper,the previous research about the conversion between the Geocentric Celestial Reference System and International Terrestrial Reference System is briefly summarized,and a practical concise precession-nutation model is proposed for coordinate transformation computation based on Celestial Intermediate Pole(CIP).The idea that simplifying the CIP-based model with interpolation method is driven by characteristics of precession-nutation parameters changing with time.A cubic spline interpolation algorithm is applied to obtain the required CIP coordinates and Celestial Intermediate Origin locator.The complete precession nutation model containing more than 4000 parameters is simplified to the calculation of a cubic polynomial,which greatly reduces the computational load.In addition,for evaluating the actual performance,an orbit propagator is built with the proposed simplified precession-nutationmodel.Compared with the orbit prediction results obtained by the truncated series of IAU2000/2006 precession-nutation model,the simplified precession-nutation model with cubic spline interpolation can significantly improve the accuracy of orbit prediction,which implicates great practical application value in further on-orbit missions of spacecraft. 展开更多
关键词 Orbit prediction CIP-based coordinate transformation cubic spline interpolation
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旋转超声加工碳纤维复合材料研究现状与展望 被引量:2
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作者 束静 廖文和 +2 位作者 郑侃 董松 孙连军 《航空学报》 EI CAS CSCD 北大核心 2024年第13期108-132,共25页
碳纤维复合材料因其轻量化、耐高温、耐腐蚀等优异性能在多种极端服役环境得到了广泛的应用,在航空航天装备中的占比逐年提升。旋转超声加工技术在提高碳纤维复合材料去除效率、减小切削力和改善加工质量等方面具有显著优势,是当前难加... 碳纤维复合材料因其轻量化、耐高温、耐腐蚀等优异性能在多种极端服役环境得到了广泛的应用,在航空航天装备中的占比逐年提升。旋转超声加工技术在提高碳纤维复合材料去除效率、减小切削力和改善加工质量等方面具有显著优势,是当前难加工材料制造领域的研究热点。近年来,国内外学者在碳纤维复合材料的旋转超声钻削、铣削和磨削等方面展开了大量的研究工作并取得了丰硕的成果,然而,不同加工方式下多种形式超声振动能量的摄入对其切削效果的影响机理存在显著差异。此外,针对多种碳纤维复合材料表面完整性和使役性能研究的深度和广度仍存在较大的提升空间。为此,对材料去除机理、切削特性、表面质量研究及实际工程应用的国内外文献进行了总结和凝练,并展望了旋转超声加工碳纤维复合材料的发展趋势。 展开更多
关键词 旋转超声加工 碳纤维复合材料 纤维断裂 表面损伤抑制 表面粗糙度
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A novel method of suppressing machining vibration in robotic milling using magneto-rheological foam damper 被引量:1
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作者 Bo LI Chenxin SU +3 位作者 Wei ZHAO Shengli SONG Wei TIAN wenhe liao 《Chinese Journal of Aeronautics》 SCIE EI CAS CSCD 2024年第12期522-543,共22页
Owing to their remarkable flexibility and favorable cost-effectiveness,industrial robots have found extensive applications to cutting of materials across sophisticated manufacturing fields.However,the structurally low... Owing to their remarkable flexibility and favorable cost-effectiveness,industrial robots have found extensive applications to cutting of materials across sophisticated manufacturing fields.However,the structurally low rigidity of these robots renders the tool tip prone to substantial oscillations during machining processes,significantly impacting product fabrication quality.The objective of this study is to present a novel methodology employing magnetorheological dampers for mitigating vibrations during robotic milling operations.Specifically,a new type of ring nested Magneto-Rheological Foam Damper(MRFD)working in the squeeze mode is developed.Firstly,the MRFD’s structure is designed considering the vibrational characteristics of robotic milling.Subsequently,a damping force model of the MRFD is derived.The feasibility of the MRFD’s structural design is validated by the finite element analyses,which is instrumental in comprehending the influence of structural parameters on the electromagnetic characteristics of the MRFD.Next,a prototype of the MRFD is fabricated selecting appropriate parameters.Finally,a series of excitation and milling experiments are conducted on a KUKA KR500 robot.The outcomes demonstrate a substantial reduction(37%-69%)in radial vibration amplitude at the tool tip during robotic milling,highlighting the effectiveness of the developed MRFD.This research endeavor has introduced a pioneering avenue and framework for vibration control in robotic milling,offering a novel paradigm for enhancing the precision of robotic machining. 展开更多
关键词 Industrial robots Machining vibration Magneto-rheological dampers Robotic milling Vibration suppression
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Investigation on ignition characteristics of charring conductive polymers stimulated by electric energy
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作者 Zhiyuan ZHANG Hanyu DENG +2 位作者 wenhe liao Yantao PU Ping CAO 《Chinese Journal of Aeronautics》 SCIE EI CAS CSCD 2024年第10期68-82,共15页
The arc ignition based on charring conductive polymers has advantages of simple structure,low ignition power consumption and restart capacity,which bringing it broadly application prospect in hybrid propulsion system ... The arc ignition based on charring conductive polymers has advantages of simple structure,low ignition power consumption and restart capacity,which bringing it broadly application prospect in hybrid propulsion system of micro/nano satellite.In order to optimize the performance of arc ignition system,it is essential to have a deeper understanding of the ignition processes and ignition characteristics of charring conductive polymers.In this paper,the thermal decomposition,electrical conductivity and thermal conductivity characteristics of charring conductive polymers with different conductive additives and matrix materials were comprehensively evaluated.An experimental investigation was conducted to determine the ignition behaviors and characteristics of different charring conductive polymers in a visual ignition combustor.The experiment result showed that the ignition delay and external energy required for ignition are negatively correlated with voltage and initial temperature of the ignition grain,but positively correlated with oxidizer flow velocity.Compared with charring conductive polymers containing multi-walled carbon nanotube,the ignition delay of charring conductive polymers with carbon black is significantly higher and the pyrolysis time is relatively longer.However,the ignition and initial flame propagation of charring conductive polymers with carbon black is more violent and more inclined to carbon particle ignition.Finally,the restart characteristic of different charring conductive polymers was studied.The ignition delay and external energy required for ignition of different charring conductive polymers all reduced with the increasing of the number of ignitions.However,the ignition characteristics would not change a lot after repeated ignition. 展开更多
关键词 Micro/nano satellite hybrid rocket motors Arc ignition Charring conductive polymer Ignition process Ignition characteristic Restart characteristic
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A method for dynamic parameter identification of an industrial robot based on frequency response function
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作者 Bo Li Wei Zhao +2 位作者 Yunfei Miao Wei Tian wenhe liao 《International Journal of Mechanical System Dynamics》 2024年第4期461-471,共11页
Having accurate values of the dynamic parameters is necessary to characterize the dynamic behaviors of mechanical systems and for the prediction of their responses.To accurately describe the dynamic characteristics of... Having accurate values of the dynamic parameters is necessary to characterize the dynamic behaviors of mechanical systems and for the prediction of their responses.To accurately describe the dynamic characteristics of industrial robots(IRs),a new method for dynamic parameter identification is proposed in this study with the goal of developing a real IR dynamics model that combines the multibody system transfer matrix method(MSTMM)and the nondominated sorting genetic algorithm-II(NSGA-II).First,the multibody dynamics model of an IR is developed using the MSTMM,by which its frequency response function(FRF)is calculated numerically.Then,the experimental modal analysis is conducted to measure the IR's actual FRF.Finally,the objective function of the minimum errors between the calculated and measured eigenfrequencies and FRFs are constructed to identify the dynamic parameters of the IR by the NSGA-II algorithm.The simulated and experimental results illustrate the effectiveness of the methodology presented in this paper,which provides an alternative to the identification of IR dynamic parameters. 展开更多
关键词 industrial robots multibody system transfer matrix method robotic machining dynamic parameter identification
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Hole surface strengthening mechanism and riveting fatigue life of CFRP/aluminum stacks in robotic rotary ultrasonic drilling 被引量:3
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作者 Song DONG wenhe liao +2 位作者 Kan ZHENG Feng XUE Lianjun SUN 《Chinese Journal of Aeronautics》 SCIE EI CAS CSCD 2023年第10期471-484,共14页
Carbon fiber reinforced plastic(CFRP)and aluminum stacks are widely used in aviation industry due to light weight and high performance.Millions of rivet holes need to be drilled on body materials,and more than 80%of f... Carbon fiber reinforced plastic(CFRP)and aluminum stacks are widely used in aviation industry due to light weight and high performance.Millions of rivet holes need to be drilled on body materials,and more than 80%of fatigue cracks occur at the connection holes,so the damage and residual stress of hole surface have crucial effect on the riveting fatigue life of CFRP/aluminum stacks and the flight performance.Recently,robotic rotary ultrasonic drilling(RRUD)technology is a promising method to machine the stacks.However,the hole surface strengthening mechanism in RRUD and the service performance of the riveting joint are not verified.Thus,in this paper,the hole surface strengthening mechanism of RRUD for CFRP/aluminum stacks is investigated,a theoretical residual stress model is established,and the fatigue life experiment of riveted joints is conducted.Firstly,analysis on residual stress in RRUD is carried out with consideration of strengthening force and cutting temperature.Residual stress model is established based on the calculation of elastic stress,plastic stress and stress release.Validation experiment results show that ultrasonic vibration changes residual stress from tensile stress to compressive stress.At the same time,comparative damage analysis of CFRP hole exit and hole surface in robotic conventional drilling(RCD)and RRUD is presented.Finally,fatigue strength experiments of riveted joints are conducted for performance verification.Experimental results indicate that fatigue life of single-hole riveted joints is increased by 68%with ultrasonic vibration,and four-hole riveted joint arranged according to aerospace design standards is increased by more than 86%. 展开更多
关键词 CFRP/aluminum stacks Drilling damage Residual stress Riveting fatigue life Robotic rotary ultrasonic drilling
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Crack-free and high-strength AA2024 alloy obtained by additive manufacturing with controlled columnar-equiaxed-transition 被引量:2
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作者 Xing Zhu Zhiguang Zhu +3 位作者 Tingting Liu wenhe liao Yulei Du Huiliang Wei 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 2023年第25期183-196,共14页
Laser powder bed fusion(LPBF)of high-strength Al alloys is challenging due to the formation of both hot and cold cracks.In the present work,highly dense and crack-free AA2024 samples could be additively manufactured v... Laser powder bed fusion(LPBF)of high-strength Al alloys is challenging due to the formation of both hot and cold cracks.In the present work,highly dense and crack-free AA2024 samples could be additively manufactured via inoculation treatment of Zr-based metallic glass(MG)powders.The columnar grains in the LPBF-fabricated AA2024 alloy were significantly refined and almost completely transformed to the equiaxed grains with a bimodal grain size distribution consisting of ultrafine grains with a size smaller than 1μm and relatively coarser grains.The grain refinement can be associated with the formation of Al3Zr particles,serving as the heterogeneous nucleation sites for theα-Al matrix.Complete routes for columnar-equiaxed-transition(CET)have been revealed by tailoring the concentration of nucleation particles and solidification conditions.CET occurs both at the melt pool boundary due to the sufficiently high concentration of Al3Zr particles and at the topmost of the melt pool due to the heterogeneous nucleation driven by constitutional undercooling.Between these two regions,columnar grains epitaxially grow with orientations determined by the thermal gradient.The as-built Zr-based MG inoculated AA2024 specimens are robust in healing hot cracks due to a more tortuous propagation path of cracks for equiaxed grains.The as-fabricated AA2024/5%MG specimens exhibit a high ultimate tensile strength of 531 MPa due to crack elimination and grain refinement,surpassing most of the reported values for the LPBF-fabricated AA2024 alloy inoculated with other inoculated powders.The present work could provide a novel inoculation agent to fabricate high-strength Al alloys and the CET can be used to precisely control the grain morphology. 展开更多
关键词 Laser powder bed fusion Aluminum alloy Solidification parameters Columnar-equiaxed-transition Hot cracking Grain refinement
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Stability analysis of robotic longitudinal-torsional composite ultrasonic milling 被引量:2
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作者 Lianjun SUN wenhe liao +3 位作者 Kan ZHENG Wei TIAN Jinshan LIU Jindan FENG 《Chinese Journal of Aeronautics》 SCIE EI CAS CSCD 2022年第8期249-264,共16页
Currently,industrial robots are considered as an alternative towards traditional machine tools.Especially for the large-scale parts milling,robotic flexibility and low cost make it possess the irreplaceability.However... Currently,industrial robots are considered as an alternative towards traditional machine tools.Especially for the large-scale parts milling,robotic flexibility and low cost make it possess the irreplaceability.However,the milling chatter caused by its weak rigidity hampers robotic application and promotion severely in aviation industry.Rotary ultrasonic milling(RUM)technology with one-dimensional axial vibration has been proven and approved on avoiding robotic chatter.Based on this,the research of project team demonstrates that longitudinal-torsional composite ultrasonic milling(CUM-LT)involving separation characteristic has a greater advantage than RUM in terms of chatter suppression.Thereby,the CUM-LT as a new means is applied to avoid processing vibration of robotic milling system.And its influence mechanism on stability improvement of weak stiffness processing system is clarified.Meanwhile,the approaches to strengthen separation effect are provided innovatively.Moreover,a new analysis method of robotic CUM-LT(RCUM-LT)stability is proposed on the basis of ultrasonic function angles.The simulation and experimental results indicate that compared with robotic RUM(RRUM),stability regions of separated RCUM-LT(SRCUM-LT)and unseparated RCUM-LT(URCUM-LT)are improved by 124.42%and39.20%,respectively.The addition of torsional ultrasonic energy has a wonderful effect on the milling chatter suppression of low stiffness robots. 展开更多
关键词 Chatter suppression Industrial robots Longitudinal-torsional composite Rotary ultrasonic milling Stability analysis
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Feasibility analysis of angles-only navigation algorithm with multisensor data fusion for spacecraft noncooperative rendezvous 被引量:2
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作者 Ronghua Du wenhe liao Xiang Zhang 《Astrodynamics》 EI CSCD 2023年第2期179-196,共18页
Relative navigation is crucial for spacecraft noncooperative rendezvous,and angles-only navigation using visible and infrared cameras provides a feasible solution.Herein,an angles-only navigation algorithm with multis... Relative navigation is crucial for spacecraft noncooperative rendezvous,and angles-only navigation using visible and infrared cameras provides a feasible solution.Herein,an angles-only navigation algorithm with multisensor data fusion is proposed to derive the relative motion states between two noncooperative spacecraft.First,the design model of the proposed algorithm is introduced,including the derivation of the state propagation and measurement equations.Subsequently,models for the sensor and actuator are introduced,and the effects of various factors on the sensors and actuators are considered.The square-root unscented Kalman filter is used to design the angles-only navigation filtering scherne.Additionally,the Clohessy-Wiltshire terminal guidance algorithm is introducedto obtain the theoretical relative motion trajectories during the rendezvous operations of two noncooperative spacecraft.Finally,the effectiveness of the proposed angles-only navigation algorithm is verified using a semi-physical simulation platform.The results prove that an optical navigation camera combined with average accelerometers and occasional orbital maneuvers is feasible for spacecraft noncooperative rendezvous using angles-only navigation. 展开更多
关键词 angles-only navigation feasibility analysis multisensor data fusion spacecraft noncooperative rendezvous
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Chatter stability of robotic rotary ultrasonic countersinking
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作者 Zhenwen SUN wenhe liao +3 位作者 Kan ZHENG Song DONG Pei LEI Lianjun SUN 《Chinese Journal of Aeronautics》 SCIE EI CAS CSCD 2023年第10期434-444,共11页
In recent years,industrial robots have received extensive attention in manufacturing field due to their high flexibility and great workspace.However,the weak stiffness of industrial robots makes it extremely easy to a... In recent years,industrial robots have received extensive attention in manufacturing field due to their high flexibility and great workspace.However,the weak stiffness of industrial robots makes it extremely easy to arouse chatter,which affects machining quality inevitably and generates noise pollution in severe cases.Compared with drilling,the chatter mechanism of robotic countersinking is more complex.The external excitation changes with cutting width and depth in countersinking.This characteristic results in time-varying and nonlinearity of robotic countersinking dynamics.Thus,it is urgent to propose a new method of chatter suppression and provide an accurate stability analysis model.As a new special machining technology,rotary ultrasonic machining has been proved to improve robotic drilling and milling stability effectively.Based on this,robotic rotary ultrasonic countersinking(RRUC)is proposed to improve the robotic countersinking stability in this paper.A three-dimensional stability domain method of RRUC is established.First,the countersinking process was divided intoρparts.The dynamic model of every unit was constructed based on ultrasonic function angle(γ)and dynamic chip area.Then,the stability region of RRUC is obtained based on the semi-discrete method(SDM).Compared with the robotic conventional countersinking(RCC),RRUC improves the stability by 27%.Finally,the correctness and effectiveness of the stability region model are proved by robotic ultrasonic countersinking experiments. 展开更多
关键词 Industrial robot Rotary ultrasonic machining Dynamic model Countersinking chatter Stability analysis
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In-situ synthesis of high-entropy Al_(2)O_(3)/RE_(3)Al_(5)O_(12)/ZrO_(2) ceramic by laser powder bed fusion with exceptional properties
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作者 Zhiwei Xiong Kai Zhang +3 位作者 wenhe liao Tingting Liu Yang Zhang Zhiguang Zhu 《Journal of Advanced Ceramics》 2024年第12期2004-2020,共17页
Eutectic ceramics with exceptional hardness,elevated Young’s modulus,and impressive fracture toughness have become indispensable materials for various demanding industrial applications in extreme environments.In this... Eutectic ceramics with exceptional hardness,elevated Young’s modulus,and impressive fracture toughness have become indispensable materials for various demanding industrial applications in extreme environments.In this work,in-situ synthesis of high-entropy Al_(2)O_(3)/(Y_(0.2)Eu_(0.2)Er_(0.2)Yb_(0.2)Lu_(0.2))_(3)Al_(5)O_(12)/ZrO_(2)ceramics was successfully achieved with onestep slurry-based laser powder bed fusion(LPBF).The phase formation,microstructure morphologies,phase distribution,crystallographic characteristics,and mechanical properties were systematically investigated.The typical microstructure of a shell–core architecture resembling cell-like features consists of both crystalline and amorphous phases.The selective aggregation of constituents is the combined outcome of solute exclusion and convective transport mechanisms.The crystallographic orientation relationships inside the shell may include■ZrO_(2)//RE_(3)Al_(5)O_(12)and RE_(3)Al_(5)O_(12)//ZrO_(2).During the rapid cooling of LPBF,the amorphous phase is an intermediate metastable product of crystal structure adjustment(REAlO_(3),RE_(4)Al_(2)O_(9)→amorphous phase→RE_(3)Al_(5)O_(12)).Owing to the slower diffusion rate and higher transition energy threshold of Eu elements,more Eu elements are retained in the amorphous phase.Structural analysis indicates that the remarkable mechanical properties can be attributed to several factors,including the significant dissociation energy,strong cationic field,and stress transfer among Al_(2)O_(3),RE_(3)Al_(5)O_(12),ZrO_(2),and the amorphous phase.Additionally,the cocktail effect and plastic deformation mechanism of the high-entropy shell contribute to these properties. 展开更多
关键词 laser powder bed fusion(LPBF) Al_(2)O_(3)-RE_(3)Al_(5)O_(12)-ZrO_(2) high-entropy ceramic mechanical properties crystallographic characteristics
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