The kinetics of PTC-Wittig reaction between substituted aromatic aldehydes and 2-butenyl methyldiphenylphosphonium salt has been studied. The low reaction constant (ρ=0. 30) implies that these PTC-Wittig reactions ta...The kinetics of PTC-Wittig reaction between substituted aromatic aldehydes and 2-butenyl methyldiphenylphosphonium salt has been studied. The low reaction constant (ρ=0. 30) implies that these PTC-Wittig reactions take place through low polar intermediate.展开更多
The first aliphatic phosphenium cation featuring a P-S bond (dimethylamino)(methylthio)phosphenium cation 1.has been prepared by treatument of the (dimethylamino)(methylthio) chlorophosphines 2 wih the stoichiometri q...The first aliphatic phosphenium cation featuring a P-S bond (dimethylamino)(methylthio)phosphenium cation 1.has been prepared by treatument of the (dimethylamino)(methylthio) chlorophosphines 2 wih the stoichiometri quantity of AlCl3 in CH2Cl2 solution, and charcterized by 1H 13C 27Al and 31P NMR spectroseopy展开更多
A series of new ω-azolylalkenes 3 were synthesized by N-alkylation of ffobromoalkenes 2 which were obtained by Witting reaction of ω-hydroxyalkylphosphonium bromide with aromatic aldehydes and subsequent bromination...A series of new ω-azolylalkenes 3 were synthesized by N-alkylation of ffobromoalkenes 2 which were obtained by Witting reaction of ω-hydroxyalkylphosphonium bromide with aromatic aldehydes and subsequent bromination. The structures of products were confirmed by 1HNMR, IR,MS and elemental analysis. The preliminary bioassay indicated that some of them had high flingicidal activities.展开更多
文摘The kinetics of PTC-Wittig reaction between substituted aromatic aldehydes and 2-butenyl methyldiphenylphosphonium salt has been studied. The low reaction constant (ρ=0. 30) implies that these PTC-Wittig reactions take place through low polar intermediate.
文摘The first aliphatic phosphenium cation featuring a P-S bond (dimethylamino)(methylthio)phosphenium cation 1.has been prepared by treatument of the (dimethylamino)(methylthio) chlorophosphines 2 wih the stoichiometri quantity of AlCl3 in CH2Cl2 solution, and charcterized by 1H 13C 27Al and 31P NMR spectroseopy
文摘A series of new ω-azolylalkenes 3 were synthesized by N-alkylation of ffobromoalkenes 2 which were obtained by Witting reaction of ω-hydroxyalkylphosphonium bromide with aromatic aldehydes and subsequent bromination. The structures of products were confirmed by 1HNMR, IR,MS and elemental analysis. The preliminary bioassay indicated that some of them had high flingicidal activities.
