Three types of activators such as sodium hydroxide,calcium oxide and triethanolamine(TEA)are used to establish different activation environments to address the problems associated with the process of activating fly as...Three types of activators such as sodium hydroxide,calcium oxide and triethanolamine(TEA)are used to establish different activation environments to address the problems associated with the process of activating fly ash paste.We conducted mechanical tests and numerical simulations to understand the evolution of microstructure,and used environmental scanning electron microscopy(ESEM)and energy dispersive spectroscopy(EDS)techniques to analyze the microenvironments of the samples.The mechanical properties of fly ash paste under different activation conditions and the changes in the microstructure and composition were investigated.The results revealed that under conditions of low NaOH content(1%-3%),the strength of the sample increased significantly.When the content exceeded 4%,the rate of increase in strength decreased.Based on the results,the optimal NaOH content was identified,which was about 4%.A good activation effect,especially for short-term activation(3-7 d),was achieved using TEA under high doping conditions.The activation effect was poor for long-term strength after 28 days.The CaO content did not significantly affect the degree of activation achieved.The maximum effect was exerted when the content of CaO was 2%.The virtual cement and concrete testing laboratory(VCCTL)was used to simulate the hydration process,and the results revealed that the use of the three types of activators accelerated the formation of Ca(OH)_(2) in the system.The activators also corroded the surface of the fly ash particles,resulting in a pozzolanic reaction.The active substances in fly ash were released efficiently,and hydration was realized.The pores were filled with hydration products,and the microstructure changed to form a new frame of paste filling that helped improve the strength of fly ash paste.展开更多
通过微细观结构分析、低场核磁共振量化研究,科学、准确地描述膏体跨尺度颗粒群存在形态与水分赋存状态,并基于有限元和离散元耦合数值分析方法分析了泵压扰动下膏体颗粒流态演化规律.研究发现,膏体料浆中的吸附水、间隙水和弱自由水存...通过微细观结构分析、低场核磁共振量化研究,科学、准确地描述膏体跨尺度颗粒群存在形态与水分赋存状态,并基于有限元和离散元耦合数值分析方法分析了泵压扰动下膏体颗粒流态演化规律.研究发现,膏体料浆中的吸附水、间隙水和弱自由水存在动态连通与转化行为,并主要以吸附水形式存在,低场核磁共振技术(Low-field nuclear magnetic resonance,LF-NMR)弛豫强度与吸附水峰面积非线性增强,与料浆的流动表现出显著的正相关性.液网结构与絮网结构反映了导水通道的活跃性与力链结构的强度,共同组成了膏体稳定性与流动性的双支撑骨架结构.通过Fluent-EDEM软件耦合模拟,分析了脉冲泵压环境颗粒运动行为,在速度差的影响下高、低流速颗粒冲击扰动加剧,力链接触作用增强,流态均匀性和整体颗粒运动稳定性可有效提高.展开更多
基金Supported by Yunnan Major Scientific and Technological Projects(No.202403AA080001)National Natural Science Foundation of China(No.52074137)Yunnan Fundamental Research Projects(No.202201AT070151)。
文摘Three types of activators such as sodium hydroxide,calcium oxide and triethanolamine(TEA)are used to establish different activation environments to address the problems associated with the process of activating fly ash paste.We conducted mechanical tests and numerical simulations to understand the evolution of microstructure,and used environmental scanning electron microscopy(ESEM)and energy dispersive spectroscopy(EDS)techniques to analyze the microenvironments of the samples.The mechanical properties of fly ash paste under different activation conditions and the changes in the microstructure and composition were investigated.The results revealed that under conditions of low NaOH content(1%-3%),the strength of the sample increased significantly.When the content exceeded 4%,the rate of increase in strength decreased.Based on the results,the optimal NaOH content was identified,which was about 4%.A good activation effect,especially for short-term activation(3-7 d),was achieved using TEA under high doping conditions.The activation effect was poor for long-term strength after 28 days.The CaO content did not significantly affect the degree of activation achieved.The maximum effect was exerted when the content of CaO was 2%.The virtual cement and concrete testing laboratory(VCCTL)was used to simulate the hydration process,and the results revealed that the use of the three types of activators accelerated the formation of Ca(OH)_(2) in the system.The activators also corroded the surface of the fly ash particles,resulting in a pozzolanic reaction.The active substances in fly ash were released efficiently,and hydration was realized.The pores were filled with hydration products,and the microstructure changed to form a new frame of paste filling that helped improve the strength of fly ash paste.
文摘通过微细观结构分析、低场核磁共振量化研究,科学、准确地描述膏体跨尺度颗粒群存在形态与水分赋存状态,并基于有限元和离散元耦合数值分析方法分析了泵压扰动下膏体颗粒流态演化规律.研究发现,膏体料浆中的吸附水、间隙水和弱自由水存在动态连通与转化行为,并主要以吸附水形式存在,低场核磁共振技术(Low-field nuclear magnetic resonance,LF-NMR)弛豫强度与吸附水峰面积非线性增强,与料浆的流动表现出显著的正相关性.液网结构与絮网结构反映了导水通道的活跃性与力链结构的强度,共同组成了膏体稳定性与流动性的双支撑骨架结构.通过Fluent-EDEM软件耦合模拟,分析了脉冲泵压环境颗粒运动行为,在速度差的影响下高、低流速颗粒冲击扰动加剧,力链接触作用增强,流态均匀性和整体颗粒运动稳定性可有效提高.
