An embedded underground coal seam carries channel waves of low seismic velocity along a stratigraphic rock-coal-rock sequence.In a homogeneous and isotropic seam, seismic waves propagate as trapped waves within the se...An embedded underground coal seam carries channel waves of low seismic velocity along a stratigraphic rock-coal-rock sequence.In a homogeneous and isotropic seam, seismic waves propagate as trapped waves within the seam, which leads to propagation of channel waves.We describe how to set up a field test for transmission in order to acquire channel waves in a coal seam.Because channel wave signals are non-stationary in their frequencies and amplitudes, a necessary velocity spectrum and wavelet transformation analysis are applied to interpret the characteristics of channel waves.The advantage of using a wavelet transformation is that different resolutions can be obtained at different times and different frequencies.According to analysis of the seismic signals acquired in the S7 sensor hole, it was clearly shown that the characteristics of channel waves are lower frequencies and attenuation which can guide an effective wave for detecting voids, boundaries and faults in coal seams with strong roofs and floors.展开更多
Binary metal oxide（MnOx-A/TiO2）catalysts were prepared by adding the second metal to manganese oxides supported on titanium dioxide（TiO2）,where,A indicates Fe2O3,WO3,MoO3,and Cr2O3.Their catalytic activity,N2 sele...Binary metal oxide（MnOx-A/TiO2）catalysts were prepared by adding the second metal to manganese oxides supported on titanium dioxide（TiO2）,where,A indicates Fe2O3,WO3,MoO3,and Cr2O3.Their catalytic activity,N2 selectivity,and SO2 poisonous tolerance were investigated.The catalytic performance at low temperatures decreased in the following order：Mn-W/TiO2〉Mn-Fe/TiO2〉Mn-Cr/TiO2〉Mn-Mo/TiO2,whereas the N2 selectivity decreased in the order：Mn-Fe/TiO2〉Mn-W/TiO2〉Mn-Mo/TiO2〉Mn-Cr/TiO2.In the presence of 0.01%SO2 and 6%H2O,the NOx conversions in the presence of Mn-W/TiO2,Mn-Fe/TiO2,or Mn-Mo/TiO2 maintain 98.5%,95.8%and 94.2%, respectively,after 8 h at 120°C at GHSV 12600 h？ 1 .As effective promoters,WO3 and Fe2O3 can increase N2 selectivity and the resistance to SO2 of MnOx/TiO2 significantly.The Fourier transform infrared（FTIR）spectra of NH3 over WO3 show the presence of Lewis acid sites.The results suggest that WO3 is the best promoter of MnOx/TiO2,and Mn-W/TiO2 is one of the most active catalysts for the low temperature selective catalytic reduction of NO with NH3.展开更多
Poly（N-vinylpyrrolidone）（PVP）nanofibers containing gold nanoparticles were prepared by electrospinning method.This simple route was used to prepare composites on a large scale,and the syntheses are simple.The opti...Poly（N-vinylpyrrolidone）（PVP）nanofibers containing gold nanoparticles were prepared by electrospinning method.This simple route was used to prepare composites on a large scale,and the syntheses are simple.The optical property of gold nanoparticles in PVP aqueous solution was investigated by UV-Visible absorption spectra.The morphology of the fibers and the distribution of particles were characterized by transmission electron microscopy.The structure of the composite was characterized by Fourier transform infrared spectroscopy.展开更多
Enantiomeric four chelated planar square schiff base Cu 2+ and Ni 2+ complexes were synthesized using ( 1R,trans ) and ( 1S,trans) N,N bis(2 hydroxyphenyl methylene) 1,2 diaminocyclohexane. Th...Enantiomeric four chelated planar square schiff base Cu 2+ and Ni 2+ complexes were synthesized using ( 1R,trans ) and ( 1S,trans) N,N bis(2 hydroxyphenyl methylene) 1,2 diaminocyclohexane. The chirality could not be shown by usual UV Vis spectra. The intrinsic chiral difference of the enantiomeric complexes can be displayed by circular dichroism(CD) spectra. The Cotton effect of every polarlight sensitive absorption of one enantiomer will be the opposite of that of the other enantiomer. It was found that no tetrahedron form exists for Ni 2+ complexes, which was determined with UV Vis spectra and Electron Paramagnetic Resonance(EPR) measures.展开更多
基金Project B2532532 supported by the U.S. Mine Safety and Health Administration
文摘An embedded underground coal seam carries channel waves of low seismic velocity along a stratigraphic rock-coal-rock sequence.In a homogeneous and isotropic seam, seismic waves propagate as trapped waves within the seam, which leads to propagation of channel waves.We describe how to set up a field test for transmission in order to acquire channel waves in a coal seam.Because channel wave signals are non-stationary in their frequencies and amplitudes, a necessary velocity spectrum and wavelet transformation analysis are applied to interpret the characteristics of channel waves.The advantage of using a wavelet transformation is that different resolutions can be obtained at different times and different frequencies.According to analysis of the seismic signals acquired in the S7 sensor hole, it was clearly shown that the characteristics of channel waves are lower frequencies and attenuation which can guide an effective wave for detecting voids, boundaries and faults in coal seams with strong roofs and floors.
文摘Binary metal oxide（MnOx-A/TiO2）catalysts were prepared by adding the second metal to manganese oxides supported on titanium dioxide（TiO2）,where,A indicates Fe2O3,WO3,MoO3,and Cr2O3.Their catalytic activity,N2 selectivity,and SO2 poisonous tolerance were investigated.The catalytic performance at low temperatures decreased in the following order：Mn-W/TiO2〉Mn-Fe/TiO2〉Mn-Cr/TiO2〉Mn-Mo/TiO2,whereas the N2 selectivity decreased in the order：Mn-Fe/TiO2〉Mn-W/TiO2〉Mn-Mo/TiO2〉Mn-Cr/TiO2.In the presence of 0.01%SO2 and 6%H2O,the NOx conversions in the presence of Mn-W/TiO2,Mn-Fe/TiO2,or Mn-Mo/TiO2 maintain 98.5%,95.8%and 94.2%, respectively,after 8 h at 120°C at GHSV 12600 h？ 1 .As effective promoters,WO3 and Fe2O3 can increase N2 selectivity and the resistance to SO2 of MnOx/TiO2 significantly.The Fourier transform infrared（FTIR）spectra of NH3 over WO3 show the presence of Lewis acid sites.The results suggest that WO3 is the best promoter of MnOx/TiO2,and Mn-W/TiO2 is one of the most active catalysts for the low temperature selective catalytic reduction of NO with NH3.
文摘Poly（N-vinylpyrrolidone）（PVP）nanofibers containing gold nanoparticles were prepared by electrospinning method.This simple route was used to prepare composites on a large scale,and the syntheses are simple.The optical property of gold nanoparticles in PVP aqueous solution was investigated by UV-Visible absorption spectra.The morphology of the fibers and the distribution of particles were characterized by transmission electron microscopy.The structure of the composite was characterized by Fourier transform infrared spectroscopy.
文摘Enantiomeric four chelated planar square schiff base Cu 2+ and Ni 2+ complexes were synthesized using ( 1R,trans ) and ( 1S,trans) N,N bis(2 hydroxyphenyl methylene) 1,2 diaminocyclohexane. The chirality could not be shown by usual UV Vis spectra. The intrinsic chiral difference of the enantiomeric complexes can be displayed by circular dichroism(CD) spectra. The Cotton effect of every polarlight sensitive absorption of one enantiomer will be the opposite of that of the other enantiomer. It was found that no tetrahedron form exists for Ni 2+ complexes, which was determined with UV Vis spectra and Electron Paramagnetic Resonance(EPR) measures.
