Ordinary Portland Cement (OPC) is by mass the largest manufactured product on Earth, responsible for approximately 6% - 8% of global anthropogenic carbon dioxide emissions (CO<sub>2</sub>) and 35% of indus...Ordinary Portland Cement (OPC) is by mass the largest manufactured product on Earth, responsible for approximately 6% - 8% of global anthropogenic carbon dioxide emissions (CO<sub>2</sub>) and 35% of industrial CO<sub>2</sub> emissions. On average 0.8 to 0.9 ton of CO<sub>2</sub> is emitted to produce one ton of OPC. In this paper, partial substitution of clinker (30% - 35%) by the calcined clay-limestone mixture was investigated in order to produce an eco-cement (LC3). Analyzes by XRF, XRD and ATG/ATD have characterized different components, determined the calcination temperature and selected the right clay which can act as effective Supplementary Cementitious Material (SCM). Mechanical tests on mortar carried out over a period of 90 days. The WBCSD/WRI “Greenhouse Gas Protocol” methodology then allowed the calculation of CO<sub>2</sub> emissions into the atmosphere. Three types of clay are available in the Songololo Region. The kaolinite is the principal clay mineral and its content varies from 27% to 34%. The sum of kaolinite and amorphous phase which enable clay to react with cementitious material ranges from 57% to 60%. The SiO<sub>2</sub> content ranges from 33% to 76%, the Alumina content from 12% to 20% so that the ratio Al<sub>2</sub>O<sub>3</sub>/SiO<sub>2</sub> is on the higher side (0.17 - 0.53). The calcination window is between 750°C and 850°C and the best clay which can act as SCM identified. The clinker’s substitution reduced CO<sub>2</sub> emissions from 0.824 ton of CO<sub>2</sub> for one ton of OPC to 0.640 ton of CO<sub>2</sub> for one ton of LC3, means 22% less emissions. The compressive strengths developed by LC3 vary from 8.91 to 57.6 MPa (Day 1 to Day 90), exceed those of references 32.5 cement and are close to 42.5 cement. In view of the results, LC3 cement can be considered for industrial trials.展开更多
The bauxitic region of Sumbi and its surroundings in Central Kongo (DR Congo) is located in an area corresponding to “bands” of basic rocks made up of microdolerites, basalts and andesites. The problem of this study...The bauxitic region of Sumbi and its surroundings in Central Kongo (DR Congo) is located in an area corresponding to “bands” of basic rocks made up of microdolerites, basalts and andesites. The problem of this study is linked to the similarity of the phenomena that generated the depositional process of these ferruginous and aluminous formations. The aim of this article is to carry out a chemical and petrographic study of samples of bauxitic materials from the Mayedo and Kinzoki regions, with a view to their possible recovery. To this end, the chemical and petrographic analysis of the weathering formations outcropping in the study area was carried out using X-ray fluorescence and thin section methods. The latter revealed that two lithologies were detected in the healthy rocks: basalts with a mineralogical assemblage of plagioclase crystals, pyroxene microcrystals and oxide opaques;and dolerites represented by plagioclase crystals, pyroxenes and a few quartz crystals. X-ray fluorescence revealed high levels of Al<sub>2</sub>O<sub>3</sub> (32.69%) in the Mayedo zone (MHb1). This visibly gibbsite-rich level corresponds to the zone of friable, homogeneous bauxite with a massive, blood-red texture, with an estimated gibbsite percentage of 55.50. The percentage of Fe<sub>2</sub>O<sub>3</sub> is high in these zones at 42.77%, hence the dark red colour, reflecting a strong zone of ferruginasation. This horizon contains a high concentration of hematite and goethite minerals. Highly variable SiO<sub>2</sub> contents ranging from 13.48% to 40.82%. These variations are essentially due to the dissolution of silica by leaching and resilification.展开更多
Zatua Hills are located in the northeastern part of the DR Congo in Haut Uélé Province, formerly known as Province Orientale. This part of DR Congo is identified by the high elevated zone, which has rem...Zatua Hills are located in the northeastern part of the DR Congo in Haut Uélé Province, formerly known as Province Orientale. This part of DR Congo is identified by the high elevated zone, which has remained a witness to a stable zone not affected by the ancient erosion process. BIFs are most abundant and are dated to the Neoarchaean and Late Kibalian, hosted in the Upper Congo Granites Massifs of the DR. Congo. Zatua Hills consist of dolerite, phyllade, clay-rich sediment, poor itabirite, enriched BIFs, friable hematite, hard hematite, and mineralized and unmineralized breccias. Field study and geochemistry analysis by XRF, XRD, and ICP-MS are executed in order to know the geochemistry signature and paragenesis of Zatua Hills and the probably process could lead the BIFs to iron ore. The geochemistry analysis by XRF, XRD, and ICP-MS shows that Iron ore content has an iron rate between 57% and 69% with less deleterious elements such as Si, P, and Al. These deleterious elements are secondary and have silicium composition (probably quartz or chert, goethite, and Kaolinite), aluminum (probably gibbsite, variscite, cadwaladérite, goethite, and Kaolinite), phosphorous (probably variscite), and hydrated minerals, which are grown LOI in the samples. Hypogen and supergen processes are played in BIFs for iron ore conversion and, respectively, silica dissolution and leaching. Metamorphism was also impacted and marked by the Ti element (anatase) in samples, contributing to the crystallization of martite to hematite after magnetite oxidation.展开更多
Zatua Hills are located at Haut Uélé Province of Democratic Republic of Congo (DRC), between northern Bafwasende and southern Paulis (Isiro) Squarred Degrees. Belonging to greenstone belt of Ngayu, that area...Zatua Hills are located at Haut Uélé Province of Democratic Republic of Congo (DRC), between northern Bafwasende and southern Paulis (Isiro) Squarred Degrees. Belonging to greenstone belt of Ngayu, that area is identified by the high elevated zone which is remained the witness of stable zone, not affected by the ancienst erosion process. Zatua Hills are in the superior Kibalian formation dated to Neoarchaen, hosted in Upper Congo Granites Massifs of DRC covering a large central zone of NE of DRC, and consisting to dolerite, phyllade, clay rich sediment, poor Banded Iron Formations (BIFs), enriched BIFs, friable hematite, hard hematite, mineralized and unmineralized brechias. Magnetite, martite and hematite are associated to some secondary minerals such as goethite, gibbsite, kaolinite, strengite, variscite and others clay minerals present in BIFs. Petrographic analysis made from the samples collected in situ showed, as well as BIFs and iron ore associated, that magnetite was much abundant oxide mineral which is oxided to martite before to stabilize to hematite during the deposition time. Having about hundred meters of thickness, the rich iron ore of this area content, in the majority less deleterious elements which, are harmful in metallurgic process of iron. These secondary minerals were precipitated at various degrees in the leached cavities of rocks between martite and hematite aggregates to botryoidal texture and, are rich to Al, and are mainly consisting to gibbsite and solid solution series of variscite-strengite (AlPO<sub>4</sub>·2H<sub>2</sub>O and FePO<sub>4</sub>·2H<sub>2</sub>O). Low degree of metamorphism played when magnetite was converted to martite, with the presence of variscite and anatase like witnesses of this event in which, martite was crystalized to hematite.展开更多
文摘Ordinary Portland Cement (OPC) is by mass the largest manufactured product on Earth, responsible for approximately 6% - 8% of global anthropogenic carbon dioxide emissions (CO<sub>2</sub>) and 35% of industrial CO<sub>2</sub> emissions. On average 0.8 to 0.9 ton of CO<sub>2</sub> is emitted to produce one ton of OPC. In this paper, partial substitution of clinker (30% - 35%) by the calcined clay-limestone mixture was investigated in order to produce an eco-cement (LC3). Analyzes by XRF, XRD and ATG/ATD have characterized different components, determined the calcination temperature and selected the right clay which can act as effective Supplementary Cementitious Material (SCM). Mechanical tests on mortar carried out over a period of 90 days. The WBCSD/WRI “Greenhouse Gas Protocol” methodology then allowed the calculation of CO<sub>2</sub> emissions into the atmosphere. Three types of clay are available in the Songololo Region. The kaolinite is the principal clay mineral and its content varies from 27% to 34%. The sum of kaolinite and amorphous phase which enable clay to react with cementitious material ranges from 57% to 60%. The SiO<sub>2</sub> content ranges from 33% to 76%, the Alumina content from 12% to 20% so that the ratio Al<sub>2</sub>O<sub>3</sub>/SiO<sub>2</sub> is on the higher side (0.17 - 0.53). The calcination window is between 750°C and 850°C and the best clay which can act as SCM identified. The clinker’s substitution reduced CO<sub>2</sub> emissions from 0.824 ton of CO<sub>2</sub> for one ton of OPC to 0.640 ton of CO<sub>2</sub> for one ton of LC3, means 22% less emissions. The compressive strengths developed by LC3 vary from 8.91 to 57.6 MPa (Day 1 to Day 90), exceed those of references 32.5 cement and are close to 42.5 cement. In view of the results, LC3 cement can be considered for industrial trials.
文摘The bauxitic region of Sumbi and its surroundings in Central Kongo (DR Congo) is located in an area corresponding to “bands” of basic rocks made up of microdolerites, basalts and andesites. The problem of this study is linked to the similarity of the phenomena that generated the depositional process of these ferruginous and aluminous formations. The aim of this article is to carry out a chemical and petrographic study of samples of bauxitic materials from the Mayedo and Kinzoki regions, with a view to their possible recovery. To this end, the chemical and petrographic analysis of the weathering formations outcropping in the study area was carried out using X-ray fluorescence and thin section methods. The latter revealed that two lithologies were detected in the healthy rocks: basalts with a mineralogical assemblage of plagioclase crystals, pyroxene microcrystals and oxide opaques;and dolerites represented by plagioclase crystals, pyroxenes and a few quartz crystals. X-ray fluorescence revealed high levels of Al<sub>2</sub>O<sub>3</sub> (32.69%) in the Mayedo zone (MHb1). This visibly gibbsite-rich level corresponds to the zone of friable, homogeneous bauxite with a massive, blood-red texture, with an estimated gibbsite percentage of 55.50. The percentage of Fe<sub>2</sub>O<sub>3</sub> is high in these zones at 42.77%, hence the dark red colour, reflecting a strong zone of ferruginasation. This horizon contains a high concentration of hematite and goethite minerals. Highly variable SiO<sub>2</sub> contents ranging from 13.48% to 40.82%. These variations are essentially due to the dissolution of silica by leaching and resilification.
文摘Zatua Hills are located in the northeastern part of the DR Congo in Haut Uélé Province, formerly known as Province Orientale. This part of DR Congo is identified by the high elevated zone, which has remained a witness to a stable zone not affected by the ancient erosion process. BIFs are most abundant and are dated to the Neoarchaean and Late Kibalian, hosted in the Upper Congo Granites Massifs of the DR. Congo. Zatua Hills consist of dolerite, phyllade, clay-rich sediment, poor itabirite, enriched BIFs, friable hematite, hard hematite, and mineralized and unmineralized breccias. Field study and geochemistry analysis by XRF, XRD, and ICP-MS are executed in order to know the geochemistry signature and paragenesis of Zatua Hills and the probably process could lead the BIFs to iron ore. The geochemistry analysis by XRF, XRD, and ICP-MS shows that Iron ore content has an iron rate between 57% and 69% with less deleterious elements such as Si, P, and Al. These deleterious elements are secondary and have silicium composition (probably quartz or chert, goethite, and Kaolinite), aluminum (probably gibbsite, variscite, cadwaladérite, goethite, and Kaolinite), phosphorous (probably variscite), and hydrated minerals, which are grown LOI in the samples. Hypogen and supergen processes are played in BIFs for iron ore conversion and, respectively, silica dissolution and leaching. Metamorphism was also impacted and marked by the Ti element (anatase) in samples, contributing to the crystallization of martite to hematite after magnetite oxidation.
文摘Zatua Hills are located at Haut Uélé Province of Democratic Republic of Congo (DRC), between northern Bafwasende and southern Paulis (Isiro) Squarred Degrees. Belonging to greenstone belt of Ngayu, that area is identified by the high elevated zone which is remained the witness of stable zone, not affected by the ancienst erosion process. Zatua Hills are in the superior Kibalian formation dated to Neoarchaen, hosted in Upper Congo Granites Massifs of DRC covering a large central zone of NE of DRC, and consisting to dolerite, phyllade, clay rich sediment, poor Banded Iron Formations (BIFs), enriched BIFs, friable hematite, hard hematite, mineralized and unmineralized brechias. Magnetite, martite and hematite are associated to some secondary minerals such as goethite, gibbsite, kaolinite, strengite, variscite and others clay minerals present in BIFs. Petrographic analysis made from the samples collected in situ showed, as well as BIFs and iron ore associated, that magnetite was much abundant oxide mineral which is oxided to martite before to stabilize to hematite during the deposition time. Having about hundred meters of thickness, the rich iron ore of this area content, in the majority less deleterious elements which, are harmful in metallurgic process of iron. These secondary minerals were precipitated at various degrees in the leached cavities of rocks between martite and hematite aggregates to botryoidal texture and, are rich to Al, and are mainly consisting to gibbsite and solid solution series of variscite-strengite (AlPO<sub>4</sub>·2H<sub>2</sub>O and FePO<sub>4</sub>·2H<sub>2</sub>O). Low degree of metamorphism played when magnetite was converted to martite, with the presence of variscite and anatase like witnesses of this event in which, martite was crystalized to hematite.
