In order to analyze the thermal decomposition of MT based pyrolant in nitrogen and air environments,the thermal analysis experiments of MT and MTV pyrolants were carried out by TG-DTA and DSC.The results show that,in ...In order to analyze the thermal decomposition of MT based pyrolant in nitrogen and air environments,the thermal analysis experiments of MT and MTV pyrolants were carried out by TG-DTA and DSC.The results show that,in nitrogen environment,the spectrum result of Grignard-type reaction~[6] is verified by the decomposition characteristics of MT and MTV pyrolants.8.71% of Mg is consumed in the intermediate reaction of MT at 500-596 ℃ and the heat release of reaction is 31.93 k J/g.The endothermic decomposition of the intermediate product is at 684-740 ℃.In MTV,the intermediate reaction is at 435-595 ℃ and the heat release of reaction are increased by the addition of fluororubber.The intermediate product degrades at 677-745 ℃.In air environment,the decomposition of MT and MTV show the different reaction mechanism from the nitrogen environment.The presence of oxygen is involved in the reaction of Mg,and inhibits the intermediate reaction process of Mg and PTFE.展开更多
Aiming at the characteristics of the long tubular powder,a one-dimensional discrete group gas-solid two-phase flow model was established for the large caliber high speed Davis gun with a tubular modular charge.In this...Aiming at the characteristics of the long tubular powder,a one-dimensional discrete group gas-solid two-phase flow model was established for the large caliber high speed Davis gun with a tubular modular charge.In this model,the tubular modules were described by the Lagrangian system without being assumed as pseudofluid,whereas the gas field is described by Eulerian system.The new model was used to simulate a 480 mm Davis gun.The simulation results were compared with test results,and the model was verified to be feasibility.This study provides a new method to research the interior ballistic performance of Davis guns.展开更多
基金Sponsored by the National Natural Science Foundation of China(Grant No.51076066)
文摘In order to analyze the thermal decomposition of MT based pyrolant in nitrogen and air environments,the thermal analysis experiments of MT and MTV pyrolants were carried out by TG-DTA and DSC.The results show that,in nitrogen environment,the spectrum result of Grignard-type reaction~[6] is verified by the decomposition characteristics of MT and MTV pyrolants.8.71% of Mg is consumed in the intermediate reaction of MT at 500-596 ℃ and the heat release of reaction is 31.93 k J/g.The endothermic decomposition of the intermediate product is at 684-740 ℃.In MTV,the intermediate reaction is at 435-595 ℃ and the heat release of reaction are increased by the addition of fluororubber.The intermediate product degrades at 677-745 ℃.In air environment,the decomposition of MT and MTV show the different reaction mechanism from the nitrogen environment.The presence of oxygen is involved in the reaction of Mg,and inhibits the intermediate reaction process of Mg and PTFE.
文摘Aiming at the characteristics of the long tubular powder,a one-dimensional discrete group gas-solid two-phase flow model was established for the large caliber high speed Davis gun with a tubular modular charge.In this model,the tubular modules were described by the Lagrangian system without being assumed as pseudofluid,whereas the gas field is described by Eulerian system.The new model was used to simulate a 480 mm Davis gun.The simulation results were compared with test results,and the model was verified to be feasibility.This study provides a new method to research the interior ballistic performance of Davis guns.
