Higher alcohols are key factors affecting sensory quality and post-drinking comfort of alcoholic beverages. A strategy combining solid-phase extraction and gas chromatography-mass spectrometry(SPE-GC-MS) was establish...Higher alcohols are key factors affecting sensory quality and post-drinking comfort of alcoholic beverages. A strategy combining solid-phase extraction and gas chromatography-mass spectrometry(SPE-GC-MS) was established to analyze the metabolism pattern of higher alcohols in rat plasma after gavage of 4 common alcoholic beverages including huangjiu, baijiu, wine and brandy. 7 mL of dichloromethane was determined as the optimal extraction condition, and 8 higher alcohols were precisely quantified with detection limits of 1.82-11.65 μg/L, recoveries of 89.07%-110.89% and fine repeatability. The fastest absorption and elimination rates of plasma total higher alcohols were observed in baijiu and huangjiu group, respectively, and the highest peak concentration was found in brandy group. Additionally, the metabolic rate of plasma isoamyl alcohol in huangjiu group was faster than that in wine group at the same intragastric administration dosage. This study may provide potential insight for evaluation of alcoholic beverage quality.展开更多
Transition metal compounds are attractive for their significant applications in supercapacitors and as non-noble metal catalysts for electrochemical water splitting.Herein,we develop Ni3 S2 nanorods growing directly o...Transition metal compounds are attractive for their significant applications in supercapacitors and as non-noble metal catalysts for electrochemical water splitting.Herein,we develop Ni3 S2 nanorods growing directly on Ni foam,which act as multifunctional additive-free Ni3 S2@Ni electrode for supercapacitor and overall water splitting.Based on PVA-KOH gel electrolyte,the assembled all-solid-state Ni3 S2@Ni//AC asymmetric supercapacitor delivers a high areal energy density of 0.52 mWh cm^-2 at an areal power density of 9.02 MW cm^-2,and exhibits an excellent cycling stability with a capacitance retention ratio of 89%after 10000 GCD cycles at a current density of 30 mA cm^-2.For hydrogen evolution reaction and oxygen evolution reaction in 1 M KOH,Ni3 S2@Ni electrode achieves a benchmark of 10 mA cm^-2at overpotentials of 82 mV and 310 mV,respectively.Furthermore,the assembled Ni3 S2@Ni‖Ni3 S2@Ni electrolyzer for overall water splitting attains a current density of 10 mA cm^-2 at 1.61 V.The in-situ synthesis of Ni3 S2@Ni electrode enriches the applications of additive-free transition metal compounds in high-performance energy storage devices and efficient electrocatalysis.展开更多
The anaerobic bacteria can cause infections in different parts of the body, including appendicitis, cholecystitis, otitis media, oral infections, endocarditis, endometritis, brain abscess, myocardial necrosis, osteomy...The anaerobic bacteria can cause infections in different parts of the body, including appendicitis, cholecystitis, otitis media, oral infections, endocarditis, endometritis, brain abscess, myocardial necrosis, osteomyelitis, peritonitis, empyema, salpingitis, septic arthritis, liver abscess, sinusitis, intestinal surgery or post-traumatic wound infections, and bacteremia, such as pelvic inflammatory disease. This paper analyzes the experimental method of anaerobic bacteria to human urinary system through the influence of literature.展开更多
Tight oil in the redeposited carbonates was mainly distributed in the Lower Submember of Member 3 of Shahejie Formation in Shulu sag of Jizhong depression,North China.Through high-resolution 3D seismic data,well loggi...Tight oil in the redeposited carbonates was mainly distributed in the Lower Submember of Member 3 of Shahejie Formation in Shulu sag of Jizhong depression,North China.Through high-resolution 3D seismic data,well logging data and drilling data,the Lower Submember of Member 3 of Shahejie Formation was divided into 5 third-order sequences and 15 parasequence sets.The redeposited marl and rudstone were major reserving horizons of tight oil,and ten reserving space types were developed and could be classified into two main categories,i.e.,pores and fractures.Two types of tight oil reservoirs were established,i.e.,the marl hydrocarbon reservoir of the source-reservoir integration and the rudstone hydrocarbon reservoirs of the source-reservoir paragenesis.The assemblage relationship among the high-quality source rocks,system tracts with the source-reservoir configuration was the major control factor for tight oil accumulation in the redeposited carbonates.The lacustrine transgressive system tracts and highstand systems tracts in SQ1 to SQ5 were the favorable horizons for development of the marl hydrocarbon reservoir,the lowstand system tracts in SQ1 to SQ3 were the favorable horizons for development of the rudstone hydrocarbon reservoir.展开更多
We present a facile synthesis of trigonal selenium with butterfly-like microstructure from elemental sele- nium via a solvothermal and aging route. By using X-ray diffraction and scanning electron microscopy to charac...We present a facile synthesis of trigonal selenium with butterfly-like microstructure from elemental sele- nium via a solvothermal and aging route. By using X-ray diffraction and scanning electron microscopy to characterize the products, a possible growth mechanism is proposed. The solvothermal process pro- motes the dissolution of selenium in ethylenediamine to form a brown homogeneous [Se（en）x] solution. By introducing acetone into this [Se（en）x] solution, amorphous selenium nanoparticles were produced which then transformed into trigonal selenium, which further assembled along the c-axis to form hexag- onal rods. Owing to stereo hindrance as well as to development of opposite lateral sides of the hexagonal rod in opposing directions, a butterfly-like microstructure consisting of two long outside rods and a short inner rod was obtained.展开更多
基金supported by the National Natural Science Foundation of China(22138004 and 32001828).
文摘Higher alcohols are key factors affecting sensory quality and post-drinking comfort of alcoholic beverages. A strategy combining solid-phase extraction and gas chromatography-mass spectrometry(SPE-GC-MS) was established to analyze the metabolism pattern of higher alcohols in rat plasma after gavage of 4 common alcoholic beverages including huangjiu, baijiu, wine and brandy. 7 mL of dichloromethane was determined as the optimal extraction condition, and 8 higher alcohols were precisely quantified with detection limits of 1.82-11.65 μg/L, recoveries of 89.07%-110.89% and fine repeatability. The fastest absorption and elimination rates of plasma total higher alcohols were observed in baijiu and huangjiu group, respectively, and the highest peak concentration was found in brandy group. Additionally, the metabolic rate of plasma isoamyl alcohol in huangjiu group was faster than that in wine group at the same intragastric administration dosage. This study may provide potential insight for evaluation of alcoholic beverage quality.
基金supported by the National Natural Science Foundation of China[grant no.51701022]。
文摘Transition metal compounds are attractive for their significant applications in supercapacitors and as non-noble metal catalysts for electrochemical water splitting.Herein,we develop Ni3 S2 nanorods growing directly on Ni foam,which act as multifunctional additive-free Ni3 S2@Ni electrode for supercapacitor and overall water splitting.Based on PVA-KOH gel electrolyte,the assembled all-solid-state Ni3 S2@Ni//AC asymmetric supercapacitor delivers a high areal energy density of 0.52 mWh cm^-2 at an areal power density of 9.02 MW cm^-2,and exhibits an excellent cycling stability with a capacitance retention ratio of 89%after 10000 GCD cycles at a current density of 30 mA cm^-2.For hydrogen evolution reaction and oxygen evolution reaction in 1 M KOH,Ni3 S2@Ni electrode achieves a benchmark of 10 mA cm^-2at overpotentials of 82 mV and 310 mV,respectively.Furthermore,the assembled Ni3 S2@Ni‖Ni3 S2@Ni electrolyzer for overall water splitting attains a current density of 10 mA cm^-2 at 1.61 V.The in-situ synthesis of Ni3 S2@Ni electrode enriches the applications of additive-free transition metal compounds in high-performance energy storage devices and efficient electrocatalysis.
文摘The anaerobic bacteria can cause infections in different parts of the body, including appendicitis, cholecystitis, otitis media, oral infections, endocarditis, endometritis, brain abscess, myocardial necrosis, osteomyelitis, peritonitis, empyema, salpingitis, septic arthritis, liver abscess, sinusitis, intestinal surgery or post-traumatic wound infections, and bacteremia, such as pelvic inflammatory disease. This paper analyzes the experimental method of anaerobic bacteria to human urinary system through the influence of literature.
基金This work was supported by PetroChina Major Science and Technology Project(No.2017E-015)PetroChina Key Project(No.kt2017-07).
文摘Tight oil in the redeposited carbonates was mainly distributed in the Lower Submember of Member 3 of Shahejie Formation in Shulu sag of Jizhong depression,North China.Through high-resolution 3D seismic data,well logging data and drilling data,the Lower Submember of Member 3 of Shahejie Formation was divided into 5 third-order sequences and 15 parasequence sets.The redeposited marl and rudstone were major reserving horizons of tight oil,and ten reserving space types were developed and could be classified into two main categories,i.e.,pores and fractures.Two types of tight oil reservoirs were established,i.e.,the marl hydrocarbon reservoir of the source-reservoir integration and the rudstone hydrocarbon reservoirs of the source-reservoir paragenesis.The assemblage relationship among the high-quality source rocks,system tracts with the source-reservoir configuration was the major control factor for tight oil accumulation in the redeposited carbonates.The lacustrine transgressive system tracts and highstand systems tracts in SQ1 to SQ5 were the favorable horizons for development of the marl hydrocarbon reservoir,the lowstand system tracts in SQ1 to SQ3 were the favorable horizons for development of the rudstone hydrocarbon reservoir.
基金supports from the Chinese National Foundation of Natural Science Research under Contract No.51102025the Hunan Provincial Natural Science Foundation of China under Contract No.12JJ3039 are gratefully acknowledged
文摘We present a facile synthesis of trigonal selenium with butterfly-like microstructure from elemental sele- nium via a solvothermal and aging route. By using X-ray diffraction and scanning electron microscopy to characterize the products, a possible growth mechanism is proposed. The solvothermal process pro- motes the dissolution of selenium in ethylenediamine to form a brown homogeneous [Se（en）x] solution. By introducing acetone into this [Se（en）x] solution, amorphous selenium nanoparticles were produced which then transformed into trigonal selenium, which further assembled along the c-axis to form hexag- onal rods. Owing to stereo hindrance as well as to development of opposite lateral sides of the hexagonal rod in opposing directions, a butterfly-like microstructure consisting of two long outside rods and a short inner rod was obtained.
