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Regioselective ring opening of epoxides using NH_4SCN/silica sulfuric acid:An efficient approach for the synthesis of β-hydroxy thiocyanate under solvent-free conditions 被引量:2
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作者 Ali R. Kiasat maryam zayadi Mehdi Fallah Mehrjardi 《Chinese Chemical Letters》 SCIE CAS CSCD 2008年第6期665-668,共4页
Silica sulfuric acid was developed as a stable and efficient heterogeneous catalyst in organic synthesis. This solid acid catalyzed the regioselective ring opening of epoxides by thiocyanate anion to give thiocyanohyd... Silica sulfuric acid was developed as a stable and efficient heterogeneous catalyst in organic synthesis. This solid acid catalyzed the regioselective ring opening of epoxides by thiocyanate anion to give thiocyanohydrins as key intermediates in agricultural and pharmaceutical chemistry in high yields under solvent-free conditions. 展开更多
关键词 Silica sulfuric acid Thiocyanohydrins β-Hydroxy thiocyanate EPOXIDE SOLVENT-FREE
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