Many networks in the real world have spatial attributes, such as location of nodes and length of edges, called spatial networks. When these networks are subject to some random or deliberate attacks, some nodes in the ...Many networks in the real world have spatial attributes, such as location of nodes and length of edges, called spatial networks. When these networks are subject to some random or deliberate attacks, some nodes in the network fail, which causes a decline in the network performance. In order to make the network run normally, some of the failed nodes must be recovered. In the case of limited recovery resources, an effective key node identification method can find the key recovering node in the failed nodes, by which the network performance can be recovered most of the failed nodes. We propose two key recovering node identification methods for spatial networks, which are the Euclidean-distance recovery method and the route-length recovery method. Simulations on homogeneous and heterogeneous spatial networks show that the proposed methods can significantly recover the network performance.展开更多
Low photolumines-cence(PL)quantum yield of molybdenum disulfide(MoS_(2))quan-tum dots(QDs)has lim-ited practical applica-tion as potential fluores-cent materials.Here,we report the intercalation of aluminum ion(Al^(3+...Low photolumines-cence(PL)quantum yield of molybdenum disulfide(MoS_(2))quan-tum dots(QDs)has lim-ited practical applica-tion as potential fluores-cent materials.Here,we report the intercalation of aluminum ion(Al^(3+))to enhance the PL of MoS_(2)QDs and the un-derlying mechanism.With detailed characterization and exciton dynamics study,we suggest that additional surface states including new emission centers have been effectively introduced to MoS_(2)QDs by the Al^(3+)intercalation.The synergy of new radiative pathway for exciton re-combination and the passivation of non-radiative surface traps is responsible for the en-hanced fluorescence of MoS_(2)QDs.Our findings demonstrate an efficient strategy to improve the optical properties of MoS_(2)QDs and are important for understanding the regulation effect of surface states on the emission of two dimensional sulfide QDs.展开更多
<div style="text-align:justify;"> This paper introduces the working principle of the balanced heterodyne detection system, establishes the corresponding mathematical model, deduces the signal to noise ...<div style="text-align:justify;"> This paper introduces the working principle of the balanced heterodyne detection system, establishes the corresponding mathematical model, deduces the signal to noise ratio (SNR) formula of the balanced heterodyne detection. By comparing balance heterodyne detection with general coherent detection with MATLAB numerical simulation, the superiority of balance heterodyne detection system is proved theoretically. Finally, the simulation models of ordinary heterodyne detection, balance detection and double balance detection system are built by OptiSystem. The simulation results are consistent with the conclusions derived from the mathematical analysis, which provides a new method for the research of weak laser detection technology. </div>展开更多
Below-cloud aerosol scavenging process by precipitation is important for cleaning the polluted aerosols in the atmosphere, and is also a main process for acid rain formation. However, the related physical mechanism ha...Below-cloud aerosol scavenging process by precipitation is important for cleaning the polluted aerosols in the atmosphere, and is also a main process for acid rain formation. However, the related physical mechanism has not been well documented and clarified yet. In this paper, we investigated the below-cloud PM_(2.5)(particulate matter with aerodynamic diameter being 2.5 μm or less) scavenging by different-intensity rains under polluted conditions characterized by high PM_(2.5) concentrations, based on in-situ measurements from March 2014 to July 2016 in Beijing city. It was found that relatively more intense rainfall events were more efficient in removing the polluted aerosols in the atmosphere. The mean PM_(2.5) scavenging ratio and its standard deviation(SD) were 5.1% ± 25.7%, 38.5% ± 29.0%,and 50.6% ± 21.2% for light, moderate, and heavy rain events, respectively. We further found that the key impact factors on below-cloud PM_(2.5) scavenging ratio for light rain events were rain duration and wind speed rather than raindrop size distribution. However, the impacts of rain duration and wind speed on scavenging ratio were not important for moderate and heavy rain events. To our knowledge, this is the first statistical result about the effects of rain intensity, rain duration, and raindrop size distribution on below-cloud scavenging in China.展开更多
The molecular orientations of p-nitrobenzoic acid (PNBA) on the surface of silver nanoparticles and silver mirror have been investigated by using surface enhanced Raman scattering (SERS) and UV-visible absorption spec...The molecular orientations of p-nitrobenzoic acid (PNBA) on the surface of silver nanoparticles and silver mirror have been investigated by using surface enhanced Raman scattering (SERS) and UV-visible absorption spectroscopy. In the mixed system of silver colloid/PNBA/ethanol, the orientation of PNBA on silver nanoparticles remarkably different from that on silver mirror was observed, and it mainly resulted from the cooperation effect of the adsorption to surface active sites on silver under the pressure of aqueous molecules. This result is of some significance for further studying surface-interfacial structures and properties of silver nanoparticles, and the technique used in this note is feasible to get the SERS spectra of some molecules insoluble in aqueous solution.展开更多
Strong coupling between plasmons and multiple different exciton states(MESs)enables the creation of multiple hybrid polariton states under ambient conditions.These hybrid states possess unique optical properties diffe...Strong coupling between plasmons and multiple different exciton states(MESs)enables the creation of multiple hybrid polariton states under ambient conditions.These hybrid states possess unique optical properties different from those of their separate identities,making them ideal candidates for exploiting room-temperature multimode hybridization and multiqubit operation.In this study,we revealed the static spectral response properties of plasmon-MES strong coupling via a fully quantum mechanics approach.These theoretical predictions were experimentally demonstrated in plasmonic nanocavities containing two and three different exciton species.Additionally,the dynamical absorption processes of such strong coupling systems were investigated,and results indicated that the damping of the hybrid polariton states induced by the strong coupling could be markedly modulated by the acoustic oscillations from the plasmonic nanocavities.Our findings contribute a theoretical approach for accurately describing the plasmon-MES interactions and a platform for developing the high-speed active plasmonic devices based on multiqubit strong coupling.展开更多
In this study, a simple and effective method was proposed to improve the electrocatalytic ability of overoxidized poly(3,4-ethylenedioxythiophene)-overoxidized polypyrrole composite films modified on glassy carbon ele...In this study, a simple and effective method was proposed to improve the electrocatalytic ability of overoxidized poly(3,4-ethylenedioxythiophene)-overoxidized polypyrrole composite films modified on glassy carbon electrode for rutin and luteolin determination. The composite electrode was prepared by cyclic voltammetry copolymerization with LiClO_(4)-water as the supporting electrolyte. The peak current of rutin and luteolin on the composite electrode gradually decreased or even disappeared with the increase in the positive potential limit. After incubation in NaOH–ethanol solution with a volume ratio of 1:1, the composite electrodes prepared at positive potential limit greater than 1.5 V exhibited enhanced differential pulse voltammetry peak currents, reduced charge transfer resistance, larger effective specific surface area and higher electron transfer rate constant. The composite electrode prepared in the potential range of 0–1.7 V showed optimal electrocatalytic performance. The X-ray photoelectron spectroscopy results indicated that the content of –SO_(2)/–SO and –C=N– groups in the composite film increased significantly after incubation. Further, the Raman spectra and Fourier transform infrared spectra revealed that the thiophene ring structure changed from benzene-type to quinone-type, and the quinone-type pyrrole ring was formed. The electrocatalytic mechanism of the composite film was proposed based on the experimental results and further verified by Density Functional Theory calculation.展开更多
基金Project supported by Zhejiang Provincial Natural Science Foundation of China (Grant No. LQ23F030012)the Fundamental Research Funds for the Provincial Universities of Zhejiang (Grant No. GK229909299001-018)。
文摘Many networks in the real world have spatial attributes, such as location of nodes and length of edges, called spatial networks. When these networks are subject to some random or deliberate attacks, some nodes in the network fail, which causes a decline in the network performance. In order to make the network run normally, some of the failed nodes must be recovered. In the case of limited recovery resources, an effective key node identification method can find the key recovering node in the failed nodes, by which the network performance can be recovered most of the failed nodes. We propose two key recovering node identification methods for spatial networks, which are the Euclidean-distance recovery method and the route-length recovery method. Simulations on homogeneous and heterogeneous spatial networks show that the proposed methods can significantly recover the network performance.
基金supported by the National Natural Sci-ence Foundation of China(No.12004101,No.61905066,No.22103024,No.61805070,and No.22105063)the Nat-ural Science Foundation of Henan Province(No.202300410065)the Open Project of the State Key Laboratory of Crop Stress Adaptation and Im-provement.
文摘Low photolumines-cence(PL)quantum yield of molybdenum disulfide(MoS_(2))quan-tum dots(QDs)has lim-ited practical applica-tion as potential fluores-cent materials.Here,we report the intercalation of aluminum ion(Al^(3+))to enhance the PL of MoS_(2)QDs and the un-derlying mechanism.With detailed characterization and exciton dynamics study,we suggest that additional surface states including new emission centers have been effectively introduced to MoS_(2)QDs by the Al^(3+)intercalation.The synergy of new radiative pathway for exciton re-combination and the passivation of non-radiative surface traps is responsible for the en-hanced fluorescence of MoS_(2)QDs.Our findings demonstrate an efficient strategy to improve the optical properties of MoS_(2)QDs and are important for understanding the regulation effect of surface states on the emission of two dimensional sulfide QDs.
文摘<div style="text-align:justify;"> This paper introduces the working principle of the balanced heterodyne detection system, establishes the corresponding mathematical model, deduces the signal to noise ratio (SNR) formula of the balanced heterodyne detection. By comparing balance heterodyne detection with general coherent detection with MATLAB numerical simulation, the superiority of balance heterodyne detection system is proved theoretically. Finally, the simulation models of ordinary heterodyne detection, balance detection and double balance detection system are built by OptiSystem. The simulation results are consistent with the conclusions derived from the mathematical analysis, which provides a new method for the research of weak laser detection technology. </div>
基金Supported by the China Meteorological Administration Special Public Welfare Research Fund(GYHY200806001 and GYHY201406001)National Natural Science Foundation of China(41605111)Research Funds of the Chinese Academy of Meteorological Sciences(2016Z004)
文摘Below-cloud aerosol scavenging process by precipitation is important for cleaning the polluted aerosols in the atmosphere, and is also a main process for acid rain formation. However, the related physical mechanism has not been well documented and clarified yet. In this paper, we investigated the below-cloud PM_(2.5)(particulate matter with aerodynamic diameter being 2.5 μm or less) scavenging by different-intensity rains under polluted conditions characterized by high PM_(2.5) concentrations, based on in-situ measurements from March 2014 to July 2016 in Beijing city. It was found that relatively more intense rainfall events were more efficient in removing the polluted aerosols in the atmosphere. The mean PM_(2.5) scavenging ratio and its standard deviation(SD) were 5.1% ± 25.7%, 38.5% ± 29.0%,and 50.6% ± 21.2% for light, moderate, and heavy rain events, respectively. We further found that the key impact factors on below-cloud PM_(2.5) scavenging ratio for light rain events were rain duration and wind speed rather than raindrop size distribution. However, the impacts of rain duration and wind speed on scavenging ratio were not important for moderate and heavy rain events. To our knowledge, this is the first statistical result about the effects of rain intensity, rain duration, and raindrop size distribution on below-cloud scavenging in China.
文摘The molecular orientations of p-nitrobenzoic acid (PNBA) on the surface of silver nanoparticles and silver mirror have been investigated by using surface enhanced Raman scattering (SERS) and UV-visible absorption spectroscopy. In the mixed system of silver colloid/PNBA/ethanol, the orientation of PNBA on silver nanoparticles remarkably different from that on silver mirror was observed, and it mainly resulted from the cooperation effect of the adsorption to surface active sites on silver under the pressure of aqueous molecules. This result is of some significance for further studying surface-interfacial structures and properties of silver nanoparticles, and the technique used in this note is feasible to get the SERS spectra of some molecules insoluble in aqueous solution.
基金supported by the National Natural Science Foundation of China(Grant Nos.11874438,22105063,61905066,61805070,1200410122103024)+1 种基金Natural Science Foundation of Guangdong(Grant Nos.2021A1515010050,and 2018A030313722)Guangdong Polytechnic Normal University Talent Introduction Project Foundation of China(Grant No.XY2019022)。
文摘Strong coupling between plasmons and multiple different exciton states(MESs)enables the creation of multiple hybrid polariton states under ambient conditions.These hybrid states possess unique optical properties different from those of their separate identities,making them ideal candidates for exploiting room-temperature multimode hybridization and multiqubit operation.In this study,we revealed the static spectral response properties of plasmon-MES strong coupling via a fully quantum mechanics approach.These theoretical predictions were experimentally demonstrated in plasmonic nanocavities containing two and three different exciton species.Additionally,the dynamical absorption processes of such strong coupling systems were investigated,and results indicated that the damping of the hybrid polariton states induced by the strong coupling could be markedly modulated by the acoustic oscillations from the plasmonic nanocavities.Our findings contribute a theoretical approach for accurately describing the plasmon-MES interactions and a platform for developing the high-speed active plasmonic devices based on multiqubit strong coupling.
基金support of the Key Research and Development(R&D)Projects of Shanxi Province(Grant No.201903D121114)supported by Scientific and Technological Innovation Programs of Higher Education Institutions in Shanxi(Grant No.2020L0667).
文摘In this study, a simple and effective method was proposed to improve the electrocatalytic ability of overoxidized poly(3,4-ethylenedioxythiophene)-overoxidized polypyrrole composite films modified on glassy carbon electrode for rutin and luteolin determination. The composite electrode was prepared by cyclic voltammetry copolymerization with LiClO_(4)-water as the supporting electrolyte. The peak current of rutin and luteolin on the composite electrode gradually decreased or even disappeared with the increase in the positive potential limit. After incubation in NaOH–ethanol solution with a volume ratio of 1:1, the composite electrodes prepared at positive potential limit greater than 1.5 V exhibited enhanced differential pulse voltammetry peak currents, reduced charge transfer resistance, larger effective specific surface area and higher electron transfer rate constant. The composite electrode prepared in the potential range of 0–1.7 V showed optimal electrocatalytic performance. The X-ray photoelectron spectroscopy results indicated that the content of –SO_(2)/–SO and –C=N– groups in the composite film increased significantly after incubation. Further, the Raman spectra and Fourier transform infrared spectra revealed that the thiophene ring structure changed from benzene-type to quinone-type, and the quinone-type pyrrole ring was formed. The electrocatalytic mechanism of the composite film was proposed based on the experimental results and further verified by Density Functional Theory calculation.
