Developing advanced battery-type materials with abundant active sites,high conductivity,versatile morphologies,and hierarchically porous structures is crucial for realizing high-quality hybrid supercapacitors.Herein,h...Developing advanced battery-type materials with abundant active sites,high conductivity,versatile morphologies,and hierarchically porous structures is crucial for realizing high-quality hybrid supercapacitors.Herein,heterogeneous FeS@NiS is synthesized by cationic Co doping via surface-structure engineering.The density functional theory(DFT)theoretical calculations are firstly performed to predict the advantages of Co dopant by improving the OH^(−)adsorption properties and adjusting electronic structure,benefiting ions/electron transfer.The dynamic surface evolution is further explored which demonstrates that CoFeS@CoNiS could be quickly reconstructed to Ni(Co)Fe_(2)O_(4)during the charging process,while the unstable structure of the amorphous Ni(Co)Fe_(2)O_(4)results in partial conversion to Ni/Co/FeOOH at high potentials,which contributes to the more reactive active site and good structural stability.Thus,the free-standing electrode reveals excellent electrochemical performance with a superior capacity(335.6 mA h g^(−1),2684 F g^(−1))at 3 A g^(−1).Furthermore,the as-fabricated device shows a quality energy density of 78.1 W h kg^(−1)at a power density of 750 W kg^(−1)and excellent cycle life of 92.1%capacitance retention after 5000 cycles.This work offers a facile strategy to construct versatile morphological structures using electrochemical activation and holds promising applications in energy-related fields.展开更多
Polynary transition-metal layered hydroxides are promising energy materials owing to their unique architecture,impressive theoretical capacities,and adjustable compositions.Regulating the dimensional morphology and ac...Polynary transition-metal layered hydroxides are promising energy materials owing to their unique architecture,impressive theoretical capacities,and adjustable compositions.Regulating the dimensional morphology and active sites/redox states are the keys to electrochemical performance enhancement.Distinguish from the reported mono-metal or binary-metal configurations,a new ternary-metal AlCoNi-LTH is coanchored onto a highly graphitized porous N-doped carbon matrix to develop superior 3D hierarchical microporous functional energy hybrids AlCoNi-LTHs/NAC.The constructed hybrids possess superior structural durability,good electrical conductivity,and rich active sites due to the strong interfacial conjunction and favorable synergistic effect between the doped porous carbon and AlCoNi nanosheets.Consequently,the AlCoNi-LTHs/NAC hybrids demonstrate high conductivity,reasonable specific surface area,and superior specific capacitance,and the assembled hybrid battery-type supercapacitor reveals an ideal energy density of 72.6 Wh kg^(-1)at a power density of 625 W kg^(-1),which is superior to the reported devices.This strategy opens a platform to rationally design polynary transition-metal layered hydroxides and their hybrids for efficient supercapacitors.展开更多
基金financial support from the Chang Jiang Scholars Program (51073047)the National Natural Science Foundation of China (51773049)+5 种基金the China Aerospace Science and Technology Corporation-Harbin Institute of Technology Joint Center for Technology Innovation Fund (HIT15-1A01)the Harbin City Science and Technology Projects (2013DB4BP031 and RC2014QN017035)the Natural Science Foundation of Shandong Province of China (ZR2023QE071)the College Students’ Innovation and Entrepreneurship Training Program Projects of Shandong Province (S202211065048)the Scientific Research Foundation of Qingdao University (DC1900009425)the China Postdoctoral Science Foundation (2022TQ0282)
文摘Developing advanced battery-type materials with abundant active sites,high conductivity,versatile morphologies,and hierarchically porous structures is crucial for realizing high-quality hybrid supercapacitors.Herein,heterogeneous FeS@NiS is synthesized by cationic Co doping via surface-structure engineering.The density functional theory(DFT)theoretical calculations are firstly performed to predict the advantages of Co dopant by improving the OH^(−)adsorption properties and adjusting electronic structure,benefiting ions/electron transfer.The dynamic surface evolution is further explored which demonstrates that CoFeS@CoNiS could be quickly reconstructed to Ni(Co)Fe_(2)O_(4)during the charging process,while the unstable structure of the amorphous Ni(Co)Fe_(2)O_(4)results in partial conversion to Ni/Co/FeOOH at high potentials,which contributes to the more reactive active site and good structural stability.Thus,the free-standing electrode reveals excellent electrochemical performance with a superior capacity(335.6 mA h g^(−1),2684 F g^(−1))at 3 A g^(−1).Furthermore,the as-fabricated device shows a quality energy density of 78.1 W h kg^(−1)at a power density of 750 W kg^(−1)and excellent cycle life of 92.1%capacitance retention after 5000 cycles.This work offers a facile strategy to construct versatile morphological structures using electrochemical activation and holds promising applications in energy-related fields.
基金financial support from the Chang Jiang Scholars Program(51073047)the National Natural Science Foundation of China(51773049)+5 种基金the China Aerospace Science and Technology Corporation-Harbin Institute of Technology Joint Center for Technology Innovation Fund(HIT15-1A01)the Harbin city science and technology projects(2013DB4BP031 and RC2014QN017035)the Fundamental Research Funds for the Central Universities(HIT.OCEF.2021028)the Natural Science Funds of Heilongjiang Province(ZD2019B001)the Heilongjiang Touyan Team(HITTY-20190033)the funds from Chongqing Research Institute of HIT。
文摘Polynary transition-metal layered hydroxides are promising energy materials owing to their unique architecture,impressive theoretical capacities,and adjustable compositions.Regulating the dimensional morphology and active sites/redox states are the keys to electrochemical performance enhancement.Distinguish from the reported mono-metal or binary-metal configurations,a new ternary-metal AlCoNi-LTH is coanchored onto a highly graphitized porous N-doped carbon matrix to develop superior 3D hierarchical microporous functional energy hybrids AlCoNi-LTHs/NAC.The constructed hybrids possess superior structural durability,good electrical conductivity,and rich active sites due to the strong interfacial conjunction and favorable synergistic effect between the doped porous carbon and AlCoNi nanosheets.Consequently,the AlCoNi-LTHs/NAC hybrids demonstrate high conductivity,reasonable specific surface area,and superior specific capacitance,and the assembled hybrid battery-type supercapacitor reveals an ideal energy density of 72.6 Wh kg^(-1)at a power density of 625 W kg^(-1),which is superior to the reported devices.This strategy opens a platform to rationally design polynary transition-metal layered hydroxides and their hybrids for efficient supercapacitors.
