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A stacking-based model for the spread of Botryosphaeria laricina
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作者 hongwei zhou Shibo Zhang +3 位作者 Meng Xie Xiaodong Li Yifan Chen Wenhao Dai 《Journal of Forestry Research》 2025年第1期427-443,共17页
Botryosphaeria laricina(larch shoot blight)was first identified in 1973 in Jilin Province,China.The disease spread rapidly and caused considerable damage because its pathogenesis was unknown at the time and there were... Botryosphaeria laricina(larch shoot blight)was first identified in 1973 in Jilin Province,China.The disease spread rapidly and caused considerable damage because its pathogenesis was unknown at the time and there were no effective controls or quarantine methods.At present,it shows a spreading trend,but most research can only conduct physiological analyses within a relatively short period,combining individual influencing factors.Nevertheless,methods such as neural network models,ensemble learning algorithms,and Markov models are used in pest and disease prediction and forecasting.However,there may be fitting issues or inherent limitations associated with these methods.This study obtained B.laricina data at the county level from 2003 to 2021.The dataset was augmented using the SMOTE algorithm,and then algorithms such as XGBoost were used to select the significant features from a combined set of 12 features.A new stacking fusion model has been proposed to predict the status of B.laricina.The model is based on random forest,gradient boosted decision tree,CatBoost and logistic regression algorithms.The accuracy,recall,specificity,precision,F_(1) value and AUC of the model reached 90.9%,91.6%,90.4%,88.8%,90.2%and 96.2%.The results provide evidence of the strong performance and stability of the model.B.laricina is mainly found in the northeast and this study indicates that it is spreading northwest.Reasonable means should be used promptly to prevent further damage and spread. 展开更多
关键词 Botryosphaeria laricina Data augmentation Feature selection STACKING Status of spread
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Pore-pressure and stress-coupled creep behavior in deep coal:Insights from real-time NMR analysis 被引量:1
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作者 Wenhao Jia hongwei zhou +3 位作者 Senlin Xie Yimeng Wang Xinfeng Hu Lei Zhang 《International Journal of Mining Science and Technology》 SCIE EI CAS CSCD 2024年第1期77-90,共14页
Understanding the variations in microscopic pore-fracture structures(MPFS) during coal creep under pore pressure and stress coupling is crucial for coal mining and effective gas treatment. In this manuscript, a triaxi... Understanding the variations in microscopic pore-fracture structures(MPFS) during coal creep under pore pressure and stress coupling is crucial for coal mining and effective gas treatment. In this manuscript, a triaxial creep test on deep coal at various pore pressures using a test system that combines in-situ mechanical loading with real-time nuclear magnetic resonance(NMR) detection was conducted.Full-scale quantitative characterization, online real-time detection, and visualization of MPFS during coal creep influenced by pore pressure and stress coupling were performed using NMR and NMR imaging(NMRI) techniques. The results revealed that seepage pores and microfractures(SPM) undergo the most significant changes during coal creep, with creep failure gradually expanding from dense primary pore fractures. Pore pressure presence promotes MPFS development primarily by inhibiting SPM compression and encouraging adsorption pores(AP) to evolve into SPM. Coal enters the accelerated creep stage earlier at lower stress levels, resulting in more pronounced creep deformation. The connection between the micro and macro values was established, demonstrating that increased porosity at different pore pressures leads to a negative exponential decay of the viscosity coefficient. The Newton dashpot in the ideal viscoplastic body and the Burgers model was improved using NMR experimental results, and a creep model that considers pore pressure and stress coupling using variable-order fractional operators was developed. The model’s reasonableness was confirmed using creep experimental data. The damagestate adjustment factors ω and β were identified through a parameter sensitivity analysis to characterize the effect of pore pressure and stress coupling on the creep damage characteristics(size and degree of difficulty) of coal. 展开更多
关键词 Real-time monitoring Pore pressure-stress coupling Microscopic pore-fracture structure Variable-order fractional creep model Deep coal
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Analysis of the spatiotemporal trends and influencing factors of Hyphantria cunea in China
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作者 hongwei zhou Chaoqun Gong +2 位作者 Xiaodong Li Yue Wang Yunbo Yan 《Journal of Forestry Research》 SCIE EI CAS CSCD 2024年第6期294-305,共12页
In recent years,the situation of the Hyphantria cunea(Drury)(Lepidoptera:Erebidae),infestation in China has been serious and has a tendency to continue to spread.A comprehensive analysis was carried out to examine the... In recent years,the situation of the Hyphantria cunea(Drury)(Lepidoptera:Erebidae),infestation in China has been serious and has a tendency to continue to spread.A comprehensive analysis was carried out to examine the spa-tial distribution trends and influencing factors of H.cunea.This analysis involved integrating administrative division and boundary data,distribution data of H.cunea,and envi-ronmental variables for 2021.GeoDetector and gravity analysis techniques were employed for data processing and interpretation.The results show that H.cunea exhibited high aggregation patterns in 2021 and 2022 concentrated mainly in eastern China.During these years,the focal point of the infestation was in Shandong Province with a spread towards the northeast.Conditions such as high vegetation density in eastern China provided favorable situations for growth and development of H.cunea.In China,the spatial distribution of the moth is primarily influenced by two critical factors:precipitation during the driest month and elevation.These play a pivotal role in determining the spread of the species.Based on these results,suggestions are provided for a mul-tifaceted approach to prevention and control of H.cunea infestation. 展开更多
关键词 Hyphantria cunea Temporal trends GeoDetector spatial analysis Spatial heterogeneity
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界面聚合法制备异氰酸酯型微胶囊及其性能 被引量:13
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作者 梁丰收 陈卫星 +2 位作者 马爱洁 周宏伟 金洗郎 《高分子材料科学与工程》 EI CAS CSCD 北大核心 2018年第2期150-154,共5页
针对异氰酸酯型自修复微胶囊包封率较低、制备过程难以控制等问题,提出以聚氨酯预聚物为壁材原料,采用界面聚合法制备出微胶囊。以聚氨酯预聚物(拜尔L-75)与1,4-丁二醇(BDO)反应产物为壁材,异佛尔酮二异氰酸酯(IPDI)为芯材,油相中L-75... 针对异氰酸酯型自修复微胶囊包封率较低、制备过程难以控制等问题,提出以聚氨酯预聚物为壁材原料,采用界面聚合法制备出微胶囊。以聚氨酯预聚物(拜尔L-75)与1,4-丁二醇(BDO)反应产物为壁材,异佛尔酮二异氰酸酯(IPDI)为芯材,油相中L-75的异氰酸酯(-NCO)官能团与水相中扩链剂BDO的羟基(-OH)在界面处发生逐步聚合反应,生成聚氨酯膜,IPDI被聚氨酯膜成功包封形成微胶囊。讨论了BDO加入量,乳化剂阿拉伯胶(GA)用量对微胶囊结构、形貌及性能的影响。采用傅里叶变换红外光谱表征了微胶囊的化学结构;采用光学显微镜研究了微胶囊形貌、大小分布;热重分析仪分析了微胶囊囊芯含量。结果表明,在50℃下,扩链剂BDO质量分数为11.7%,GA质量分数为17.4%,IPDI质量分数为67%,搅拌速度为600 r/min,所制备的异氰酸酯微胶囊囊心质量分数为55.69%,包封率达到83%。 展开更多
关键词 微胶囊 异氰酸酯 制备 界面聚合
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聚己内酯对左旋聚乳酸结晶行为的影响 被引量:2
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作者 肖薇 陈卫星 +5 位作者 罗春燕 杨敏蕊 唐凤 杨晶晶 周宏伟 强涛 《高分子材料科学与工程》 EI CAS CSCD 北大核心 2019年第6期45-53,共9页
采用端羟基聚己内酯(PCL)并控制丙交酯(L-LA)的质量合成不同嵌段长度的PLLA-PCL-PLLA三嵌段共聚物;使用相对分子质量相近的左旋聚乳酸(PLLA)与PCL均聚物共混得到PLLA/PCL共混物。红外光谱测试和核磁共振氢谱测试确定了共聚物结构。差示... 采用端羟基聚己内酯(PCL)并控制丙交酯(L-LA)的质量合成不同嵌段长度的PLLA-PCL-PLLA三嵌段共聚物;使用相对分子质量相近的左旋聚乳酸(PLLA)与PCL均聚物共混得到PLLA/PCL共混物。红外光谱测试和核磁共振氢谱测试确定了共聚物结构。差示扫描量热(DSC)测试结果表明,PCL的引入有效提高了PLLA嵌段共聚物和PLLA均聚物的结晶速率。利用DSC考察总结晶速率,热台偏光显微镜考察生长速率,结果表明当共聚物中PLLA嵌段相对分子质量与共混物中PLLA均聚物相对分子质量相当时,PLLA嵌段与PLLA均聚物结晶速率相当。PCL的加入使得PLLA最大结晶速率所对应的温度降低,其加入方式对PLLA的结晶形貌有一定的影响,无论以共聚或共混的方式引入PCL均对PLLA结晶速率的提高有积极作用。 展开更多
关键词 聚己内酯 聚乳酸 嵌段共聚物 共混物 结晶行为
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Study on the relation between damage and permeability of sandstone at depth under cyclic loading 被引量:7
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作者 Yang Zhao hongwei zhou +1 位作者 Jiangcheng Zhong Di Liu 《International Journal of Coal Science & Technology》 EI 2019年第4期479-492,共14页
The damage and permeability evolution of rock under stress is of great significance to engineering safety.In this paper,the evolution law of rock damage and permeability is studied by means of acoustic emission (AE) s... The damage and permeability evolution of rock under stress is of great significance to engineering safety.In this paper,the evolution law of rock damage and permeability is studied by means of acoustic emission (AE) seepage experiment on deep roof sandstone with cyclic loading.Characterization of damage uses the changes in acoustic emission fractal characteristics and compression parameter which based on elastic modulus.The experimental results show that the AE events has fractal characteristic,in which the AE b-value and correlation dimension can represent the damage of rock.When the fractal characteristic value of AE increases,it indicates that the rock is in the compaction stage and the damage is not obvious.When the fractal characteristic value of AE drops,it indicates that the rock was damaged,and the permeabilityincrease.Under the cyclic load increasing step by step,the elastic modulus first increases and then decrease.Introducing compression parameter C to characterize the state of compaction and damage,it is obtained that the rock damage state and hydrostatic permeability show a power law function relationship with porosity and have the same monotonicity.When compression parameter is less than zero,the evolution law of permeability and damage can be described by functional relationship between hydrostatic permeability K and compression parameter C. 展开更多
关键词 Deep ROOF SANDSTONE CYCLIC loading Acoustic emission PERMEABILITY
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In-situ observation and modeling approach to evolution of pore-fracture structure in coal 被引量:4
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作者 hongwei zhou Zelin Liu +3 位作者 Jiawei Zhao Bocen Chen Xiangnan Li Jiangcheng Zhong 《International Journal of Mining Science and Technology》 SCIE EI CAS CSCD 2023年第3期265-274,共10页
The characterisation of the pore-fracture structure(PFS)and its evolution in coal during mining are essential for preventing gas outbursts and improving gas extraction efficiency.In this study,the evolution of the PFS... The characterisation of the pore-fracture structure(PFS)and its evolution in coal during mining are essential for preventing gas outbursts and improving gas extraction efficiency.In this study,the evolution of the PFS in coal samples under the condition of mining stress was directly captured in situ by combination of the mechanical testing system with high-precision visualisation nuclear magnetic resonance equipment.A fractional derivative model was established to describe the relationship between stress and porosity based on experimental results of the PFS under different stress states.The results showed that with an increase in the deviatoric stress,the adsorption pore content increases rapidly initially and then increases slowly or remains unchanged;the seepage pore and fracture(SPF)content decreases initially and then increases.The SPF compressibility coefficient decreases with an increase in the deviatoric stress.The fractional derivative model can accurately describe the stress sensitivity of the SPFs at the pre-peak stage,thus providing a new approach for accurately characterising the seepage characteristics of coal reservoirs. 展开更多
关键词 Pore-fracture structure Fractional derivative Stress sensitivity COMPRESSIBILITY Nuclear magnetic resonance imaging
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Surveillance of pine wilt disease by high resolution satellite 被引量:3
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作者 hongwei zhou Xinpei Yuan +5 位作者 Huanyu zhou Hengyu Shen Lin Ma Liping Sun Guofei Fang Hong Sun 《Journal of Forestry Research》 SCIE CAS CSCD 2022年第4期1401-1408,共8页
Pine wilt disease caused by the pinewood nematode Bursaphelenchus xylophilus has led to the death of a large number of pine trees in China.This destructive disease has the characteristics of bring wide-spread,fast ons... Pine wilt disease caused by the pinewood nematode Bursaphelenchus xylophilus has led to the death of a large number of pine trees in China.This destructive disease has the characteristics of bring wide-spread,fast onset,and long incubation time.Most importantly,in China,the fatality rate in pines is as high as 100%.The key to reducing this mortality is how to quickly find the infected trees.We proposed a method of automatically identifying infected trees by a convolution neural network and bounding box tool.This method rapidly locates the infected area by classifying and recognizing remote sensing images obtained by high resolution earth observation Satellite.The recognition accuracy of the test data set was 99.4%,and the remote sensing image combined with convolution neural network algorithm can identify and determine the distribution of the infected trees.It can provide strong technical support for the prevention and control of pine wilt disease. 展开更多
关键词 Pine wilt disease Satellite remote sensing image Pest identification Convolution neural network
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Reduction of electric field strength by two species of trees under power transmission lines 被引量:2
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作者 hongwei zhou Liping Sun +4 位作者 Yang Yang Che Liu Tianshi Liu Penghao Xie Ling Ma 《Journal of Forestry Research》 SCIE CAS CSCD 2018年第5期1415-1422,共8页
Electrical pollution is a worldwide concern,because it is potentially harmful to human health.Trees not only play a significant role in moderating the climate,but also can be used as shields against electrical polluti... Electrical pollution is a worldwide concern,because it is potentially harmful to human health.Trees not only play a significant role in moderating the climate,but also can be used as shields against electrical pollution.Shielding effects on the electric field strength under transmission lines by two tree species,Populus alba and Larix gmelinii,were examined in this study.The electrical resistivity at different heights of trees was measured using a PiCUS sonic tomograph,which can image the electrical impedance for trees.The electric field strength around the trees was measured with an elf field strength measurement system,HI-3604,and combined with tree resistivity to develop a model for calculating the electric field intensity around trees using the finite element method.In addition,the feasibility of the finite element method was confirmed by comparing the calculated results and experimental data.The results showed that the trees did reduce the electric field strength.The electric field intensity was reduced by 95.6%,and P.alba was better than L.gmelinii at shielding. 展开更多
关键词 Trees Power transmission lines Electric environment Tree electrical resistivity SHIELDING Finite element method
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Research progress and application of deep in-situ condition preserved coring and testing 被引量:2
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作者 Heping Xie Yunqi Hu +14 位作者 Mingzhong Gao Ling Chen Ru Zhang Tao Liu Feng Gao hongwei zhou Xiaobo Peng Xiongjun Li Jianbo Zhu Cunbao Li Ruidong Peng Yanan Gao Cong Li Jianan Li Zhiqiang He 《International Journal of Mining Science and Technology》 SCIE EI CAS CSCD 2023年第11期1319-1337,共19页
With the depletion of shallow resources,the exploration of deep earth resources has become a global strategy.The study of the different patterns in the physical mechanical properties of rocks at different occurrence d... With the depletion of shallow resources,the exploration of deep earth resources has become a global strategy.The study of the different patterns in the physical mechanical properties of rocks at different occurrence depths is the basis for exploring deep into the earth,with the core and premise being the acquisition and testing of deep in-situ core specimens.Based on the original idea of deep in-situ condition preserved coring(ICP-Coring)and testing,combined with theoretical modeling,numerical analysis,test platform development,indoor testing and engineering application,the principles and technologies of deep ICP-Coring are developed.This principle and technology consists of five parts:in-situ pressurepreserved coring(IPP-Coring),in-situ substance-preserved coring(ISP-Coring),in-situ temperaturepreserved coring(ITP-Coring),in-situ light-preserved coring(ILP-Coring),and in-situ moisturepreserved coring(IMP-Coring).The theory and technology of temperature and pressure reconstruction at different occurrence depths and in different environments are proposed,and prototype trial production was completed by following the principle of displacement and tests based on the in-situ reconstructed environment.The notable advances are as follows:(1)Deep in-situ coring system:A pressure-preserved controller with an ultimate bearing capacity greater than 140 MPa,highperformance(temperature-resistant,pressure-resistant,and low thermally conductive)temperaturepreserved materials,an active temperature control system,and high-barrier quality-preserved membrane materials were developed;a deep ICP-Coring capacity calibration platform was independently developed,a deep in-situ coring technology system was developed,and the acquisition of deep in-situ cores was realized.(2)In-situ storage displacement system:Following the dual-circuit hydraulic design idea,a single-drive source push-pull composite grabbing mechanism was designed;the design of the overall structure for the deep in-situ displacement storage system and ultrahigh pressure cabin structure was completed,which could realize docking the coring device and core displacement in the in-situ reconstructed environment.(3)Test analysis system:A noncontact acoustic-electric-magnetic test system was developed under the in-situ reconstructed environment,and the errors between the test results and traditional contact test results were mostly less than 10%;a detachable deep in-situ core true triaxial test system was developed,which could perform loading tests for deep in-situ cores.The relevant technological achievements were successfully applied to the exploration and development of deep resources,such as deep mines,deep-sea natural gas hydrates,and deep oil and gas.The research results provide technical and equipment support for the construction of a theoretical system for deep in-situ rock mechanics,the development of deep earth resources and energy,and the scientific exploration of different layers and occurrence depths(deep and ultradeep)of the Earth. 展开更多
关键词 Deep mining Deep in-situ CORING DISPLACEMENT Test
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Numerical analysis on mechanical difference of sandstone under in-situ stress,pore pressure preserved environment at depth 被引量:1
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作者 hongwei zhou Mingyuan Lu +5 位作者 Heping Xie Wenhao Jia Ruidong Peng Yimeng Wang Bocen Chen Pengfei Jing 《International Journal of Mining Science and Technology》 SCIE EI CAS CSCD 2023年第11期1339-1350,共12页
Deep in-situ rock mechanics considers the influence of the in-situ environment on mechanical properties,differentiating it from traditional rock mechanics.To investigate the effect of in-situ stress,pore pressure pres... Deep in-situ rock mechanics considers the influence of the in-situ environment on mechanical properties,differentiating it from traditional rock mechanics.To investigate the effect of in-situ stress,pore pressure preserved environment on the mechanical difference of sandstone,four tests are numerically modeled by COMSOL:conventional triaxial test,conventional pore pressure test,in-situ stress restoration and reconstruction test,and in-situ pore pressure-preserved test(not yet realized in the laboratory).The in-situ stress restoration parameter is introduced to characterize the recovery effect of in-situ stress on elastic modulus and heterogeneous distribution of sandstone at different depths.A random function and nonuniform pore pressure coefficient are employed to describe the non-uniform distribution of pore pressure in the in-situ environment.Numerical results are compared with existing experimental data to validate the models and calibrate the numerical parameters.By extracting mechanical parameters from numerical cores,the stress-strain curves of the four tests under different depths,in-situ stress and pore pressure are compared.The influence of non-uniform pore pressure coefficient and depth on the peak strength of sandstone is analyzed.The results show a strong linear relationship between the in-situ stress restoration parameter and depth,effectively characterizing the enhanced effect of stress restoration and reconstruction methods on the elastic modulus of conventional cores at different depths.The in-situ pore pressurepreserved test exhibits lower peak stress and peak strain compared to the other three tests,and sandstone subjected to non-uniform pore pressure is more prone to plastic damage and failure.Moreover,the influence of non-uniform pore pressure on peak strength gradually diminished with increasing depth. 展开更多
关键词 In-situ pore pressure-preserved ENVIRONMENT Numerical simulation approach Deep in-situ rock mechanics In-situ stress restoration and reconstruction
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A Method for Calculating the Heats of Formation of Medium-Sized and Large-Sized Molecules
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作者 Bing He hongwei zhou +1 位作者 Fan Yang Wai-Kee Li 《Open Journal of Physical Chemistry》 2015年第3期71-86,共16页
A calculation method for heats of formation (HOF, referred to as △Hf) based on the density functional theory (DFT) is presented in this work. Similar to Gaussian-3 theory, the atomic scheme is applied to calculate th... A calculation method for heats of formation (HOF, referred to as △Hf) based on the density functional theory (DFT) is presented in this work. Similar to Gaussian-3 theory, the atomic scheme is applied to calculate the heats of formation of the molecules. In this method, we have modified the formula for calculation of Gaussian-3 theory in several ways, including the correction for diffuse functions and the correction for higher polarization functions. These corrections are found to be significant. The average absolute deviation from experiment for the 164 calculated heats of formation is about 1.9 kcal·mol?1, while average absolute deviation from G3MP2 for the 149 (among the 164 molecules, 15 large-sized molecules can not be calculated at the G3MP2 level) calculated heats of formation is only about 1.9 kcal·mol?1. It indicates that the present method can be applied to predict the heats of formation of medium-sized and large-sized molecules, while the heats of formation of these molecules using Gaussian-3 theory are much difficult, even impossible, to calculate. That is, this method provides a choice in the calculation of △Hf for medium-sized and large-sized molecules. 展开更多
关键词 HEATS of FORMATION Gaussian-3 THEORY Energy ABSOLUTE Deviation
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Design of 1.5 bit quantization correlator in satellite navigation software receiver
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作者 hongwei zhou Tian Jin Fangyao Lü 《Journal of Systems Engineering and Electronics》 SCIE EI CSCD 2016年第2期449-456,共8页
Currently, 1 bit or 2 bit signal quantization is widely used in satellite navigation software receivers. The bit-wise parallel algorithm has been proposed for 1 bit and 2 bit signal quantization, which performs correl... Currently, 1 bit or 2 bit signal quantization is widely used in satellite navigation software receivers. The bit-wise parallel algorithm has been proposed for 1 bit and 2 bit signal quantization, which performs correlation with high efficiency. In order to improve the performance of the correlator, this paper proposes a new 1.5 bit quantization method. Theoretical analyses are made from the aspects of complexity and quantization loss, and performance comparison between 1.5 bit quantization correlator and traditional correlators is discussed. The results show that the 1.5 bit quantization algorithm can save about 30 percent complexity under similar quantization loss, reduce more than 0.5 dB signal noise ratio(SNR) loss under similar complexity. It shows great performance improvement for correlators of satellite navigation software receivers. 展开更多
关键词 correlator bit-wise 1.5 bit quantization satellite navigation
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高强度珠光体钢丝拉拔过程中渗碳体的演变
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作者 吴燕 焦建宇 +4 位作者 白凤梅 周红伟 赵刚 薛军 郑光文 《过程工程学报》 北大核心 2025年第1期80-88,共9页
冷拔珠光体钢丝因具有高强度和一定的韧性而获得广泛应用。冷拔过程中,渗碳体片层演变对钢丝强韧性有重要的影响。本工作选用直径为7.81 mm的高碳钢盘条,通过多道次冷拉拔至最大真应变2.18,获得系列高强度珠光体钢丝。通过透射电子显微... 冷拔珠光体钢丝因具有高强度和一定的韧性而获得广泛应用。冷拔过程中,渗碳体片层演变对钢丝强韧性有重要的影响。本工作选用直径为7.81 mm的高碳钢盘条,通过多道次冷拉拔至最大真应变2.18,获得系列高强度珠光体钢丝。通过透射电子显微镜(TEM)和扫描电子显微镜(SEM)观察盘条拉拔过程中渗碳体片层的演变规律及其微观机制。结果表明,在钢丝拉拔过程中,珠光体纤维化程度不断增强,由铁素体和渗碳体构成的珠光体片层逐渐向拉拔方向调整,在真应变为2.18下全部平行于拉拔方向。拉拔过程中渗碳体片层发生了复杂的变化,形貌上表现为片层细化、弯曲和断裂,微观结构上出现了多晶化、非晶化和纳米晶化等现象。珠光体片层取向与拉拔方向近平行时,片层间距逐步减小,片层排列方向逐渐转到拉拔方向,渗碳体片层发生了非晶化和纳米晶化等现象。珠光体片层与拉拔方向近垂直时,渗碳体片层发生了弯曲、断裂和多晶化。拉拔过程中,位错与渗碳体强烈交互作用,渗碳体内晶格畸变增大,是渗碳体片层发生复杂变化的主要原因。 展开更多
关键词 珠光体钢丝 拉拔 渗碳体 位错滑移 微观结构
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非石油原料合成己二腈研究进展
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作者 陈颖 周宏伟 俞磊 《科学通报》 EI CAS CSCD 北大核心 2024年第3期370-380,共11页
己二腈是一种重要的有机化工中间体.己二腈加氢后可制备己二胺,主要用于生产尼龙-66,故而市场应用前景巨大.传统的己二腈合成方法需要使用大量的石油原料,具有很多的发展制约.因此,近年来,以非石油原料合成制备己二腈的研究备受关注.本... 己二腈是一种重要的有机化工中间体.己二腈加氢后可制备己二胺,主要用于生产尼龙-66,故而市场应用前景巨大.传统的己二腈合成方法需要使用大量的石油原料,具有很多的发展制约.因此,近年来,以非石油原料合成制备己二腈的研究备受关注.本文对目前已发表的关于非石油原料合成己二腈的研究成果进行了总结,包括基于生物质、煤基和其他可再生资源的合成方法以及使用酶催化、电催化、化学催化等不同的合成策略.本文还结合现有的路线汇总了当前有望被开发的反应路径,并探讨了未来可能的研究方向和应用前景.需要强调的是,开发具有自主知识产权的己二腈合成工艺对于我国尼龙-66产业的发展至关重要,如何有效地开发新型己二腈合成技术将是未来面临的重大挑战.本文对非石油原料合成己二腈的研究进行了展望,为相关产业的路线设计和开发提供参考. 展开更多
关键词 己二腈 尼龙-66 生物质 可再生资源
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High-fat diet impairs gut barrier through intestinal microbiota-derived reactive oxygen species 被引量:2
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作者 Nianyi Zeng Fan Wu +18 位作者 Junqi Lu Xiang Li Shaomei Lin Lang zhou Zhongwei Wang Guangyan Wu Qingfa Huang Daowen Zheng Jie Gao Shan Wu Xiaojiao Chen Muxuan Chen Fanguo Meng Haitao Shang Yan He Peng Chen Hong Wei Zhuang Li hongwei zhou 《Science China(Life Sciences)》 SCIE CAS CSCD 2024年第5期879-891,共13页
Gut barrier disruption is a key event in bridging gut microbiota dysbiosis and high-fat diet(HFD)-associated metabolic disorders.However,the underlying mechanism remains elusive.In the present study,by comparing HFD-a... Gut barrier disruption is a key event in bridging gut microbiota dysbiosis and high-fat diet(HFD)-associated metabolic disorders.However,the underlying mechanism remains elusive.In the present study,by comparing HFD-and normal diet(ND)-treated mice,we found that the HFD instantly altered the composition of the gut microbiota and subsequently damaged the integrity of the gut barrier.Metagenomic sequencing revealed that the HFD upregulates gut microbial functions related to redox reactions,as confirmed by the increased reactive oxygen species(ROS)levels in fecal microbiota incubation in vitro and in the lumen,which were detected using in vivo fluorescence imaging.This microbial ROS-producing capability induced by HFD can be transferred through fecal microbiota transplantation(FMT)into germ-free(GF)mice,downregulating the gut barrier tight junctions.Similarly,mono-colonizing GF mice with an Enterococcus strain excelled in ROS production,damaged the gut barrier,induced mitochondrial malfunction and apoptosis of the intestinal epithelial cells,and exacerbated fatty liver,compared with other low-ROS-producing Enterococcus strains.Oral administration of recombinant high-stability-superoxide dismutase(SOD)significantly reduced intestinal ROS,protected the gut barrier,and improved fatty liver against the HFD.In conclusion,our study suggests that extracellular ROS derived from gut microbiota play a pivotal role in HFD-induced gut barrier disruption and is a potential therapeutic target for HFD-associated metabolic diseases. 展开更多
关键词 fatty liver disease gut microbiota gut barrier high-fat diet oxidative stress reactive oxygen species
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Novel strategy of multidimensional information encryption via multi-color carbon dots aggregation-induced emission 被引量:1
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作者 Liu Ding Xilang Jin +6 位作者 Yuchong Gao Shouwang Kang Haiyan Bai Xuehao Ma Taotao Ai hongwei zhou Weixing Chen 《Nano Research》 SCIE EI CSCD 2024年第6期5680-5687,共8页
Carbon dots(CDs)with aggregation-induced emission(AIE)have sparked significant interest in multidimensional anti-counterfeiting due to their exceptional fluorescence properties.However,the preparation of AIE CDs with ... Carbon dots(CDs)with aggregation-induced emission(AIE)have sparked significant interest in multidimensional anti-counterfeiting due to their exceptional fluorescence properties.However,the preparation of AIE CDs with multicolor solid-state fluorescence remains a formidable challenge due to its complicated construction.In the present work,a novel class of multicolor AIE CDs(M-CDs)were fabricated using selected precursor(salicylic acid,thiosalicylic acid,and 2,2'-dithiodibenzoic acid),with an eco-friendly,low-cost one-pot solvothermal method.In the dilute organic solution,M-CDs manifested blue emission,but upon aggregation in the presence of water,the red,yellow,green,and blue emissions were displayed due to the AIE effect.Structural analysis,coupled with theoretical calculations,revealed that the increase in the size of sp2 domains would lower the Eg and cause a red-shift emission wavelength.Significantly,the continuous emission of M-CDs from blue to red can be utilized as ink for multimode printing,enabling the creation of a variety of school badges and quick response codes.These findings hold promising implications for multi-information encryption applications. 展开更多
关键词 aggregation-induced emission(AIE) luminescence mechanism multi-color emission information encryption.
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Gut commensal metabolite rhamnose promotes macrophages phagocytosis by activating SLC12A4 and protects against sepsis in mice
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作者 Dongping Li Rongjuan Wei +15 位作者 Xianglong Zhang Shenhai Gong Meijuan Wan Fangzhao Wang Jiaxin Li Meiling Chen Ruofan Liu Yantong Wan Yinghao Hong Zhenhua Zeng Peng Gu Zhang Wang Kutty Selva Nandakumar Yong Jiang hongwei zhou Peng Chen 《Acta Pharmaceutica Sinica B》 SCIE CAS CSCD 2024年第7期3068-3085,共18页
Sepsis progression is significantly associated with the disruption of gut eubiosis.However,the modulatory mechanisms of gut microbiota operating during sepsis are still unclear.Herein,we investigated how gut commensal... Sepsis progression is significantly associated with the disruption of gut eubiosis.However,the modulatory mechanisms of gut microbiota operating during sepsis are still unclear.Herein,we investigated how gut commensals impact sepsis development in a pre-clinical model.Cecal ligation and puncture(CLP)surgery was used to establish polymicrobial sepsis in mice.Mice depleted of gut microbiota by an antibiotic cocktail(ABX)exhibited a significantly higher level of mortality than controls.As determined by metabolomics analysis,ABX treatment has depleted many metabolites,and subsequent supplementation with L-rhamnose(rhamnose,Rha),a bacterial carbohydrate metabolite,exerted profound immunomodulatory properties with a significant enhancement in macrophage phagocytosis,which in turn improved organ damage and mortality.Mechanistically,rhamnose binds directly to and activates the solute carrier family 12(potassium-chloride symporter),member 4(SLC12A4)in macrophages and promotes phagocytosis by activating the small G-proteins,Ras-related C3 botulinum toxin substrate1(Rac1)and cell division control protein 42 homolog(Cdc42).Interestingly,rhamnose has enhanced the phagocytosis capacity of macrophages from sepsis patients.In conclusion,by identifying SLC12A4 as the host interacting protein,we disclosed that the gut commensal metabolite rhamnose is a functional molecular that could promote the phagocytosis capacity of macrophages and protect the host against sepsis. 展开更多
关键词 Gut microbiota SEPSIS RHAMNOSE SLC12A4 GTP-Rac1 GTP-Cdc42 Macrophage PHAGOCYTOSIS
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Wrinkled and Fibrous Conductive Bandages with Tunable Mechanoelectrical Response Toward Wearable Strain Sensors
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作者 Xin Xu Yang Liu +10 位作者 hongwei zhou Zhong Li Ruhai Wang Birui Jin Hao Liu Qianqian Fan Yunsheng Fang Na Liu Dong Wang Feng Xu Guoxu Zhao 《Advanced Fiber Materials》 SCIE EI CAS 2024年第4期1174-1187,共14页
Wearable strain sensors(WSSs)have found widespread applications,where the key is to optimize their sensing and wearing performances.However,the intricate material designs for developing WSSs often rely on costly reage... Wearable strain sensors(WSSs)have found widespread applications,where the key is to optimize their sensing and wearing performances.However,the intricate material designs for developing WSSs often rely on costly reagents and/or complex pro-cesses,which bring barriers to their large-scale production and use.Herein,a facile and affordable(material cost of<$0.002/cm2)method is presented for fabricating conductive bandage(CB)-based WSSs by electrospraying a carbon nanotube(CNT)layer on commercial self-adhesive bandages with excellent biosafety,stretchability,mechanical compliance,breathability and cost effectiveness.The wrinkled and fibrous structures of self-adhesive bandages were rationally leverage to control the geometry of CNT layer,thereby ensuring tunable mechanoelectrical sensitivities(gauge factors of 2~850)of CBs.Moreover,a strain-sensing mechanism directly mediated by the highly wrinkled microstructure is unveiled,which can work in synergy with a training-loosened-fibrous microstructure.The excellent performance of CBs for monitoring full-range strain signals in human bodies was further demonstrated.CBs would possess great potential for being developed into WSSs because of their outstanding cost-performance ratio. 展开更多
关键词 Flexible electronics Carbon nanotubes Nonwoven fabrics WRINKLES Strain sensors
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Tunable single emitter-cavity coupling strength through waveguide-assisted energy quantum transfer
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作者 Yuan Liu hongwei zhou +1 位作者 Linhan Lin Hong-Bo Sun 《Light(Science & Applications)》 SCIE EI CSCD 2024年第9期1779-1788,共10页
The emitter-cavity strong coupling manifests crucial significance for exploiting quantum technology,especially in the scale of individual emitters.However,due to the small light-matter interaction cross-section,the si... The emitter-cavity strong coupling manifests crucial significance for exploiting quantum technology,especially in the scale of individual emitters.However,due to the small light-matter interaction cross-section,the single emitter-cavity strong coupling has been limited by its harsh requirement on the quality factor of the cavity and the local density of optical states.Herein,we present a strategy termed waveguide-assisted energy quantum transfer(WEQT)to improve the single emitter-cavity coupling strength by extending the interaction cross-section.Multiple ancillary emitters are optically linked by a waveguide,providing an indirect coupling channel to transfer the energy quantum between target emitter and cavity.An enhancement factor of coupling strength eg=g>10 can be easily achieved,which dramatically release the rigorous design of cavity.As an extension of concept,we further show that the ancillae can be used as controlling bits for a photon gate,opening up new degrees of freedom in quantum manipulation. 展开更多
关键词 QUANTUM coupling TRANSFER
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