As the cost of grouting treatment for water control in coal roofs during underground coal mining continues to rise,coupled with the accumulation of industrial solid waste resulting from rapid economic development in C...As the cost of grouting treatment for water control in coal roofs during underground coal mining continues to rise,coupled with the accumulation of industrial solid waste resulting from rapid economic development in China,the ecological environment is facing severe challenges.To address these issues,this study,based on a high water-to-cement ratio,uses mine overburden(OB)and furnace bottom ash(FBA)as the primary raw materials,with sodium silicate as the modifier,to develop a new type of geopolymer grouting material with high stability and compressive strength for coal roof water control.Additionally,COMSOL software was used to numerically simulate the diffusion process of the grout slurry in fractures under dynamic water flow.The results indicate that,with a sodium silicate modulus of 1.5 and a dosage of 4%,the stability of the slurry increased by 26.2%,and the 28-day compressive strength improved by 130.98%.Numerical simulations further show that the diffusion process of the slurry is closely related to slurry viscosity,grouting pressure,and grouting time and that the diffusion pattern in the fractures is similar to that of ultra-fine cement slurry.This study provides a theoretical basis for coal mine roof grouting water control projects.展开更多
As the miniaturization of electronic devices and complication of electronic packaging,there are growing demands for thermal interfacial materials with enhanced thermal conductivity and the capability to direct the hea...As the miniaturization of electronic devices and complication of electronic packaging,there are growing demands for thermal interfacial materials with enhanced thermal conductivity and the capability to direct the heat toward heat sink for highly efficient heat dissipation.Pitch-based carbon fiber(CF)with ultrahigh axial thermal conductivity and aspect ratios exhibits great potential for developing thermally conductive composites as TIMs.However,it is still hard to fabricate composites with aligned carbon fiber in a general approach to fully utilize its excellent axial thermal conductivity in specific direction.Here,three types of CF scaffolds with different oriented structure were developed via magnetic field-assisted Tetris-style stacking and carbonization process.By regulating the magnetic field direction and initial stacking density,the self-supporting CF scaffolds with horizontally aligned(HCS),diagonally aligned and vertically aligned(VCS)fibers were constructed.After embedding the polydimethylsiloxane(PDMS),the three composites exhibited unique heat transfer properties,and the HCS/PDMS and VCS/PDMS composites presented a high thermal conductivity of 42.18 and 45.01 W m^(−1)K^(−1)in fiber alignment direction,respectively,which were about 209 and 224 times higher than that of PDMS.The excellent thermal conductivity is mainly ascribed that the oriented CF scaffolds construct effective phonon transport pathway in the matrix.In addition,fishbone-shaped CF scaffold was also produced by multiple stacking and carbonization process,and the prepared composites exhibited a controlled heat transfer path,which can allow more versatility in the design of thermal management system.展开更多
文摘As the cost of grouting treatment for water control in coal roofs during underground coal mining continues to rise,coupled with the accumulation of industrial solid waste resulting from rapid economic development in China,the ecological environment is facing severe challenges.To address these issues,this study,based on a high water-to-cement ratio,uses mine overburden(OB)and furnace bottom ash(FBA)as the primary raw materials,with sodium silicate as the modifier,to develop a new type of geopolymer grouting material with high stability and compressive strength for coal roof water control.Additionally,COMSOL software was used to numerically simulate the diffusion process of the grout slurry in fractures under dynamic water flow.The results indicate that,with a sodium silicate modulus of 1.5 and a dosage of 4%,the stability of the slurry increased by 26.2%,and the 28-day compressive strength improved by 130.98%.Numerical simulations further show that the diffusion process of the slurry is closely related to slurry viscosity,grouting pressure,and grouting time and that the diffusion pattern in the fractures is similar to that of ultra-fine cement slurry.This study provides a theoretical basis for coal mine roof grouting water control projects.
基金The authors are grateful for the financial support by Sichuan Science and Technology Program(2022YFH0090)the Fundamental Research Funds for the Central Universities.
文摘As the miniaturization of electronic devices and complication of electronic packaging,there are growing demands for thermal interfacial materials with enhanced thermal conductivity and the capability to direct the heat toward heat sink for highly efficient heat dissipation.Pitch-based carbon fiber(CF)with ultrahigh axial thermal conductivity and aspect ratios exhibits great potential for developing thermally conductive composites as TIMs.However,it is still hard to fabricate composites with aligned carbon fiber in a general approach to fully utilize its excellent axial thermal conductivity in specific direction.Here,three types of CF scaffolds with different oriented structure were developed via magnetic field-assisted Tetris-style stacking and carbonization process.By regulating the magnetic field direction and initial stacking density,the self-supporting CF scaffolds with horizontally aligned(HCS),diagonally aligned and vertically aligned(VCS)fibers were constructed.After embedding the polydimethylsiloxane(PDMS),the three composites exhibited unique heat transfer properties,and the HCS/PDMS and VCS/PDMS composites presented a high thermal conductivity of 42.18 and 45.01 W m^(−1)K^(−1)in fiber alignment direction,respectively,which were about 209 and 224 times higher than that of PDMS.The excellent thermal conductivity is mainly ascribed that the oriented CF scaffolds construct effective phonon transport pathway in the matrix.In addition,fishbone-shaped CF scaffold was also produced by multiple stacking and carbonization process,and the prepared composites exhibited a controlled heat transfer path,which can allow more versatility in the design of thermal management system.
