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Geochemistry and mineral chemistry of granitic rocks from west Wadi El Gemal area,southern Eastern Desert of Egypt:Indicators for highly fractionated syn-to post-collisional Neoproterozoic felsic magmatism
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作者 Hesham Mokhtar Adel A.Surour +2 位作者 Mokhles K.Azer Minghua Ren amir said 《Acta Geochimica》 2025年第1期163-188,共26页
Leucogranite,pegmatite,and aplite from selected areas in the Wadi El Gemal area in the southern Eastern Desert of Egypt were investigated geochemically for their petrogenesis.These rocks represent a significant episod... Leucogranite,pegmatite,and aplite from selected areas in the Wadi El Gemal area in the southern Eastern Desert of Egypt were investigated geochemically for their petrogenesis.These rocks represent a significant episode of felsic magmatism during the late stage of the Pan-African orogeny in the evolution of the Arabian–Nubian Shield(ANS)during the Late Neoproterozoic.On a petrographic basis,the leucogranite is sometimes garnetiferous and can be distinguished into monzogranite,syenogranite,and alkali feldspar granite.The analyses of muscovite,biotite,garnet,and apatite reveal the magmatic nature of the studied leucogranite.The investigated leucogranite,pegmatite,and aplite are alkali-calcic,calc-alkaline,and peraluminous.The peraluminous nature of these rocks is evidenced by using the chemical analyses of biotite.These studied rocks show a slight enrichment in light rare-earth elements(LREEs)and large-ion lithophile elements(LILE,especially Rb and Th),with an insignificant depletion of heavy rareearth elements(HREEs).On a geochemical basis,the leucogranite,pegmatite,and aplite in the study area crystallized from multiple-sourced melts that include mafic,metagraywake,and pelitic.They were derived from melts generated at crystallization temperatures around 568-900℃ for leucogranite,553-781℃ for pegmatite,and 639-779℃ for aplite based on the Zr saturation geothermometers,and at a pressure around 0.39-0.48 GPa,i.e.shallow depth intrusions.The studied felsic rocks have strong negative Eu anomalies,which are very consistent with an upper crust composition,indicating fractionation of feldspar cumulates.Also,they show a moderate La/Sm ratio indicating combined magmatic processes represented by partial melting and fractional crystallization.Integration of whole-rock chemical composition and mineral microanalysis suggests that felsic magmatism in the west Wadi El Gemal area produced voluminous masses of syn-to post-collisional granite,pegmatite,and aplite.An evolutionary three-stage model is presented to understand late magmatism in the ANS in terms of a geodynamic model.Such a model discusses the propagation of felsic magmatism in the ANS during syn-collisional to post-collisional stages. 展开更多
关键词 LEUCOGRANITE PEGMATITE Aplite Wadi El Gemal Petrogenesis Syn-collisional POST-COLLISIONAL
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水相氧化钛团簇的合成、性质和应用
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作者 刘彩云 amir said 王一峰 《中国科学:化学》 CAS CSCD 北大核心 2021年第6期583-594,共12页
氧化钛团簇是一类具有明确结构的分子型化合物,可以视为二氧化钛纳米颗粒的分子类似物,不仅具有新奇的分子结构,而且具有优异的光响应性质.近10年来,氧化钛团簇的合成、性质和应用研究取得了快速发展.水相合成的氧化钛团簇是多金属氧团... 氧化钛团簇是一类具有明确结构的分子型化合物,可以视为二氧化钛纳米颗粒的分子类似物,不仅具有新奇的分子结构,而且具有优异的光响应性质.近10年来,氧化钛团簇的合成、性质和应用研究取得了快速发展.水相合成的氧化钛团簇是多金属氧团簇(广义多酸、多金属氧酸盐)的一个分支.本文综述了水相氧化钛团簇的合成思路、合成体系和典型案例,氧化钛团簇的水溶性和稳定性,以及氧化钛团簇的已有应用案例,最后探讨了未来的发展方向. 展开更多
关键词 团簇 二氧化钛 主客体化学 分子光催化 晶体生长
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