The method to fluorinate the terminal group has achieved remarkable success and been widely used to fine-tune the intrinsic properties of organic acceptor materials.Referring to chlorination,however,it gets less atten...The method to fluorinate the terminal group has achieved remarkable success and been widely used to fine-tune the intrinsic properties of organic acceptor materials.Referring to chlorination,however,it gets less attention and remains ambiguous effect on organic photovoltaic(OPV)cells.Herein,a new non-fullerene acceptor named Y19 was reported with benzotriazole as the electron-deficient core and 2Cl-ICs as the strong electron-withdrawing end groups.Y19 exhibits a wide film absorption band from 600 nm to 948 nm and low LUMO(the lowest unoccupied molecular orbital)energy level of−3.95 eV.Photovoltaic devices based on PM6:Y19 show high-power conversion efficiency(PCE)of 12.76%with high open-circuit voltage(Voc)of 0.84 V,short-circuit current density(Jsc)of 22.38 mA/cm2 and fill factor(FF)of 68.18%.Broad external quantum efficiency(EQE)response of over 60%in the range of 480−860 nm can be obtained.This study demonstrates that chlorination,as a low-cost molecular design strategy,has its own superiorities to improve device performance and promote the potential application in OPV.展开更多
The rational design of polymer acceptors with strong and broad absorption is critical to improve photovoltaic performance.In this work,a new polymer acceptor PY9-T based on heptacyclic benzotriazole(Y9-C16)as a buildi...The rational design of polymer acceptors with strong and broad absorption is critical to improve photovoltaic performance.In this work,a new polymer acceptor PY9-T based on heptacyclic benzotriazole(Y9-C16)as a building block and thiophene unit as the linking unit was synthesized,which exhibited a low bandgap(1.37 eV)and a high extinction coefficient of the neat film(1.44×10^(5) cm^(−1)).When PY9-T was blended with the wide bandgap polymer donor PBDB-T,the all-polymer solar cells(APSCs)showed a high power conversion efficiency(PCE)of 10.45%with both high open circuit voltage of 0.881 V and short-circuit current density of 19.82 mA/cm^(2).In addition,APSCs based on PY9-T show good thermal stability,as evidenced by slight changes morphologies when annealed at 100℃.These results suggest that Y9-C16 provides a new building block to develop efficient and stable polymer acceptors.展开更多
BIM(building information modelling)指的是建筑信息模型技术,是一种基于数字化、信息化的建筑设计、施工和管理方法。BIM 技术将建筑物的全部信息通过计算机软件进行可视化模拟,模型中包含了建筑物的结构、空间、材料、设备、费用等...BIM(building information modelling)指的是建筑信息模型技术,是一种基于数字化、信息化的建筑设计、施工和管理方法。BIM 技术将建筑物的全部信息通过计算机软件进行可视化模拟,模型中包含了建筑物的结构、空间、材料、设备、费用等方面的信息数据。这些数据可以在不同阶段被不同人员使用,协调不同的专业与部门,以提高建筑项目的效率和精度。BIM 技术作为数字化建筑设计和施工的重要工具,在建筑业和土木工程领域得到越来越广泛的应用。利用BIM技术,可以实现建筑物设计与施工全过程的数字化管理,提高项目的设计质量、施工效率、安全以及节约成本。同时,BIM 也支持各个参与者在迭代和阶段性交付方面的管理,从而有助于在整个生命周期中提高建筑物的维护和运行效率。展开更多
基金Project(21875286)supported by the National Natural Science Foundation of China。
文摘The method to fluorinate the terminal group has achieved remarkable success and been widely used to fine-tune the intrinsic properties of organic acceptor materials.Referring to chlorination,however,it gets less attention and remains ambiguous effect on organic photovoltaic(OPV)cells.Herein,a new non-fullerene acceptor named Y19 was reported with benzotriazole as the electron-deficient core and 2Cl-ICs as the strong electron-withdrawing end groups.Y19 exhibits a wide film absorption band from 600 nm to 948 nm and low LUMO(the lowest unoccupied molecular orbital)energy level of−3.95 eV.Photovoltaic devices based on PM6:Y19 show high-power conversion efficiency(PCE)of 12.76%with high open-circuit voltage(Voc)of 0.84 V,short-circuit current density(Jsc)of 22.38 mA/cm2 and fill factor(FF)of 68.18%.Broad external quantum efficiency(EQE)response of over 60%in the range of 480−860 nm can be obtained.This study demonstrates that chlorination,as a low-cost molecular design strategy,has its own superiorities to improve device performance and promote the potential application in OPV.
基金Project(21875286)supported by the National Natural Science Foundation of China。
文摘The rational design of polymer acceptors with strong and broad absorption is critical to improve photovoltaic performance.In this work,a new polymer acceptor PY9-T based on heptacyclic benzotriazole(Y9-C16)as a building block and thiophene unit as the linking unit was synthesized,which exhibited a low bandgap(1.37 eV)and a high extinction coefficient of the neat film(1.44×10^(5) cm^(−1)).When PY9-T was blended with the wide bandgap polymer donor PBDB-T,the all-polymer solar cells(APSCs)showed a high power conversion efficiency(PCE)of 10.45%with both high open circuit voltage of 0.881 V and short-circuit current density of 19.82 mA/cm^(2).In addition,APSCs based on PY9-T show good thermal stability,as evidenced by slight changes morphologies when annealed at 100℃.These results suggest that Y9-C16 provides a new building block to develop efficient and stable polymer acceptors.
