Polydentate ligands, N,N’-bis[o-(diphenylphosphino)benzylidene]-1,2-propane-dia-mine [P2N2Me for short] and N,N’-bis[o-(diphenylphosphino)benzy1]-12-propanediamine [P2N2 H4Me for short] have been synthesized. The in...Polydentate ligands, N,N’-bis[o-(diphenylphosphino)benzylidene]-1,2-propane-dia-mine [P2N2Me for short] and N,N’-bis[o-(diphenylphosphino)benzy1]-12-propanediamine [P2N2 H4Me for short] have been synthesized. The interaction of RuCl2(DMSO)4 with one equiv-alent of P2N2Me or P2N2H4Me in refluxing toluene gave trans-RuCl2(P2N2Me) and trans-RuClz(P2N4H4Me) in good yield, respectively. The ligands and the complexes have been fully characterized by elemental analysis and spectroscopic methods. The complexes act as an excellent catalyst precursor in hydrogen transfer hydrogenation of aretophenone in catalyst: aretophenone :iso-PrOK of 1: 100: 15, leading to 2-phenylethanol of 89-96% yield.展开更多
After widely screening, a kind of bacteria was obtamed, which is casy to culture and hasstrong ability of reducing Au3+ to Au0. It was used to prepare the highly dispersive Au/a-Fe2O3catalyst by in situ reducmg the Au...After widely screening, a kind of bacteria was obtamed, which is casy to culture and hasstrong ability of reducing Au3+ to Au0. It was used to prepare the highly dispersive Au/a-Fe2O3catalyst by in situ reducmg the Au3+ ions impregnated on a-Fe2O3 supporter to Au0 particles.with a mean size of 5 nm, under the condition of 28℃ and pH 4.5. The reductive degree ofAu3+ was up to 100%. This catalyst showed good catalytic property for the oxidation of carbonmonoxide, the percent conversion of 1.5% CO, balanced withe air was up to 100% under thecondition of 25~28℃and GHSV 500mL·h-1·g-1, and the percent conversion of 100% lastedfor 75 h at 25 ℃.展开更多
文摘Polydentate ligands, N,N’-bis[o-(diphenylphosphino)benzylidene]-1,2-propane-dia-mine [P2N2Me for short] and N,N’-bis[o-(diphenylphosphino)benzy1]-12-propanediamine [P2N2 H4Me for short] have been synthesized. The interaction of RuCl2(DMSO)4 with one equiv-alent of P2N2Me or P2N2H4Me in refluxing toluene gave trans-RuCl2(P2N2Me) and trans-RuClz(P2N4H4Me) in good yield, respectively. The ligands and the complexes have been fully characterized by elemental analysis and spectroscopic methods. The complexes act as an excellent catalyst precursor in hydrogen transfer hydrogenation of aretophenone in catalyst: aretophenone :iso-PrOK of 1: 100: 15, leading to 2-phenylethanol of 89-96% yield.
文摘After widely screening, a kind of bacteria was obtamed, which is casy to culture and hasstrong ability of reducing Au3+ to Au0. It was used to prepare the highly dispersive Au/a-Fe2O3catalyst by in situ reducmg the Au3+ ions impregnated on a-Fe2O3 supporter to Au0 particles.with a mean size of 5 nm, under the condition of 28℃ and pH 4.5. The reductive degree ofAu3+ was up to 100%. This catalyst showed good catalytic property for the oxidation of carbonmonoxide, the percent conversion of 1.5% CO, balanced withe air was up to 100% under thecondition of 25~28℃and GHSV 500mL·h-1·g-1, and the percent conversion of 100% lastedfor 75 h at 25 ℃.
