乍得潜山地层微裂缝发育丰富,地层压力系数在1以下,采用常规钻井液体系往往导致地层发生恶性漏失,针对该技术难题,提出采用可循环微泡钻井液钻潜山储层。合成出一种可用于可循环微泡钻井液的发泡能力强同时具有稳泡能力的发泡剂GWFOM-LS...乍得潜山地层微裂缝发育丰富,地层压力系数在1以下,采用常规钻井液体系往往导致地层发生恶性漏失,针对该技术难题,提出采用可循环微泡钻井液钻潜山储层。合成出一种可用于可循环微泡钻井液的发泡能力强同时具有稳泡能力的发泡剂GWFOM-LS,在120、150℃时0.5%GWFOM-LS的发泡体积分别为720 m L和400 m L以上,其抗温能力达到130℃,抗盐能力达10%,抗钙能力达0.5%。基于该发泡剂优选出密度范围在0.70~0.96 g/cm^3的可循环微泡钻井液体系。该体系在乍得Baobab C1-13井裂缝发育的潜山油层进行了应用。现场应用表明,该发泡剂配制的可循环微泡钻井液性能稳定,而且具有较好的携岩性能和储层保护性能,利于井下工具信号传导,解决了钻井过程中潜山地层恶性漏失问题,为今后潜山储层开发奠定了技术基础。展开更多
We investigated the effect of calcination temperature, reaction temperature, and different amounts of replenished lattice oxygen on the partial oxidation of methane （POM） to synthesis gas using perovskite-type LaFeO...We investigated the effect of calcination temperature, reaction temperature, and different amounts of replenished lattice oxygen on the partial oxidation of methane （POM） to synthesis gas using perovskite-type LaFeO3 oxide as oxygen donor instead of gaseous oxygen, which was prepared by the sol-gel method, and the oxides were characterized by XRD, TG/DTA, and BET. The results indicated that the particle size increased with the calcination temperature increasing, while BET and CH4 conversion declined with the calcination temperature increasing using LaFeO3 oxide as oxygen donor in the absence of gaseous oxygen. CO selectivity remained at a high level such as above 92%, and increased slightly as the calcination temperature increased. Exposure of LaFeO3 oxides to methane atmosphere enhanced the oxygen migration of in the bulk with time online owing to the loss of lattice oxygen and reduction of the oxidative stated Fe ion simultaneously, The high reaction temperature was favorable to the migration of oxygen species from the bulk toward the surface for the synthesis gas production with high CO selectivity. The product distribution and evolution for POM by sequential redox reaction was determined by amounts of replenished lattice oxygen with gaseous oxygen. The optimal process should decline the total oxidation of methane, and increase the selectivity of partial oxidation of methane.展开更多
文摘乍得潜山地层微裂缝发育丰富,地层压力系数在1以下,采用常规钻井液体系往往导致地层发生恶性漏失,针对该技术难题,提出采用可循环微泡钻井液钻潜山储层。合成出一种可用于可循环微泡钻井液的发泡能力强同时具有稳泡能力的发泡剂GWFOM-LS,在120、150℃时0.5%GWFOM-LS的发泡体积分别为720 m L和400 m L以上,其抗温能力达到130℃,抗盐能力达10%,抗钙能力达0.5%。基于该发泡剂优选出密度范围在0.70~0.96 g/cm^3的可循环微泡钻井液体系。该体系在乍得Baobab C1-13井裂缝发育的潜山油层进行了应用。现场应用表明,该发泡剂配制的可循环微泡钻井液性能稳定,而且具有较好的携岩性能和储层保护性能,利于井下工具信号传导,解决了钻井过程中潜山地层恶性漏失问题,为今后潜山储层开发奠定了技术基础。
基金the National Natural Science Foundation of China (20306016, 20322201)
文摘We investigated the effect of calcination temperature, reaction temperature, and different amounts of replenished lattice oxygen on the partial oxidation of methane （POM） to synthesis gas using perovskite-type LaFeO3 oxide as oxygen donor instead of gaseous oxygen, which was prepared by the sol-gel method, and the oxides were characterized by XRD, TG/DTA, and BET. The results indicated that the particle size increased with the calcination temperature increasing, while BET and CH4 conversion declined with the calcination temperature increasing using LaFeO3 oxide as oxygen donor in the absence of gaseous oxygen. CO selectivity remained at a high level such as above 92%, and increased slightly as the calcination temperature increased. Exposure of LaFeO3 oxides to methane atmosphere enhanced the oxygen migration of in the bulk with time online owing to the loss of lattice oxygen and reduction of the oxidative stated Fe ion simultaneously, The high reaction temperature was favorable to the migration of oxygen species from the bulk toward the surface for the synthesis gas production with high CO selectivity. The product distribution and evolution for POM by sequential redox reaction was determined by amounts of replenished lattice oxygen with gaseous oxygen. The optimal process should decline the total oxidation of methane, and increase the selectivity of partial oxidation of methane.
